DATA VALIDATION · 2020. 12. 12. · documentation of manual integrations was included in the data...

DATA VALIDATION

FOR

OCCIDENTAL CHEMICAL PLANTPOTTSTOWN, PENNSYLVANIA

ORGANIC DATA:Pesticide/PCB in Waters

Order Number 43191

Chemical Analyses Performed by;BCM Laboratory

FOR:

Occidental Chemical CompanyNiagara Falls, NY

BY:

Trillium, Inc.7A Grace's Drive

Coatesville, Pennsylvania 19320(215) 383-7233

March 3, 1992

M Wo?\ TRILL1UM.NC.

91141/DAS

HR3051498A

TRILLIUM,

EXECUTIVE SUMMARY

Validation of the pesticide/PCB data prepared by the BCMLaboratory for two groundwater samples from the Occidental ChemicalPlant Site in Pottstown, Pennsylvania, has been completed accordingto EPA's "Functional Guidelines for Evaluating Organics Analyses(2/88)" with modifications specified by EPA Region III. These datawere reported under Laboratory Order Number 43191, which includedthe following field samples:

Sample Number Lab ID Collected

OXY-TB1GW-1 130414 9/24/91Rinse Blank 130419 9/24/91

Sample results for this sample set were valid as reported.No qualifications were required based on the results of the datavalidation effort.

The following observations were made with respect to thedata package presentation:

• No documentation was provided for manually integratedareas and the alterations were not dated and initialledon the sample quantitation reports.

• The data system failed to identify one or more analytepeaks in many of the standards.

• The analyst failed to identify degradation products ofendrin and DDT in several standard runs, resulting inincorrect reported breakdown values.

• The presence of unexplained gaps in the 72-hour sequencegives rise to the question of whether the appropriateorder of analysis was followed.

\ TRILLIUM,NC.

INTRODUCTION

Analyses were performed according to the USEPA ContractLaboratory Program (CLP) 2/88 Statement of Work. Results of sampleanalyses are reported by the laboratory as either qualified orunqualified. Unqualified results mean that the reported values maybe used without reservations. Various qualifier codes are used bythe laboratory to denote specific information regarding theanalytical results.

The data validation process is intended to evaluate data on atechnical basis rather than a contract compliance basis forchemical analyses conducted under the CLP. An initial assumptionis that the data package is presented in accordance with the CLPrequirements. It is also assumed that the data package representsthe best efforts of the laboratory and has already been subjectedto adequate and sufficient quality review prior to submission forvalidation.

During the validation process, laboratory-qualified andunqualified data are verified against all available supportingdocumentation. Based on this evaluation, qualifier codes may beadded, deleted, or modified by the data validator. Final validatedresults are, therefore, either qualified or unqualified.Unqualified results still mean that the reported values may be usedwithout reservation. Validator-qualified results are annotatedwith the following codes in accordance with the Region Ill-modifiedFunctional Guidelines:

U = Not detected. The associated number indicates approximatesample concentration necessary to be detected.

B = Not detected substantially above the level reported inlaboratory or field blanks.

R = Unreliable result. Analyte may or may not be present inthe sample. Supporting data necessary to confirm result.

N = Tentative identification. Consider present. Specialmethods may be needed to confirm its presence or absencein future sampling efforts.

J = Analyte present. Reported value may not be accurate orprecise.

K = Analyte present. Reported value may be biased high.Actual value is expected to be lower.

L = Analyte present. Reported value may be biased low.

2

AR3Q55QQ

\ TRILLIUM

Actual value is expected to be higher.

UJ = Not detected. Quantitation limit may be inaccurate orimprecise.

UL = Not detected. Quantitation limit is probably higher.

These codes are recorded on the Data Summary Forms (AttachmentA) and the Organic Analysis Data Sheets (Attachment B) for eachsample to qualify the results as appropriate according to thereview of the data package.

Details of the validation findings and conclusions withrespect to the pesticide/PCB data are provided in the followingsections of this report:

I. Holding Times

II. Pesticides Instrument Performance

III. Calibration

A. Initial

B. Analytical Sequence

C. Continuing

IV. Blanks

V. Surrogate Recovery

VI. Matrix Spike/Matrix Spike Duplicate

VII. Field Duplicates

VIII. Compound Identification

IX. Compound Quantitation and Reported Detection Limits

X. Overall Assessment

INC.

SR30550I

\TRILLILJlV

I. Holding Times

Both samples were extracted and analyzed within prescribedholding times.

II. Pesticides Instrument Performance

Four criteria are evaluated to ensure that adequatechromatographic resolution and instrument sensitivity were achievedduring the analyses. These include: (1) DDT Retention Time (RT);(2) RT Windows; (3) DDT/Endrin Breakdown Check; and (4) theDibutylchlorendate (DBC) Surrogate RT Check.

Both samples and associated QC samples were analyzed under asingle Standard Series run on October 14-16, 1991. Channels ADC-13and ADC-14 on a single instrument were used for quantitation andconfirmation runs, respectively. The series was performed using asplit injection system that allowed simultaneous injections on thetwo columns.

The DDT RT was well beyond the 12 minute minimum requirement;runs were made on wide-bore capillary columns, with DDT eluting at24 minutes or later on both columns.

Stability of standard analyte RTs throughout the 72-hourseries is evaluated through the use of RT windows established atthe start of each series and recorded on Form 9. As often happenswith capillary column analysis, the RTs for the pesticide/PCBanalytes were so consistent in the original calibration that therewas 0% range reported for most of the analytes; in effect, nowindow allowance at all was calculated. This results in standardanalytes appearing "outside" of the allowable "(0%) window". Wherea slight shift in RTs was observed for the standards, it was smalland consistent throughout the chromatogram. There were manyoccasions where an analyte was not identified by the data system,apparently due to these slight shifts in RT. With careful andconsistent analyst review there should be no difficulty in properlyidentifying the target compounds based on RT. No data werequalified based on analyte RT shifts in some of the standards.

RT stability within a series is also monitored by watching theshift of the DBC surrogate RT in every standard and sample run. Thepercent difference (%D) between the DBC RT in the first EVALA runof the series and the current run is recorded on Form 8E. Thisform also serves as a run log since it identifies, in chronologicalsequence, all runs performed in each series. All DBC RT shiftswere below the maximum allowable shift of 1.5% for mega-borecolumns with the exception of one run on 10/15/91 at 12:49 on

c.

\ TRILLIUM™,

ADC-13, with a %D of 1.5. The affected sample was not associatedwith this data set and subsequent runs were below the limit; nopertinent sample data were affected.

Breakdown calculations for DDT and Endrin were incorrectlyperformed for several of the EVALB standards. These errorsoccurred where slight RT shifts prevented the data system fromcorrectly identifying the breakdown products. Zero percent (0%)breakdown was reported for both Endrin and DDT on 10/15/91 at 17:52on ADC-13. After careful examination on the raw data it wasapparent that endrin aldehyde, endrin ketone, DDE and ODD were allpresent in the standard but were not identified by the data systemdue to a RT shift of approximately 0.03 minutes. Similar errorsoccurred for the EVALB run 10/14/91 at 10:05 on ADC-14, where onlyendrin aldehyde and endrin ketone were missed by the data system.Corrected breakdowns were calculated as follows:

% DegradationADC-13 10/15/91 17:52 Endrin 23.8

DDT 9.6Combined 14.8

ADC-14 10/14/91 10:05 Endrin 10.8.Combined 10.8

Breakdown values for endrin were all above the maximumallowable (20%) for ADC-13. However, neither endrin nor itsbreakdown products were detected in any of the samples andacceptable matrix spike recoveries indicate that this did notadversely affect the data.

III. Calibration

A. Initial. The percent relative standard deviations (%RSD)for aldrin, endrin, and DBC were below the upper QC limit of 10%for both ADC-13 and ADC-14. The %RSD for DDT was acceptable onADC-14 but above the limit on ADC-13, the quantitation column. DDTwas not detected in the field samples so no qualifiers wererequired.

B. Analytical Sequence. The correct sequence appears to havebeen followed for both ADC-13 and ADC-14. However, the timeintervals between injections is highly inconsistent. The datapackage includes a number of hexane blanks which were not listed onthe run log. The validator made the assumption that the analysisof such unlisted blanks and/or lapses in instrument operation wasresponsible for the observed time inconsistencies. Based on thisassumption there was no need to qualify any data.

5R305503

\ TRILLIUM,

The laboratory would be well advised to list the blanks andalso indicate any lapses in instrument operation on the form 8E sothat there is no question that the proper order has been followedthroughout each 72-hour series.

C. Continuing. Continuing calibration standards met themaximum %D criteria of 15% for quantitation (ADC-13) and 20% forconfirmation (ADC-14) with the following exceptions:

ADC-13 INDB 10/16/91 04:37 Endrin 20.0%

ADC-14 INDA 10/15/91 11:58 DDT 20.5%

INDB 10/16/91 00:20 Endosulfan sulfate 25.1%

INDB 10/16/91 04:37 Endosulfan sulfate 25.0%

None of these analytes was detected in the field samples,therefore no data were qualified.

Integrations for several compounds in one or more standardruns were altered manually on the quantitation reports. Thesechanges were not dated or initialled, and there was no way toascertain the reason for the change from the raw data provided. Nodocumentation of manual integrations was included in the datapackage and no mention was made in the case narrative. In theabsence of supporting documentation, these alterations were assumedto be valid in order to complete the validation.

IV. Blanks

One laboratory method blank (MB) and one Rinse Blank (RB) wereprepared with this sample set. No target analytes were detected ineither the RB or the MB.

V. Surrogate RecoveryAll reported surrogate recoveries were within the CLP advisory

limits of 24-154% for waters samples.

VI. Matrix Spike/Matrix Spike Duplicates (MS/MSDs)

A matrix spike/matrix spike duplicate (MS/MSD) pair wasprepared and analyzed using sample OXY-TB1GW-1. All values forpercent recovery (%R) as well as relative percent difference (RPD)were calculated and reported correctly. All values for %R and RPD

TRLLIUIVLc

were within acceptance criteria.

VII. Field Duplicates

No field duplicate/sample pair was included in this sampleset.

VIII. Compound Identification

No target analytes at levels above the contract requiredquantitation limits (CRQLs) were qualitatively confirmed in any ofthe groundwater samples or blanks associated with this sample set.

IX. Compound Quantitation and Reported Detection Limits

All target analytes were correctly reported as "not detected";no adjustments to the CRQLs were required for any of the samples.

X. Overall Assessment

The pesticide/PCB results for the samples in this data packagewere determined to be valid as reported with no qualificationsbased on the validation effort-

The following observations were made with respect to the datapackage presentation:

• Peak areas were altered manually for several compounds inone or more standards in the data package. Nodocumentation was provided for manual integrations andthe alterations were not dated and initialled.

• The data system failed to identify one or more analytepeaks in many of the standards. This appeared to be dueto slight RT shifts and was generally corrected by theanalyst, but could lead to false negatives in sampleanalyses.

• The analyst failed to identify degradation products ofendrin and DDT in several standard runs, resulting inincorrect reported breakdown values.

• The presence of unexplained gaps in the 72-hour sequencegives rise to the question of whether the appropriateorder of analysis was followed.

HK30SSOS

\TRILLILJM 1NC.

ATTACHMENT A

DATA SUMMARY FORM-PESTICIDE/PCBOrder # 43191

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ATTACHMENT B

ORGANIC ANALYSIS DATA SHEETS (FORM I)Pesticide/PCB Order # 43191

W3Q55G3

ID EPA SAMPLE .NOPESTICIDE ORGANICS ANALYSIS DATA SHEET

Name: BCM Contract:J30414

Lab Code: BCM Case No.: 43191 SAS No.: SDG No.: W1007

Matrix: (soil/water) WATER Lab Sample ID: 130414Sample wt/vol: 980. (g/mL)ML Lab File ID: N1014214»Level: (low/med) LOW Date Received: 9/24/91% Moisture: not dec. 100, dec. 0. Date Extracted: 0/30/91'Extraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 10/15/91GPC Cleanup: (Y/N) N pH: .0 Dilution Factor: 1.00

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

319-84-6 ———— alpha-BHC319-85-7 ———— beta-BHC319-86-8 ———— delta-BHC58-89-9 ——— -gamma-BHC (Lindane)76-44-8 ———— Heptachlor309-00-2 ———— Aldriri1024-57-3—— — Heptachlor epoxide959-98-8 ——— Endosulfan I60-57-1 ———— Dieldrin72-55-9 ———— 4 , 4 ' -DDE72-20-8 ——— -Endrin

33213-65-9 ———— Endosulfan II72-54-8 ———— 4, 4 '-ODD

1031-07-8— —— Endosulfan sulfate50-29-3- ———— 4, 4 '-DDT72-43 -5 —— — Methoxychlor

53494-70-5 —— — Endrin ketone5103-7 1-9 ———— alpha-Chlordane5103-74-2 ——— 'gamma-Chlordane8001-35-2 —— — Toxaphene12674-11-2 ———— Aroclor-101611104-28-2 ——— Aroclor-122111141-16-5 —— - — Aroclor-123253469-21-9 ———— Aroclor-124212672-29-6 ———— Aroclor-124811097-69-1 ———— Aroclor-125411096-82-5 ————— Aroclor-1260

.051

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FORM I PEST 1/87 Rev.

HR3055Q9 000005

ID . EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET

Lab Name: BCM Contract:' 130419


Matrix: (soil/water) WATER Lab Sample ID: 130419Sample wt/vol: 980. (g/mL)ML Lab File ID: N1014216Level: (low/med) LOW Date Received: 9/24/91% Moisture: not dec. 100. dec. 0. Date Extracted: 9/30/91Extraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 10/15/91GPC Cleanup: . (Y/N) N pH: .0 Dilution Factor: 1.00


319-84-6 ———— alpha-BHC319-85-7 ———— beta-BHC3 19-8 6-8 —— — delta-BHC58-89-9 —— — gamma-BHC (Lindane)76-44-8 ———— Heptachlor309-00-2 ——— Aldrin1024-57-3— — —Heptachlor epoxide959-98-8 ———— Endosulfan I60-57-1 ——— Dieldrin72-55-9 ———— 4 , 4 ' -DDE72-20-8- ——— Endrin

33213-65-9 ——— Endosulfan II72-54-8 ———— 4, 4 '-ODD

1031-07-8 ——— Endosulfan sulfate50-29-3 ———— 4, 4 '-DDT72-43-5 ——— Methoxychlor

53494-7 0-5——- -Endrin ketone5103-71-9— —— alpha-Chlordane5103-74-2 ——— gamma-Chlordane8001-35-2 ——— Toxaphene12674-11-2 ———— Aroclor-101611104-28-2 ———— Aroclor-122111141-16-5 ———— AroclOr-123253469-21-9 ———— Aroclor-124212672-29 -6 ———— Aroclor-124 811097-69-1-- ——— Aroclor-125411096-82-5 - ——— Aroclor-1260

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000006

Attachment C

flR3055

'A'-ft Ljaomary Analytics! ;»ata Package

Divisionr»ravers Road _______._____......f.-.own. ?A i.9401 i ~"

I'ata Pacxa:s13. iJ^rc. I .... .'.'17'

Clients OCCIDENTAL CSHICAL

Project No.: 00-4064-13

Project Manager:

Order: 43191

: PA 46-007

SAMPLE ID 2CH No. iOCftTJON SAHPii 13 3C« No. LOCATION SAKPLE ID BCM No.

iXY-iT.Gii-j. ijNFii.fi!'.?) 130414 RIM?. -LM JNfluIPIO 130419 «E!H)D BLANK 1304221UP 130414 130423 SPIKE 1WU4 130424

This case includes the following package?: BCH Subcontractor

K/hS Voi.uiies Cv3V C ]CC/MS S2ni-Volatiles CvJ - C 3

Metajf CtX £3Hicro C 3 C 3

5C C IT C 3

This is nc Gas ChroBJtoprapny package for \hjs case

Ojt-3 Pacitane andiKd oy0

oooooiAR3055I2

2EWATER PESTICIDE SURROGATE RECOVERY

Lab Name: BCM Contract:Lab Code: BCM Case No.: H Lj SAS Mo>. SDG No

1-2345-6-

S-9-101112131415

1718192021222324252627282930

EPASAMPLE NO.

x^y o J jh '?98?lMr?

-f2 8-2iMSB ___-MSPIKE —————42-9B2-1 ——————— 3r2982€ —————

p- 129818 —————— 12002S —————130422130414MS\30414MSDMSPIKE/30414130419•129810 —— • ——

SI(DBC) *

—112r 89

82— KJ6 __i QQ

49—— 3*-—1-49—

836260925677

—— 45—

OTHER

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ADVISORY -QC LIMITS o//

SI (DBC) = Dibutylchlorendate (24-154) /fc># Column to be used to flag recovery values* Values outside of contract reguired QC limitsD Surrogates diluted out

page 1 of 1FORM II PEST-1 1/87 Rev

000012

3EWATER PESTICIDE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Name: BCM Contract:

Code: BCM Case No.: 43191 SAS No.: SDG No.: W1007

Matrix Spike - EPA Sample No. :j 30414

COMPOUND

gamma-BHC (Lindane)HeptachlorAldrinDieldrinEndrin4,4' -DDT

SPIKEADDED(UG/L )

.20

.20

.20

.51

.51

.51

SAMPLECONCENTRATION

(UG/L )

.00

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.00

.00

.00

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MSCONCENTRATION

(UG/L )

.19

.18• _LJ?.43.56.45

MS%

REC #

9286958411089

QCLIMITSREC.

56-12340-13140-12052-12656-12138-127

MCOMPOUNDgamma-BHC (Lindane)HeptachlorAldrinDieldrinEndrin4,4' -DDT

SPIKEADDED(UG/L )

.20

.20

.20

.51

.51

.51

MSDCONCENTRATION

(UG/L )

.21

.18

.20

.43

.54

.45

MSD%

REC #

10287968510688

%RPD #

1111041

QC L]RPD

152022182127

:MITSREC.

56-12340-13140-12052-12656-12138-127

# Column to be used to flag recovery and RPD values with an asterisk

* Values outside of QC limits

RPD: 0 out of 6 outside limitsSpike Recovery: 0 out of 12 outside limits

COMMENTS:

FORM III PEST-1 1/87 Rev.

4CPESTICIDE METHOD BLANK SUMMARY

Lab Name: BCM Contract:

Lab Code: BCM Case No.:< /3/9/ SAS No.: SDG No.: W1007Lab Sample ID: 130422MB Lab File ID: N1014209

Matrix: (soil/water) WATER Level: (low/med) LOW

Date Extracted: B/JU/31"-?/ /?/ \a\ Extraction: (SepF/Cont/Sonc) SEPFtot*. i\\fli 'Date Analyzed (1) : 10/15/91 r Date Analyzed (2) : 10/15/91

Time Analyzed (1): 15:43 Time Analyzed (2): 15:43Instrument ID (1) : 0013 Instrument ID (2) : 0014GC Column ID (1) : DB608 GC Column ID (2) : DB1701

THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS AND MSD:

1234567891011121314151617181920212223242526

EPASAMPLE NO.

/30414MS/30414MSDMS PIKE

/ 30414130419

LABSAMPLE ID

130424S130423DMS PIKE130414130419

DATEANALYZED 1

10/15/9110/15/9110/15/9110/15/9110/15/91

DATEANALYZED 2

10/15/9110/15/9110/15/9110/15/9110/15/91

Comments:

page 1 ofFORM IV PEST 1/87 Rev.

000014

SR3055I5

BCM

Sample Data

000015&R305516

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET

Lab Name: BCM Contract: Occ,(be-WTflL-130414


Matrix: (soil/water) WATER Lab Sample ID: 130414Sample wt/vol: 980. (g/mL)ML Lab File ID: N1014214

tLevel: (low/med) LOW Date Received: 9/24/91% Moisture: not dec. 100. dec. 0. Date Extracted: 0/30/9iExtraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 10/15/91GPC Cleanup: (Y/N) N pH: .0 Dilution Factor: 1.00

CONCENTRATION UNITS:GAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

319-84-6————alpha-BHC319-85-7————beta-BHC319-86-8———delta-BHC58-89-9———gamma-BHC (Lindane)76-44-8————Heptachlor309-00-2———Aldrin1024-57-3————Heptachlor epoxide959-98-8————Endosulfan I60-57-1———Dieldrin72-55-9————4 ,4 ' -DDE72-20-8 ———Endrin

33213-65-9———Endosulfan II72-54-8————4 , 4 ' -DDD

1031-07-8————Endosulfan sulfate/ _72-43-5———Methoxychlor

53494-70-5————Endrin ketone5103-71-9————alpha-Chlordane5103-74-2 ————gamma-Chlordane8001-35-2————Toxaphene12674-11-2———Aroclor-101611104-28-2———Aroclor-122111141-16-5————Aroclor-123253469-21-9————Aroclor-124212672-29-6————Aroclor-124811097-69-1————Aroclor-125411096-82-5————Aroclor-1260

051051,051,051,051,051,051,051.10.10.10.10.10.10.10.51.10.51.511.0.51.51.51.51.511.01.0


FORM I PEST 1/87 Rev

ooooisAR3055I7

L Ii. i

BUM LABUKAIUKltb Keport - UtN 11 Hediurn Area rorm

bampie Name : 13U414 6Ua yaUML-lUML ~UI1UU/ Keport No : y/.UlHIM rUK LLP PtbIb/PLBb UN AUL-13 Page 1LULUHN UB6U8 3UH X U.^?43 HH U.a3 DM hlLM 1U#U331222 . 1NJ 1 '.ULAKKltK P-1? A I -?Pbl, IUI AL hLUU ~/UML/niN tUU 3UUU KANb't Ulul INJtLllUN I'yUU, Imin ^U/rnin, 'Z/ L 14M1N

Uook/Haqe :

Heak Processor : Lienie Multilevel : t-alse

Instrument : ftUL 13 Application : Loop

Ualculation : LxternalblU Uuant i t a t i on : AreaUnits

Kesuit r i l e : /UR Ift/tX I K«U I b/Khb'UL I /Nil) 14214. Ktb

Kun l i m e : 4U.UU Hinutes Iniected on lue Uct I1?,, 1VV1 /:1V:UU pm

Sequence rile: /UA Ift/tX I KAL Lb/ShUUhNUL/btULLP lUl^Vl l^.btU

bubseq/bample: I/ 14 Bottle no. : 14

reshold Min-Ar Pkwidth Kh Unknown2.U 1.UUUUL+U3 . U4U U - U U U t + U U

Kef Udw Abs Kef-KIW Non Kef Win Abs Non Pef-KIW Ident LevelU.UU l.bU U.UU l.bU 1UUU.UU

% Uil-Hact Smp-Amt btd-Amt % Purity Ini "o 1 Katio3 U.UUUUt+UU l.UUUUt+UU 1UU.UUU l.UUU

Kun Status : KunbtatusUKtndUf FBase i me

limed tvents lime tvents Logic Ualue hventUpdate1 U.UU Neqat ivePeaks tventUff -l.UU halse2 .11) KesetBLAl iUal ley LventUn -l.UU halse

Pk# Kl ID-tm PeakWidth Area Lode AH1JUN I Name1 1.32 #1.32 .U221 221362BB 6.UU!J4t.-U6 bULULN I hKUNI2 1.61 .2/31 13BUUU62BS U.UUUUt+UU3 l.W . U'?2y 6U3iyt!B U.UUUUt + UU4 2.43 .U42/ V/UUBB U.UUUUt+UU•? 2.6U .U41U 1U63"?3BB U.UUUUt + UU6 3-. Ul . UV1?/ ia4///BB U . UUUUt+UU

3.'717 . Ua2"7 33x'4VBB U.UUUUt+'JU3./I? . UV4« l/ia32BB U.UUUUt+UU4-^u .ua24 ia2aaB u.uuuut+uu4.6y .26U1 136U"?BB U.UUUUt+UU"y.uy .ll'?/' yiloBB U.UUUUt + UU

12 17.4b> .UyVU 21b/lBB U.UUUUt + UU13 b.y? . 122a 1U6336BB U.UUUUt + UU 00001714 6. ay .1U/'U 21?31BB Li. UULIUt+UU fl R fl S 5 | 8lt> /.2/ .12y/ 64l?'?2BB U.UUUUt + UU H H O U U U I U16 .-'." y .1414 >"-"r>. BB I.' . IJUU.Ut + UU

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BUM LABUKAIUKltb Keport - UtNlt Medium Area rorm

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BUM LABUKAIUKltb Keport - btN 11 Medium Area !-orm

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l o t a i Area : 1/6"?1B16 lotal AMUUNI : 1.411?

Heport l i m e : Wed Uct 16, 1**1 12:U*:46 pmMethod : /UAIA/tXIKAUIb/MtIHUU/MIHULP lUlb*l 13.MIH

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BUM LABUKAIUKltb Keport - UtNlt Medium Area rorm

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BUM LABUKAIUKltb Keport - UtN 11 Medium Area rorm

bampie Name : 13U414 6UB *BUML-1UML UI1UU/ Keport No : B/.UUMIH hUK ULP Ptblb/PUBb UN AUU-14 ' Page 1UULUMN UB1/U1 3UM X U.'?3MM 1UM r 1LM 1 U# U4*3U1?2 1NJ I 2l?UUP-1? --7ML/M1N MAbb r LUU1 MAKt UP P-1? (-UK IU I AL Ur -/UML/M1NtUU 3UUU, KANb't U, lu i INJtUliUN l^UU, 1m in ^U/min, 2

Book/Page :

Peak Processor : Uenie Multilevel : halse

Instrument : AUU 14 Application : Loop

Ualculation : txternalblU Uuantitation: AreaUnits

Kesult h i l e : /DA IA/tXIKAUib/KtbULI/U1U14214. Ktb

Kun l i m e : 4U.UU Minutes Iniected on I ue Uct 11?, 1**1 /:i*:UU pm

bequence hile: /UA 1 A/tX I KAUJ b/btUUtNUt/btUULP 1U11?*! 14.btU


reshold Mm-Ar Pkwidth Kh Unknown"7.U 2.UUUUt+U3 .16U U.UUUt+UU

Kef Wdw Abs Kef-KIW Non Kef Win Abs Non Kef-KIW Ident LevelU.UU l.bU U.UU 1.1? U 1UUU.UU

% Uii-hact bmp-Amt btd-Amt % Purity In i Uo1 Katiol.U2U4t+U3 U.UUUUt+UU 1.UUUUt+UU 1UU.UUU l.UUU

Kun btatus : KunbtatusUKtndUf fBasel me

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BUM LABUKAIUKltb Keport - btNlt Medium Area horm

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bl l/.Ub .14yu *3b2UU U.UUUUt+UUb2 I/.22 .14/8 1/1/UUU U.UUUUt+UUb3 l/.4b .2*/l 48438UU U.UUUUt+UUb4 18.Ul .26b4 lb6*4UU U.UUUUt+UUbb 18.-'2 .4682 414U8UU U . UU M Ut + U Ubo l*.2b #l*.2b .1448 21//*BPU 3.213*t-Ul Huffi L LI.. * o . -UU-A fdeb/ l*./b .3U*4 IbbUUUB U.UUUUt+UU _____b8 2U.bB #2U.6U . 136/ 22U3UU 2.8U21t-U3 ^glU Ul. i u i UBneby 2U.*2 #2U.By . 16iy 3814PU *.3866t-U3 4,-?+ - - Uh.6U 21.3/ .13U3 *8/4PU U.UUUUt+UU61 ,22.J.y _ .2/V/ 2/64BU U.UUUUt + UU .___ OOOO2?62" "21_'/4*.?rf . 182b 2113UU U.UUUUt+UU ^ VUUUiC*

"SR305523

BUM LABUKAIUKltb Keport - UtNlt Medium Area horm

Sample Name : 13U414 6U8 *aUML-!UML W1UU/ Keport No : B/.UUMIH hUK ULP Ptblb/PUBb UN AUU-14 Page 3Pk# Kl ID-tm PeakWidth Area Uode AMUUNI Name63 23. bl .1*63 2*36UU U.UUUUt + UJJ64 24.32 #24.31 .1418 811*UU 2.1*86t-U2 4y'i ' UU I6b 24.b6 .132b 3b*4/UU U.UUUUt+UU66 2b.41 #2b.4/ . 2b43 *28yUU l./b6Ut-U2 Lnndi ill J 1LJU i.,uu6/ 2b.au .2U62 1231UUU U.UUUUt+UU6B 26.22 #26.26 .182* 43*bllUU 4.U//6t+UU Lndu^LI 1 . Jli ju-ifate & ./6* 26.bb #26.6/ . 2b6b bU311bUU /.*6bUt-Ul L) ibu t y 1 ch 1 orendate «*° /,»/U 28.2* .41U4 1*468UU U.UUUUt+UU/I 2*.*1 .2214 36182PB U.UUUUt+UU/2 32.42 .2*6* 121**UU U.UUUUt+UU/3 33.48 .•?l?22 //1UPU U.UUUUt+UU/4 34.U3 .38*3 64/bUU U.UUUUt+UU/b 34.88 .623U 12U234UU U.UUUUt+UU/6 /'B.b6 .bb*2 6434UB~ U.UUUUt+UU

l o t a l Area : 223823/6 lotal AMUUNI : 6.2B1

Keport l i m e : lue Uct lb, 1**1 y:UU:2* pmMethod : /DA IA/tXIKAUIb/MtIHUU/MIHULP 1U14*1 14.MIH

000023

BUM LABUKAIUKltb Keport - UtN 1 t Medium Area horm

bampie Name : 13U414 6UB yBUML-lUML W1UU/ Keport No : 'd/.UUMIH hUK ULP Ptblb/PUBb UN AUU-14 Page 4

F f - 123L i

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~"~ ""™———— lU./6b

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l -I tndrin aldehyde•_ _ _ tn d o s u J f a n =. u ). f a t e

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f 32.421

L | 33.4/6 000024i i * A 1 1 • j t-,1 f _•' -t . U __

AR305525

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET ____ _____

Name: BCM Contract:130419


Matrix: (soil/water) WATER Lab Sample ID: 130419

Sample wt/vol: 980. (g/mL)ML Lab File ID: N1014216Level: (low/med) LOW Date Received: 9/24/91% Moisture: not dec. 100. dec. 0. Date Extracted: 9/30/91Extraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 10/15/91 . .

'HO fa IGPC Cleanup: (Y/N) N pH: .0 Dilution Factor: 1.00


319-84-6 ———— alpha-BHC319-85-7 ———— bet a-BHC319-86-8 ———— delta-BHC58-89-9' —— • — gamma-BHC (Lindane)76-44-8 ———— Heptachlor309-00-2 ———— Aldrin1024-57-3 ———— Heptachlor epoxide959-98-8 ———— Endosulfan I60-57-1 ——— Dieldrin72-55-9 ————— 4 , 4 ' -DDE72-20-8 ———Endrin

33213-65-9 ———— Endosulfan II72-54-8 ———— 4 , 4 ' -ODD

1031-07-8 ——— Endosulfan sulfate50-29-3 —— —4 , 4 ' -DDT72-43 -5 —— — Methoxychlor

53494-70-5 —— • — Endrin ketone5103-71-9 ———— alpha-Chlordane5103-74-2 ——— gamma-Chlordane8001-35-2 ——— Toxaphene12674-11-2 ——— Aroclor-101611104-28-2 ———— Aroclor-122111141-16-5 ———— Aroclor-123253469-21-9 ———— Aroclor-124212672-29-6 —— — Aroclor-124811097-69-1 ———— Aroclor-125411096-82-5 ———— Aroclor-1260

.051

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000025SR305526

i !L iI •! 3*.U86

BUM LABUKAIUKltb Keport - UtN1t Medium Area horm

bampie Name : 13U4iy 6UB *8UML-1UML W1UU/ Keport rio : B*.U1MIH hUK ULP Ptblb/PUBb UN ALJU-13 Paqe 1UULUMN UB6U8 3UM X U.b43 MM U.83 UM hILM 1U#U331222,1NJ I 2bUL'AKKltK P-b At bPbl, I U I AL hLUW -/UML/MIN tUU 3UUU KANbit Ulul INJtUllUN IbUU, Imin bU/min, 2/bU 14M1N

Book/Page :

Peak Processor : Lienie Multilevel : halse


Ualculation : txternalblU ljuant i tat ion : AreaUnits

Pesult h i l e : /DA I A/tX I KAU 1 b/Ktb'UL I/N1U14216 . Ktb

Kun l i m e : 4U.U2 Minutes Iniected on Iue Uct Ib , 1**1 8:46:43 pm

bequence hile: /UA I A/tX I KAU I b/btUUtNUt/btLJULP lUlb*l 13.btL|


threshold Min-Ar Pkwidth Kh Unknown2.U l.UUUUt+U3 .U4U U.UUUt+UU

Kef Wdw Abs Kef-KIW Non Wef Win Abs Non Kef-KIW Ident LevelU.UU l.bU U.UU l.bU 1UUU.UU

•4 Uii-hact bmp-Amt btd-Amt % Purity Ini Uo 1 Katioi.U2U4t+U3 U.UUUUt+UU 1.UUUUt+UU 1UU.UUU l.UUU

Kun btatus : KunbtatusUK

limed tvents lime tvents Logic Ualue tventUpdate1 U.UU NegativePeaks tventUrf -l.UU halse2 .1U KesetBLAl lUa1 ley tventUn -l.UU halse

Pk# Kl ID-tm PeakWidth Area Uode AMUUNI Name1 1.32 #1.32 .U*bb B38U11BB 2.b/44t-Ub bULUtNI hKUNI2 1./6 .U441 2/b/4BB U.UUUUt+UU3 1.B4 .Ub34 1/lbBBB U.UUUUt+UU4 l.*8 . U282 12bbBB U.UUUUt+UUb 2.Uy .U618 43/U6BB U.UUUUt+UU6 2.44 .Uby4 18/3UBB U.UUUUt+UU

3.43 .U*26 168*BB U.UUUUt+UU8 3./* .U/42 211/BB U.UUUUt+UU* 3.*8 .U83/ 4U*UBB U.UUUUt+UU

1U 4.28 .14/3 3b43BB U.UUUUt+UU11 b./U .U*ll 13U1BB U.UUUUt+UU12 b.*1? .1214 3bUUbBB U.UUUUt + UU13 6.bl .lb3U 2b28BB U.UUUUt+UU14 6.88 .1441 1*U8BB U.UUUUt + UU 000026Ib /.2/ .1313 6*64IJBB U.UUUUt+UU16 /.*b . 1/U* 26/UBB U.UUUUt + UU1 ••' B - 6b . 1/4> 1 U U2Bc U . U U !j Ut + U U

BUM LABUKAIUKltb Keport - UtNlt Medium Area harm

Sample Name : 13U41* 6U8 *8UML-1UML M1UU/ Keport No : y*.UlMIH NJK ULP Ptblb/PUBb UN AUU-13 Page 2Pk# PI lU-trn PeakWidth Area Uc-de AMUUN! Name18 *.46 .1664 2BB8BB U.UUUUt+UU1* lU.Ub #1U.U4 .11*3 431*32BB B.U12Ut-Ul 2,4,b,6-ItIKAUHLUKU-m-XYLt2U 1U.*2 .114* 1142BB U.UUUUt+UU21 11./* .136/ 4*4*BB U.UUUUt+UU22 12.34 .1U81 llblBB U.UUUUt+UU23 12.66 .2U/2 1221BB U.UUUUt+UU24 13.28 .1/ba 14U/BB U.UUUUt+UU2b 14.36 .163* 1U46BB U.UUUUt+UU26 Ib./a .11744 1846 UBB U.UUUUt+UU2/ 16.3* .12U1 18U6BB U.UUUUt+UU28 1/.6U .12/2 163U1BB U.UUUUt+UU2* 21.I/ .4324 36/1BB U.UUUUt+UUJiU 24.34 .18UU 1834BB U.UUUUt + UU_'1 24. B2 .-14** bU22BB U.UUUUt+UU32 2b.2b . U*3* 2*8bBB U.UUUUt + UUJO 2b.4J- .1U24 b*13BB U.UUUUt+UU34 26.U6 .Ilb2 1*16BB U.UUUUt+UU3b 26.61 .lbU4 123424BB U.UUUUt+UU36 2/.Ub .14/6 l/bU8BB U.UUUUt+UU3/ 28.13 #28.11 .1662 312423BB /.8662t-Ul Ulbuty1ch1orendate

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lotal Area : 212U3U2 lotal AMUUMI : l.bBB

Keport l i m e : Wed Uct 16, 1**1 .12:21:44 pmMethod : /UA I A/tX. I KAU I b/Mt 1 HUU/M I HULK lUlb*l 13.MIH

000027

BUM LABUKAIUKltb Keport - LJtN 11 Medium Area horm

bampie Name : 13U41* 6UB *BUML-1UML W1UU/ Keport No : 8*.U1MIH hUK ULP Ptblb/PUBb UN AUU-13 ' Paqe 3

f !L i

! [' 2 ,4,b ,6- I t IKAUHLUKU-m-XYLtNtM 1U.*21hf ll./ya

i j 13.2/6h!j j 14. 3b8

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h I. 2y.8aUL I/ 3U.628 :

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(• '1r 000028

AR305529

h!

iri

BUM LABUKAIUKltb Keport - U-tN 11 Medium Area horm

bampie Name : 13U4iy 6UB *8UML-1UML W1UU/ Keport No : 8*.UUMIH hUK ULP Ptblb/PUBb UN AUU-14 Page 1UULUMN UB1/1J1 3UM X U.b3MM 1UM hlLM 1 U# U4*3Ub2 1NJ I 2bUUP-b -bML/MIN MAbb hLUW MAKt UP P-b h UK I UI AL Uh -/'UML/M1NtUU 3UUU, KANbt U, lul INJtUllUN IbUU, Imin bU/min, 2/bU

Book/Page :

Peak Processor : benie Multilevel : halse


Ualculation : txternalblU Lluan t 11 a t ion : AreaUnits

Kesult h i l e : /UftIA/tXIKAUIb/KtbUL1/U1U14216.Ktb

Kun lime : 4U.U2 Minutes iniected on lue Uct Ib, 1**1 8:46:43 pm

bequence h i le : /DA IA/tXIKAUIb/btUUtNUt/btUULP lUlb*l 14.btU

bubseq/bample: 1/16 Bottle no. : 66

reshold Min-Ar Pkwidth Kh Unknownb.U 2.UUULIt+U3 . .16U U.UUUt+UU

Kef Uldw Abs Kef-KIW Non Kef Win Abs Non Kef-KIW Ident LevelU.UU 1.b U U.UU l.bU 1UUU.UU

% Uii-hact bmp-Amt btd-Arnt % Purity Ini Uo 1 Katiol.U2U4t+U3 U.UUUUt+UU 1.UUUUt+UU 1UU.UUU l.UUU

Kun btatus : KunbtatusUK

l i m e d tvents lime tvents Logic Ualue tventUpdate1 U.UU KesetBLAtUalley tventUn -l.UU halse2 U.UU NegativePeaks tventUff -l.UU halse3 b.UU KesetBLAtUa1 ley tventUn -l.UU halse4 1U.UU KesetBLAtUa1 ley tventUn -l.UU halse

. b Ib.UU KesetBLAtUa1 ley tventUn -l.UU halse6 2U.UU KesetBLAtUalley tventUn -l.UU halse/ 2b.UU KesetBLAtUa1 ley tventUn -l.UU halse:-' 3 U . U U H ? 3 e t bLP. t' .'a 1 i e y t ve n t Ur,

Pk# Kl lU-tm PeakWidth Area Uode AMUUNI Name1 .12 .2bl* 2/41BB U.UUUUt+UU2 1.62 .143* 186bU*3Bb U.UUUUt+UU3 l.*3 .Ub4* 2U4U2BI U.UUUUt+UU4 2.3U .U/48 /6/*/BI U.UUUUt+UUb 2.43 .U8b2 /31//UI U.UUUUt+UU6 2.61 . UV34 //b4/UI U.UUUUt+UU/ 2.88 .U8*6 1366/P1 U.UUUUt+UUB 2.*/ .U616 b/U*UI U.UUUUt + UU 000079'-> .^.U* . U63b 22644PI U.UUUUt+UU "

j.1!.-""' ~ y~ M •*•'»t r» . 'J 6 2 Li vJ> 2 >' Pi u-uouL i t + UU11 3.3* .U/U6 23b4PI U.UUUUt+UU

rif v/x^«_r

BUM LABUKAIUKltb Keport - UtN1t Medium Area harm

bampie Name : 13U41* 6UB *8UML-1UML U1UU/ Keport No : 8*.UUMIH hUK ULP Ptblb/PUBb UN AUU-14 Page 2PMt= Kl lU-tm PeakWidth Area Uode AMUUN I Name12 4./I .1U12 4b**UI U.UUUUt+UU13 b.13 .U8b/ 642/PI U.UUUUt+UU14 b.38 .U*yi 2/48BU U.UUUUt+UUI1? b.*b .1464 b/*2PU U.UUUUt + UU !16 6.12 .Ibl/ 4341UU U.UUUUt+UUI/ 6.48 .183* 2U1UUU U.UUUUt+UU18 6./3 .1343 317/2UU U.UUUUt + UU !1^ 6.*8 .264b 4424UU U.UUUUt+UU2U /.6b .bUb/ 1U/14UU U.UUUUt+UU21 /.*8 .2436 4Ub3UU U.UUUUt+UU'•^ 8.24 .1114 b884UUU U.UUUUt+UU^ 8.63 .18*U 38/BUU U.UUUUt+UU'•4 B.*6 .23** 2138UU U.UUUUt + UU2b *./U #y.82 .1132 b23148PB 8.3166t-Ul 2 ,4 , b ,, 6- I 11 KAUHLUKU-m-XYLt!26 lU.yb . 14yiJ 2UU4PU U.UUUUt+UU'*/ 11.22 .lUiy 2233PU U.UUUUt+UU28 11.41 .11/U 62*2UU U.UUUUt+UU2* 12./3 .162U /62/UU U.UUUUt+UU3U 14.2* .111* 2/68UU U.UUUUt+UU31 117.10 .1124 ///2PB U.UUUUt+UU32 lb.6U .13y3 21*4BU U.UUUUt+UU33 I/.42 .26b3 218/4PU U.UUUUt+UU34 18.6/ .448b /1U/UU U.UUUUt+UU3b 22.U8 .3223 26b*UU U.UUUUt+UU36 24.2* #24.31 .Ib83 bbU6PU 1.4*llt-U23/ 24.b3 .142/ !U84bUU U.UUUUt+UU38 2b./* .1*/U b26*BU U.UUUUt+UU3* 26.1* .2U/3 66*42UU U.UUUUt+UU4U 26.b3 #26.6/ .2b8U 4/6132UU /.b3/8t-Ul Uibuty1ch1orendate41 28.3U .316* *163UU U.UUUUt+UU42 34.U8 .bUb6 b/4UUU U.UUUUt+UU**3 34.3>o .4/b3 36/2UB U.UUUUt+UU

l o t a l Area : 3448146 lotal AMUUNI : 1.6UU

Heport l i m e : lue Uct Ib, 1**1 *:28:U1 pmMethod : /UAIA/tXIKAU1b/Mt1HUU/MIHULP 1U14*1 14.M1H

000030SR30553!


Sample Name : 13U41* 6U8 *8UML-1UML W1UU/ Keport No : 8*.UUMIH hUK ULP Ptbib/PUBb UN AUU-14 Paqe 3

1.616

h V———————— __—— ———2 .. 4 . b . 6 - 111 KAUHLUKU- m- XYLtNt

r iI f

i- r 12./3U

14.2*1lb.181

L f ib.b**I JL j1 i' 1 /. 42 Ur iL. f 18.6/4i ii i.h ii jF i 22.U/6L i

ijibutv Ich lo rendate"

L ;Jj j 2b.2**!" !i ir j

L 1 000031! 1 :.y-<* ...... ---.=- AR305532

BCM

Standards Data

000032AR305533

8DPESTICIDE EVALUATION STANDARDS SUMMARY

Name: BCM Contract:

Lab Code: BCM Case No.: /0// SAS No.: SDG No.:Instrument ID: 0013 GC Column ID: DB608Dates of Analyses: 10/14/91 to 10/16/91

Evaluation Check for Linearity

PESTICIDE

AldrinEndrin4, 4 '-DDTDBC

CALIBRATIONFACTOREVAL MIX A

13148800.7232300.6836300.14384560.

CALIBRATIONFACTOREVAL MIX B

13029400.6642800.7108900.14568850.

CALIBRATIONFACTOREVAL MIX C

14504300.7000500.8491050.15694880.

%RSD(</-10.0%)

6.04.311.94.8

(1) If > 10.0% RSD, plot a standard curve and determine the ngfor each sample in that set from the curve.

Evaluation Check for 4,4'-DDT/Endrin Breakdown(percent breakdown expressed as total degradation)

1234567891011121314

INITIALEVAL MIX BEVAL MIX BEVAL MIX B

DATEANALYZED

10/14/9110/15/9110/15/91

TIME .ANALYZED

10:053:3517:52

ENDRIN

28.9724.48.00

4 , 4 ' -DDT

9.489.10.00

COMBINED__ (2}__

16.7614.84.00

(2) See Form instructions.

(D

FORM VIII PEST-1 1/87 Rev.

00003

8EPESTICIDE EVALUATION STANDARDS SUMMARY

Evaluation of Retention Time Shift for DibutylchlorendateLab Name: BCM Contract:

Lab Code: BCM Case No.: l^i^f SAS No.: SDG No.:Instrument ID: 0013 GC Column ID: DB608Dates of Analyses: 10/14/91 to 10/16/91

* Values outside of QC limits (2.0% for packed columns,0.3% for capillary columns)

page I of 2

1234567891011121314151617181920212223242526272829303132333435363738

EPASAMPLE NO.

EVALAEVALBEVALCINDAINDBTOXAPHEAR1016AR1221AR1232AR1242AR1248AR1254AR1260DDTMIX1DDTMIX2DDTMIX3129833'29821MSI29821MSDMS PIKE(29821EVALB129826129815129818128828I29273MSINDA2/29273MSD129275130422/30414MSI30414MSDEVALBMSPIKE/30414130419INDB2

LAB SAMPLEID

129833MB129835S129834DMSPIKE129821

129826129815129818128828129282S

129281D129275130422MB130424S130423D

MSPIKE130414130419

DATEANALYZED

10/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/16/91

TIMEANALYZED

9:2110:0510:4811:3112:1514:4015:2316:0616:4917:3318:1619:0019:4321:0921:5222:350:010:441:272:102:523:354:185:015:446:279:5211:5812:4914:1615:4316:2617:0917:5218:3619:1920:460:20

%D

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

.4

.01.5.8.1.1.0.1.0.0.0.0

*

*

TTTTT Bwo'T'-.T 1/C7

000034flR305535


Evaluation of Retention Time Shift for Dibutylchlorendate

L^a :Name: BCM Contract:Code: BCM Case No.: l\^\c\} SAS No.: SDG No.:

Instrument ID: 0013 GC Column ID: DB608

Dates of Analyses: 10/14/91 to 10/16/91

1234567891011121314151617181920212223242526272829303132333435363738

EPASAMPLE NO.

APP9PES129818 REINDA3INDB3

LAB SAMPLEID

129818

DATEANALYZED

10/16/9110/16/9110/16/9110/16/91

TIMEANALYZED

1:032:293:554:37

%D

.0

.0

.0

.0

.

*


page 2 of 2POT?M T7TTT T3TCT-O T /_7 P.9V.

000035

8DPESTICIDE EVALUATION STANDARDS SUMMARY

Lab Name: BCM Contract:Lab Code: BCM Case No.:A-3)G/ SAS No.: SDG No.:

Instrument ID: 0014 GC Column ID: DB1701Dates of Analyses: 10/14/91 to 10/16/91

Evaluation Check for Linearity

PESTICIDE

AldrinEndrin4, 4 '-DDTDBC

CALIBRATIONFACTOREVAL MIX A

16013600.13628800.9288500.20398460.

CALIBRATIONFACTOREVAL MIX B

17045100.13629400.8859350.20038710.

CALIBRATIONFACTOREVAL MIX C

19286050.14853430.10525830.20562640.

%RSD(</-10.0%)

9.65.09.11.3

(1) If > 10.0% RSD, plot a standard curve and determine the ngfor each sample in that set from the curve.

Evaluation Check for 4,4'-DDT/Endrin Breakdown(percent breakdown expressed as total degradation)

1234567891011121314

INITIALEVAL MIX BEVAL MIX BEVAL MIX B

DATEANALYZED

10/14/9110/15/9110/15/91

TIMEANALYZED

10:053:3517:52

ENDRIN

.0010.8116.25

4,4' -DDT

.00

.001.98

COMBINED(2)

.005.279.11

(2) See Form instructions.

(D

FORM VIII PEST-1 1/87 Re

00003fR3 05537


Evaluation of Retention Time Shift for DibutylchlorendateName: BCM Contract:

Code: BCM Case No.: 6 ff\ \ SAS No"* SDG No.:

Instrument ID: 0014 GC Column ID: DB1701Dates of Analyses: 10/14/91 to 10/16/91

1234567891011121314151617181920212223242526272829303132333435363738

EPASAMPLE NO.

EVALAEVALBEVALCINDAINDBTOXAPHEAR1016AR1221AR1232AR1242AR1248AR1254AR1260DDTMIX1DDTMIX2DDTMIX3129833I29821MS\29821MSDMSPIKE129821EVALB129826129815129818128828I29273MSINDA2I29273MSD129275130422I30414MS<30414MSDEVALBMSPIKE130414130419INDB2

LAB SAMPLEID

129833MB129835S129834DMSPIKE129821

129826129815129818128828129282S

129281D129275130422MB130424S130423D

MSPIKE130414130419

DATEANALYZED

10/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/14/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/15/9110/16/91

TIMEANALYZED

9:2110:0510:4811:3112:1514:4015:2316:0616:4917:3318:1619:0019:4321:0921:5222:350:010:441:272:102:523:354:185:015:446:279:5211:5812:4914:1615:4316:2617:0917:5218:3619:1920:460:20

%D

.0

.0

.0

.1

.2

.2

.3

.3

.1

.0

.1

.1

.1

.3

.3

.4

.4

.4

.4

.4

.4

.4

.4

.2

.2

.5

.6

.3

.81.3.4.4.4.4.6.5.6.7

*


1 of 2FORM VTTT PT?qnn_-7 1/2? P.:

000037AR3G5538


Evaluation of Retention Time Shift for Dibutylchlorendate

Lab Name: BCM Contract:Lab Code: BCM Case No.: TnA SAS No.: SDG No.:

Instrument ID: 0014 GC Column ID: DB1701

Dates of Analyses: 10/14/91 to 10/16/91

1234567891011121314It161718192021?.2.?A25267.7287.9303137.333435363738

EPASAMPLE NO.

APP9PES129818 REINDA3INDB3

-

LAB SAMPLEID

129318

-

DATEANALYZED

10/16/9110/16/9110/16/9110/16/91

TIMEANALYZED

1:032:293:554:37

%D

.7

.0

.6

.7

i ~

,. .

*

V1

«•£f-

* Values outside . " ?c limits (2.0% for packed0.3% for . liar, , jlu~..ns)

page 2 of 2FORM VIII PEST-2

AR3Q5539

9PESTICIDE/PCB STANDARDS SUMMARY

Name: BCM Contract:

Code: BCM Case No.:^j^|Hi SAS No.: SDG No.:Instrument ID: 0013 . GC Column ID: DB608

COMPOUND

alpha-BHCbeta-BHCdelta-BHC _gamma-BHC (LiHeptachlor __AldrinKept . EpoxideEndosulfan IDieldrin4,4' -DDE

, EndrinEndosulfan II^ '-DDD•_o. sulfatePT'-DDT

, Methoxychlor_Endrin ketonea. Chlordaneg. ChlordaneToxaphene __Aroclor-1016Aroclor-1221Aroclor-1232Aroclor-1242Aroclor-1248Aroclor-1254Aroclor-1260

DATE(S) OF FROM: 10/14/91ANALYSIS TO: 10/14/91TIME(S) OF FROM: 11:31ANALYS IS TO : 'fll.32 JJ ; '*£~

p*lk. IllrSt '

RT

13.1315.1616.77 i14.8716.2917.7320.1221.6222.9122.4824.4425.1724.7727.0326.0030.2331.2121.4820.8025.2315.7112.9416.3416.3419.6222.7425.04

JWI*

FROM

13.0015.0116.6014.7216.1317.5519.9221.4122.6822.2624.2024.9124.5226.7625.7429.9230.9021.2620.5925.2315.5512.8116.3416.1819.4222.5125.04

ITIDOW

TO

13.2615.3116.9415.0216.4517.9120.3321.8423.1422.7124.6925.4225.0127.3126.2630.5331.5221.6921.0125.2315.8713.0716.3416.5019.8222.9725.04

CALIBRATIONFACTOR

4591200.3088600.3835750.4157800.6193000.5070850.5600650.5675400.4620200.4001200.2359550.4349375.2726175.4941700.2517450.2077800.4498100.5939950.6017000.178908.1057026.314666.605504.902342.785372.1197810.1448092.

DATE OF ANALYSIS 10/15/91TIME OF ANALYSIS 11:58EPA SAMPLE NO.(STANDARD) INDA2

RT

14.8916.3117.7520.1421.6422.93

25.18

26.0230.25

CALIBRATIONFACTOR

4277900.6374500.5180950.5497450.5580200.4586750.

4277775.

2714650.2324145.

QNTY/N

YYYYYYYYYYYYYYYYYYYYYYYYYYY

%D

2.9.3

2.21.81.7.7.

1.6

77811.9

Jnder QNT Y/N: enter Y if quantitation was performed, N if not performed.ID must be less than or equal to 15.0% for quantitation, and less thanor equal to 20.0% for confirmation.Note: Determining that no compounds were found above the CRQL is a form ofquantitation, and therefore at least one column must meet the 15.0% criteria.For multicomponent analytes, the largest single peak that is characteristicof the component should be used to establish retention time and %D.Identification of such analytes is based primarily on pattern recognition.page 1 of 5

FORM IX PEST 1/87 Rev.

000033


Lab Name: BCM Contract:Lab Code: BCM Case No.: 4,-5/Q/ SAS No.: SDG No.:Instrument ID: 0013 • GC Column ID: DB608

COMPOUND

alpha-BHCbeta-BHCdelta-BHC _gamma-BHC (LiHeptachlorAldrinHept . EpoxideEndosulfan IDieldrin4,4' -DDEEndrinEndosulfan II4,4' -ODDEndo. sulfate4,4' -DDTMethoxychlorEndrin ketonea . Chlordaneg. ChlordaneToxapheneAroclor-1016Aroclor-1221Aroclor-1232Aroclor-1242Aroclor-1248Aroclor-1254Aroclor-1260

DATE(S) OF FROM: 10/14/91ANALYSIS TO: 10/14/91TIME(S) OF FROM: 11:31ANALYSIS TO: •»•" 'KJ

—&/ *g~ fZfk,,//sh,

RT

13.1315.1616.7714.8716.2917.7320.1221.6222.9122.4824.4425.1724.7727.0326.0030.2331.2121.4820.8025.2315.7112.9416.3416.3419.6222.7425.04

fWIli

FROM

13.0015.0116.6014.7216.1317.5519.9221.4122.6822.2624.2024.9124.5226.7625.7429.9230.9021.2620.5925.2315.5512.8116.3416.1819.4222.5125.04

ITIDOW

TO

13.2615.3116.9415.0216.4517.9120.3321.8423.1422.7124.6925.4225.0127.3126.2630.5331.5221.6921.0125.2315.8713.0716.3416.5019.8222.9725.04

CALIBRATIONFACTOR

4591200.3088600.3835750.4157800.6393000.5070850.5600650.5675400.4620200.4001200.2359550.4349375.2726175.4941700.2517450.2077800.4498100.5939950.6017000.178908.1057026.314666.605504.902342.785372.1197810.1448092.

DATE OF ANALYSIS 10/16/91TIME OF ANALYSIS 0:20EPA SAMPLE NO.(STANDARD) INDB2

RT

13.1315.1716.78

17.74

22.4924.45

24.7827.04

31.2321.4920.81

CALIBRATIONFACTOR

4868300.3232800.4064300.

5704750.

4233850.2664450.

2877325.4975875.

4476400.6078200.6017100.

QNTY/N


%D

6.04.76.0

12.5

5.812.9

_3.5

2.3.0

Under QNT Y/N: enter Y if quantitation was performed, N if not performed.%D must be less than or equal to 15.0% for quantitation, and less thanor equal to 20.0% for confirmation.Note: Determining that no compounds were found above the CRQL is a form ofquantitation, and therefore at least one column must meet the 15.0% criteria,

For multicomponent analytes, the largest single peak that is characteristicof the component should be used to establish retention time and %D.Identification of such analytes is based primarily on pattern recognition.page 2 of 5

FORM IX PEST 1/87 Re


Name: BCM Contract: _Code: BCM Case No.: 4J Hf SAS No.: SDG No.:

Instrument ID: 0013 . GC Column ID: DB608

COMPOUND

alpha-BHCbeta-BHCdelta-BHCgamma-BHC (LiHeptachlorAldrinHept . EpoxideEndosulfan IDieldrin4,4' -DDEEndrinEndosulfan IIK'-DDD

o. sulfate'-DDT

MethoxychlbrEndrin ketonea . Chlordaneg. ChlordaneToxapheneAroclor-1016Aroclor-1221Aroclor-1232Aroclor-1242Aroclor-1248Aroclor-1254Aroclor-1260

DATE(S) OF FROM: 10/14/91ANALYSIS TO: 10/14/91TIME(S) OF FROM: 11:31ANALYSIS TO: 3HB£

J33/J& PVk.nl/is/-n

RT

13.1315.1616.7714.8716.2917.7320.1221.6222.9122.4824.4425.1724.7727.0326.0030.2331.2121.4820.8025.2315.7112.9416.3416.3419.6222.7425.04

fWIL

FROM

13.0015.0116.6014.7216.1317.5519.9221.4122.6822.2624.2024.9124.5226.7625.7429.9230.9021.2620.5925.2315.5512.8116.3416.1819.4222.5125.04

ITroowTO

13.2615.3116.9415.0216.4517.9120.3321.8423.1422.7124.6925.4225.0127.3126.2630.5331.5221.6921.0125.2315.8713.0716.3416.5019.8222.9725.04

CALIBRATIONFACTOR

4591200.3088600.3835750.4157800.6393000.5070850.5600650.5675400.4620200.4001200.

' 2359550.4349375.2726175.4941700.2517450.2077800.4498100.5939950.6017000.178908.1057026.314666.605504.902342.785372.1197810.1448092.

DATE OF ANALYSIS 10/16/91TIME OF ANALYSIS 1:03EPA SAMPLE NO.(STANDARD) APP9PES

RT CALIBRATIONFACTOR

QNTY/N


%D

Under QNT Y/N: enter Y if quantitation was performed, N if not performed.ID must be less than or equal to 15.0% for quantitation, and less thanor equal to 20.0% for confirmation.Note: Determining that no compounds were found above the CRQL is a form ofquantitation, and therefore at least one column must meet the 15.0% criteria.

For multicomponent analytes, the largest single peak that is characteristicof the component should be used to establish retention time and %D.Identification of such analytes is based primarily on pattern recognition.

page 3 of 5FORM IX PEST 1/87 Rev.

000041


Lab Name: BCM Contract: O

Lab Code: BCM Case No.: f3/ // SAS No-: SDG No*:Instrument ID: 0013 . GC Column ID: DB608

COMPOUND

alpha-BHCbeta-BHCdelta-BHC _gamma-BHC (LiHeptachlorAldrinHept . EpoxideEndosulfan !__Dieldrin4,4' -DDEEndrinEndosulfan II4,4' -ODDEndo. sulfate4,4' -DDTMethoxychlor__Endrin ketonea . Chlordaneg. ChlordaneToxapheneAroclor-1016Aroclor-1221Aroclor-1232Aroclor-1242Aroclor-1248Aroclor-1254Aroclor-1260

DATE(S) OF FROM: 10/14/91ANALYSIS TO: 10/14/91TIME(S) OF FROM: 11:31ANALYSIS TO: 2H52 J*:jf

fttt iil«hiRT

13.1315.1616.7714.8716.2917.7320.1221.6222.9122.4824.4425.1724.7727.0326.0030.2331.2121.4820.8025.2315.7112.9416.3416.3419.6222.7425.04

EWIN

FROM

13.0015.0116.6014.7216.1317.5519.9221.4122.6822.2624.2024.9124.5226.7625.7429.9230.9021.2620.5925.2315.5512.8116.3416.1819.4222.5125.04

.Troow

TO

13.2615.3116.9415.0216.4517.9120.3321.8423.1422.7124.6925.4225.0127.3126.2630.5331.5221.6921.0125.2315.8713.0716.3416.5019.8222.9725.04

CALIBRATIONFACTOR

4591200.3088600.3835750.4157800.6393000.5070850.5600650.5675400.4620200.4001200.2359550.4349375.2726175.4941700.2517450.2077800.4498100.5939950.6017000.178908.1057026.314666.605504.902342.785372.1197810.1448092.


RT

14.8716.2917.7320.1321.6222.91

25.17

26.0130.23

CALIBRATIONFACTOR

4448500.6461600.5356500.5775700.5833650.4822850.

4479325.

2635050.2077245.

QNTY/N


%D

7.01.15.63.12.84.4

3.o|

——— j47.0

————

Under QNT Y/N: enter Y if quantitation was performed, N if not performed.%D must be less than or equal to 15.0% for quantitation, and less thanor equal to 20.0% for confirmation.Note: Determining that no compounds were found above the CRQL is a form ofquantitation, and therefore at least one column must meet the 15.0% criteria.


page 4 of 5FORM IX PEST 1/87 Re

OOOWB055U3


Name: BCM Contract:Code: BCM Case Uo.i^r^)I II SAS No.: SDG No.

I \s * i j

Instrument ID: 0013 . GC Column ID: DB608

COMPOUND

alpha-BHCbeta-BHCdelta-BHC _gamma-BHC (LiHeptachlorAldrinHept. EpoxideEndosulfan IDieldrin4, 4 '-DDEEndrinEndosulfan IIU 4'-DDD•LO. sulfate•1 ' -DDTMethoxy chl orEndrin ketonea. Chlordaneg. ChlordaneToxapheneAroclor-1016Aroclor-1221Aroclor-1232Aroclor-1242Aroclor-1248Aroclor-1254Aroclor-1260

DATE(S) OF FROM: 10/14/91ANALYSIS TO: 10/14/91TIME(S) OF FROM: 11:31ANALYSIS TO: 21 : S3- j.-~

t&(£tl//sfy

RT

13.1315.1616.7714.8716.2917.7320.1221.6222.9122.4824.4425.1724.7727.0326.0030.2331.2121.4820.8025.2315.7112.9416.3416.3419.6222.7425.04

IWII

FROM

13.0015.0116.6014.7216.1317.5519.9221.4122.6822.2624.2024.9124.5226.7625.7429.9230.9021.2620.5925.2315.5512.8116.3416.1819.4222.5125.04

ITIDOW

TO

13.2615.3116.9415.0216.4517.9120.3321.8423.1422.7124.6925.4225.0127.3126.2630.5331.5221.6921.0125.2315.8713.0716.3416.5019.8222.9725.04

[Jnder QNT Y/N: enter Y if quantitat%D must be less than or equal to 15or equal to 20.0% for confirmation.

CALIBRATIONFACTOR

4591200.3088600.3835750.4157800.6393000.5070850.5600650.5675400.4620200.4001200.2359550.4349375.2726175.4941700.2517450.2077800.4498100.5939950.6017000.178908.1057026.314666.605504.902342.785372.1197810.1448092.


RT

13.1315.1616.77

17.73

22.4824.45

24.7727.04

31.2221.4820.80

CALIBRATIONFACTOR

5037700.3367300.4222000.

5701900.

4371350.2831750.

3007550.5212625.

4808000.6335100.6303450.

QNTY/N


%D

9.79.010.1

12.4

9.320.0

10.35.5

6.96.74.8

ion was performed, N if not performed.. 0% for quantitation, and less than

Note: Determining that no compounds were found above the CRQL is a form ofquantitation, and therefore at least one column must meet the 15.0% criteria.For multicomponent analytes, the largest single peak that is characteristicof the component should be used to establish retention time and %D.Identification of such analytes is based primarily on pattern recognition.




Lab Code: BCM Case No.: </3/0"') / SAS No-: SDG No-:Instrument ID: 0014 GC Column ID: DB1701

COMPOUND

alpha-BHCbeta-BHCdelta-BHC __gamma-BHC (LiHeptachlor _____AldrinKept . EpoxideEndosulfan IDieldrin4,4' -DDE ____EndrinEndosulfan II4,4' -ODDEndo. sulfate4,4' -DDTMethoxychlor_Endrin ketonea. Chlordaneg. ChlordaneToxapheneAroclor-1016Aroclor-1221Aroclor-1232Aroclor-1242Aroclor-1248Aroclor-1254Aroclor-1260

DATE(S) OF FROM: 10/14/91ANALYSIS TO: 10/14/91TIME(S) OF FROM: 11:31ANALYSIS TO: 22:35

RT

13.3717.6818.6114.9215.7116.7419.2520.2521.5620.8922.2724.0023.7026.2624.3126.3928.1720.6020.4122.0515.3011.8515.3314.3717.5420.8723.77

SWI*

FROM

13.3717.6818.6114.9215.7116.7419.2520.2521.5620.8922.2724.0023.7026.2624.3126.3928.1720.6020.4122.0515.3011.8515.3314.3717.5420.8723.77

ITFDOW

TO

13.3717.6818.6114.9215.7116.7419.2520.2521.5620.8922.2724.0023.7026.2624.3126.3928.1720.6020.4122.0515.3011.8515.3314.3717.5420.8723.77

CALIBRATIONFACTOR

5136400.3692300.4304600.4439900.8362050.6170600.6914900.6937750.5948050.4145550.5116500.4675875.2236000.1099850.3768200.2276305.6775500.8021250.6847250.177096.1336300.352602.658792.732440.1124022.1468016.1818690.


RT

14.8715.6616.7119.2020.1921.51

23.94

24.2526.33

CALIBRATIONFACTOR

4617500.8335900.6788450.6912400.6824750.6129400.

4710775.

4542525.2197930.

Under QNT Y/N: enter Y if quantitation was performed, N if not per%D must be less than or equal to 15.0% for quantitation, and less 1or equal to 20.0% for confirmation.

QNTY/N

N"NNNNNNNNNNNNNNNNNNNNNNNNNN

form*than

%D

4.0.3

10.0.01.63.0

7

=120.3.4

20.

Note: Determining that no compounds were found above the CRQL is a form ofquantitation, and therefore at least one column must meet the 15.0% criteria.For multicomponent analytes, the largest single peak that is characteristicof the component should be used to establish retention time and %D.Identification of such analytes is based primarily on pattern recognition.page 1 of 5

FORM IX PEST 1/87 Rev

00004044^055*45


Name: BCM Contract:

Code: BCM Case No.: \5 j^ | SAS No': SDG No*:Instrument ID: 0014 GC Column ID: DB1701

COMPOUND

alpha-BHCbeta-BHCdelta-BHC _gamma-BHC (LiHeptachlorAldrinHept . EpoxideEndosulfan IDieldrin4.4' -DDEEndrinEndosulfan II4 '-ODD•flo. sulfate•['-DDTHetnoxychlorEndrin ketonea. Chlordaneg. ChlordaneToxapheneAroclor-1016Aroclor-1221Aroclor-1232Aroclor-1242Aroclor-1248Aroclor-1254Aroclor-1260


RT

13.3717.6818.6114.9215.7116.7419.2520.2521.5620.8922.2724.0023.7026.2624.3126.3928.1720.6020.4122.0515.3011.8515.3314.3717.5420.8723.77

IVtTl

FROM

13.3717.6818.6114.9215.7116.7419.2520.2521.5620.8922.2724.0023.7026.2624.3126.3928.1720.6020.4122.0515.3011.8515.3314.3717.5420.8723.77

ITIDOW

TO

13.3717.6818.6114.9215.7116.7419.2520.2521.5620.8922.2724.0023.7026.2624.3126.3928.1720.6020.4122.0515.3011.8515.3314.3717.5420.8723.77

CALIBRATIONFACTOR

5136400.3692300.4304600.4439900.8362050.6170600.6914900.6937750.5948050.4145550.5116500.4675875.2236000.1099850.3768200.2276305.6775500.8021250.6847250.177096.1336300.352602.658792.732440.1124022.1468016.1818690.


RT

13.2417.5518.47

16.60

20.7622.14

23.5726.12

27.9920.4720.28

CALIBRATIONFACTOR

5345500.3697750.4397450.

6470350.

4733550.5442350.

2145250.824300.

6643825.8202800.6835700.

QNTY/N

NNNNNNNNNNNNNNNNNNNNNNNNNNN

%D

4.1.1

2.2

4.9

14.26.4

4.125.1

TT92.3.2

————

————

————Under QNT Y/N: enter Y if quantitation was performed, N if not performed.%D must be less than or equal to 15.0% for quantitation, and less thanor equal to 20.0% for confirmation.Note: Determining that no compounds were found above the CRQL is a form ofquantitation, and therefore at least one column must meet the 15.0% criteria.For multicomponent analytes, the largest single peak that is characteristicof the component should be used to establish retention time and %D.Identification of such analytes is based primarily on pattern recognition.

page 2 of 5FORM IX PEST 1/87 Rev,


Lab Name: BCM Contract

Lab Code: BCM Case No.: \<\\ SAS No.: SDG No.:Instrument ID: 0014 . GC Column ID: DB1701

COMPOUND

alpha-BHCbeta-BHCdelta-BHC _^gamma-BHC (LiHeptachlorAldrinHept . EpoxideEndosulfan IDieldrin4, 4 '-DDEEndrinEndosulfan II4,4' -ODDEndo. sulfate4,4' -DDTMethoxychlorEndrin ketonea. Chlordaneg. ChlordaneToxapheneAroclor-1016Aroclor-1221Aroclor-1232Aroclor-1242Aroclor-1248Aroclor-1254Aroclor-1260


RT

13.3717.6818.6114.9215.7116.7419.2520.2521.5620.8922.2724.0023.7026.2624.3126.3928.1720.6020.4122.0515.3011.8515.3314.3717.5420.8723.77

FWI1<

FROM

13.3717.6818.6114.9215.7116.7419.2520.2521.5620.8922.2724.0023.7026.2624.3126.3928.1720.6020.4122.0515.3011.8515.3314.3717.5420.8723.77

IT[DOW

TO

13.3717.6818.6114.9215.7116.7419.2520.2521.5620.8922.2724.0023.7026.2624.3126.3928.1720.6020.4122.0515.3011.8515.3314.3717.5420.8723.77

CALIBRATIONFACTOR

5136400.3692300.4304600.4439900.8362050.6170600.6914900.6937750.5948050.4145550.5116500.4675875.2236000.1099850.3768200.2276305.6775500.8021250.6847250.177096.1336300.352602.658792.732440.1124022.1468016.1818690.

DATE OF ANALYSIS 10/16/91TIME OF ANALYSIS 1:03EPA SAMPLE NO.(STANDARD) APP9PES

RT CALIBRATIONFACTOR

QNTY/N


%D

1

—— 1=1—— T

Under QNT Y/N: enter Y if quantitation was performed, N if not performed.%D must be less than or equal to 15.0% for quantitation, and less thanor equal to 20.0% for confirmation.

%



00


Name: BCM Contract:

Code: BCM Case No.:43)H| SAS No*: SDG No*Instrument ID: 0014 . GC Column ID: DB1701

COMPOUND

alpha-BHCbeta-BHCdelta-BHC _gamma-BHC (LiHeptachlor _____AldrinHept. EpoxideEndosulfan IDieldrin4.4' -DDEEndrinEndosulfan II1 4 '-ODD__Bo. sulfateHI ' -DDTMethoxychlor_Endrin ketonea. Chlordaneg. ChlordaneToxapheneAroclor-1016Aroclor-1221Aroclor-1232Aroclor-1242Aroclor-1248Aroclor-1254Aroclor-1260


RT

13.3717.6818.6114.9215.7116.7419.2520.2521.5620.8922.2724.0023.7026.2624.3126.3928.1720.6020.4122.0515.3011.8515.3314.3717.5420.8723.77

IWIJ

FROM

13.3717.6818.6114.9215.7116.7419.2520.2521.5620.8922.2724.0023.7026.2624.3126.3928.1720.6020.4122.0515.3011.8515.3314.3717.5420.8723.77

ITIDOW

TO

13.3717.6818.6114.9215.7116.7419.2520.2521.5620.8922.2724.0023.7026.2624.3126.3928.1720.6020.4122.0515.3011.8515.3314.3717.5420.8723.77

Jnder QNT Y/N: enter Y if quantitatID must be less than or equal to 15or equal to 20.0% for confirmation.

CALIBRATIONFACTOR

5136400.3692300.4304600.4439900.8362050.6170600.6914900.6937750.5948050.4145550.5116500.4675875.2236000.1099850.3768200.2276305.6775500.8021250.6847250.177096.1336300.352602.658792.732440.1124022.1468016.1818690.


RT

14.7815.5716.6219.1120.1121.42

23.86

24.1726.25

CALIBRATIONFACTOR

4926900.8426650.6636100.7317250.7581050.6140550.

4646175.

3939300.2163765.

QNTY/N


ion was performed, N if not perform*. 0% for quantitation, and less than

%D

11.0.8

7.55.89.33.2

.6

4.54.9

\oT. ——

Note: Determining that no compounds were found above the CRQL is a form ofquantitation, and therefore at least one column must meet the 15.0% criteria.



0000fR3055i»8



Lab Code: BCM Case No.: 43 / SAS No': SDG No':Instrument ID: 0014 . GC Column ID: DB1701

COMPOUND

alpha-BHCbeta-BHCdelta-BHC _^gamma-BHC (LiHeptachlorAldrinHept. EpoxideEndosulfan IDieldrin4, 4 '-DDE ____EndrinEndosulfan II4, 4 '-ODDEndo. sulfate4,4' -DDTMethoxychlorEndrin ketonea . Chlordaneg. ChlordaneToxaphene __Aroclor-1016Aroclor-1221Aroclor-1232Aroclor-1242Aroclor-1248Aroclor-1254Aroclor-1260


RT

13.3717.6818.6114.9215.7116.7419.2520.2521.5620.8922.2724.0023.7026.2624.3126.3928.1720.6020.4122.0515.3011.8515.3314.3717.5420.8723.77

IWI*

FROM

13.3717.6818.6114.9215.7116.7419.2520.2521.5620.8922.2724.0023.7026.2624.3126.3928.1720.6020.4122.0515.3011.8515.3314.3717.5420.8723.77

ITfDOW

TO

13.3717.6818.6114.9215.7116.7419.2520.2521.5620.8922.2724.0023.7026.2624.3126.3928.1720.6020.4122.0515.3011.8515.3314.3717.5420.8723.77

Under QNT Y/N: enter Y if quantitat%D must be less than or equal to 15or equal to 20.0% for confirmation.

CALIBRATIONFACTOR

5136400.3692300.4304600.4439900.8362050.6170600.6914900.6937750.5948050.4145550.5116500.4675875.2236000.1099850.3768200.2276305.6775500.8021250.6847250.177096.1336300.352602.658792.732440.1124022.1468016.1818690.


RT

13.2517.5618.48

16.62

20.7722.15

23.5826.14

28.0120.4820.29

CALIBRATIONFACTOR

5095000.3678800.4284750.

6353350.

4722450.5375750.

2046375.824550.

6890650.7890700.6593900.

ion was performed, N if not perJ. 0% for quantitation, and less 1

QNTY/N


forme:han

%D

.8

.4

.5

3.0

—— . —

13.95.18.5i

25. CM

\1.71.63.7

————

sd.

»



'055149


Name: BCM Contract:Lab Code: BCM Case No.:^J|Yf SAS No.: SDG No.: W1007

Matrix: (soil/water) WATER Lab Sample ID: 130422MB

Sample wt/vol: 1000. (g/mL)ML Lab File ID: N1014209Level: (low/med) LOW Date Received: O/ O/ 0

% Moisture: not dec.100. dec. 0. Date Extracted: 0/30/01Extraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 10/15/91 ftfc.ii|nK

GPC Cleanup: (Y/N) N pH: .0 Dilution Factor: 1.00


319-84 -6 ———— alpha-BHC3 19-85-7 ———— beta-BHC319-86-8 ——— delta-BHC58-89-9 ———— gamma-BHC (Lindane)76-44-8 ———— Heptachlor309-00-2 ———— Aldrin1024-57-3 ———— Heptachlor epoxide959-98-8 ——— Endosulfan I60-57-1 ——— Dieldrin

33213-65-9 ——— Endosulfan II72-54-8 ———— 4 , 4 ' -ODD

103 1-07-8 ——— Endosulfan sulfate50-29-3 ———— 4, 4 '-DDT72-43-5 ———— Methoxychlor

53494-70-5 ———— Endrin ketone5103-7 1-9 ———— alpha-Chlordane5103-74-2 ———— gamma-Chlordane8001-35-2 ———— Toxaphene12674-11-2 ———— Aroclor-101611104-28-2 ———— Aroclor-122111141-16-5 ———— Aroclor-123253469-21-9 ———— Aroclor-124212672-29-6 ———— Aroclor-124811097-69-1 ———— Aroclor-125411096-82-5 ———— Aroclor-1260

.050

.050

.050

.050

.050

.050

.050. .050

.100

.100

.100

.100

.100

.100

.100.50

.100.50.501.0.50.50.50.50.501.01.0

UUUUUUUUUUUUUUUUuuuuuuuuuuu


flR305550 °00287

rLII

BUM LftBUKA I UHltb Keport - UtNlt Medium ftrea horrn

Sample Name : 13U422MB 6U8 1L-1UML W1UU/ Keport No : 82.UlMIH hlJK LLK Htb I b'/HUBb UN ftL'L-l.<. .. Kaae 1LJULUMN UB6U8 3UM X U . b43 MM 0.83 UM h i LM iU#U331222,iNJ I 2bULnKKltK K-b ft I bHb'l, I U IftL h LUW -'UML/M1N tLU 3UUL KftNUt Ului INJtLllUN IbUL, 1mm bL/min, 2/bL 14M1N

Book/Kaqe :

Keak h'rocessor : Lienie M u l t i l e v e l : halse

Instrument : ftUL 13 ftpplication : Loop

Lalcuiation : txternalblU LJuan t 11 a t ion : flreaUnits

Kesult h i l e : /DA I A/tX I KAL I b'/Ktb'JL I /N1U142U* . Ktb

Kun l i m e : 4U.UU Minutes Iniected on Iue Uct Ib , 1**1 3:43:U1 pm

Sequence h i l e : /Ufl I ft/tX I K«L I b/btUJUtNL't/btULLH lUlb*l 13 . b'tU

bubseq/bample: I/ y Bottle no. : *

Ihreshold Mm-«r Kkwidth Kh Unknown2.U l.UUUUt+U3 .U4U U.UUUt+UU

Kef '!dw Pbs Kef-KIUI r-)on Kef Mm Mbs f4on Kef-KIW Ident LevelU.UU l.bU U.UU l.bU 1UUU.UU

% Lil-hact Smp-Prnt Std-Mrnt % Kurity Ini Uo 1 Hatiol.UUUUt+U^ U.UUUUt+UU i.UUUUt+UU 1UU.UUU l.UUU

Kun 3tatus : KunbtatusUKt n d U F f B a s e 1 i n e

limed tvents lime tvents Loqic Ualue tventUpdate1 U.UU Negat iveKeat- s tvent UFf -l.UU f-alse2 . .1U KesetBLftllUalley tventUn -l.UU haise

Kklt Kl lU-tro Ksaku;idth nrea L'ode ftMUUMI Name1 1.32 l.-2 .U8/2 !U3b633BB 3.11/*t-Ub SULUtNI hKUNI2 i ./o . U4j>4 183* UBB U.UUUUt+UU

1 . 8b . Ub/y 22618BB U.U U UUt + UU^ 2.Uy .Ub86 42*46BB U.UUUUt+UUb 2.44 .Ub8* l//b6BB U.UUUUt+UU6 2;b8 . U6J3 11/ob'B U.UUUUt + UU

3.43 . U * 2 !J 14* 6 BB U . U U U U t + '.I U3 3 ./*• .LI/61 2388 BB U.UUUUt+UUy 3.ya .u/83 2yb4BB u.uuuut+uu1U 4.3L .1346 2UU6BB U.UUUUt+UU11 b.bl .U82U 11U6BB U.UUUUt+UU12 b./L! . Uy24 134bBB U.UUUUt+UU13 b.yb .118b !Ub6yBB U.UUUUt+UU1^ -,b_ -- .1364 16V4BB U . U U 0" U t + U U

/.2/ .1311 6Ub/4BB U.UUUUt+UU_•-!<-> . 1 •— '' •! ' :i v LJ y 11 11 |; 11 ;: t_ j- 11 11 •

BLM LftBUKftlUKltb Keport - btNlt Medium Rrea horm

Sample Name : 13U422MB 6U8 1L-1UML W1UU/ Keport No : 32. UlMIH J-UK ULK Htb I b/HUBb" UN nUL-i3 " ~~ - . . . . . . - - Haqe 2KU# HI lU-tm HeakWidth Prea L'ode «MUUNI NameI/ a. 68 .1632 IbU/BB U. U U U U t + U U18 IL'.Ub #1U.U4 .1188 438813BB / . */6* t- U 1 - 2 , 4 , b , 6 - I t I KftUHLUKU-rn-XYLl1* 1U.*2 .1148 12/UBB U.UUUUt+UU-U 11.32 .Ib32 1/81BB U.UUUUt+UU'21 11./* . 136/ b26/BB U.UUUUt+UU22 12,64 .1643 llb/BB U.UUUUt+UU23 13.14 #13.13 .144/ a4/bBB 1.846Ut-U224 14.38 .1/63 13U*BB U.UUUUt+UU2b 14.8* #14.8/ .116* 664bBB l.b*83t-U226 ib.ia .114/ bUU/BB U.UUUUt+UU2/ lb./a .161* 143*3BB U.UUUUt+UU28 16.3U #16.2* . 14U1 12U46BB 1.8842t-IJ2 l»t*e<gc 1 o r2* 16./* .1143 3/U6BB U.UUUUt+UU-• U i-'.2u .2388 1*38BB U.UUUUt+UU-'1 I/. 62 . U8bb 3324BB U.UUUUt+UU32 2U.14 .13bU 116*8BB U.UUUUt+UU33 21.14 .2/34 l*81Bb U.UUUUt+UU34 21.64 #21.62 . 138b 1U**2BB l.*368t-U2 1 ;i r • ~< \ i' i i^ I-^b 22. bU . 12/b 1U432BB U.UUUUt+UU ____:>6 22.*2 #22. *1 .1381 • !Ub*lBB 2.2y23t-U2 fcTl e i c i' i n/ 24.46 .Ibba //21BB U.UUUUt+UU8 24./* .12/1 33688BB U.UUUUt+UU

3* 2b.l* .134/ 3U66UBB U.UUUUt+UU-U 2b.44 .U*88 4*83BB U.UUUUt+UU41 26.U3 .124U 261/1BB U.UUUUt+UU-i2 26.62 - . 14*b *24U2BB U.UUUUt+UU^^ 2/.U6 .14/b 2U266BB U.UUUUt+UUm* J8.14 #28.11 .1643 334/8/BB 8.26U8t-Ul Uibuty1ch1orendate-^ 3U.26 #3U.23 .14*4 2Ub4Bb *.88/lt-U3 i TC •.' '•''•. .' i i o r-6 3U.6o .8U21 1*U44BB U.UUU U t + U U-i'' 31.8U .4662 *b44BB U.UUUUt + UU-a .-c, .J>G .*33b lbb214BB U.UUUUt + UU

l o t a l rtrea : 2b 13236 l o t a i AMUUN I : 1. ,'2*

Keport lime : Wed Uct 16, l*yi ll:l4:bU amMethod : /Uft I ft 'tX I KftL I b/Mt I KUU/M I HLLK lUlb*l 13.MIH

flR305552

BLM LrtBUKftlUKltb Keport - LitN 11 Medium Rrea horm

Sample Name : 13U422MB 6U8 1L-1UML W1UU/ Keport No : «2 UlMIH hUK LLH KtblS/KLBb UN ftUL-13 ' Kaqe 3

LJUL'JLiil rKUNI

Pf 9SmmagBHL CLindaneJ

_I ' ——— 2 ,4,b ,6- 1 1 IKflLHLUKU-m-XYLtNtrr lu.yiaI ( 11.321hf 11. /a*Li 12.63*I r alpha-BHLJUi i 14. 3//Pfh r1 ib./.'aI r Heptach lorhf 16. /a*l ', I ' - ' H VL f' n/rgib. iU I

f- LI r 2U. 142'" '<, 1 2 1 . 4 4_ c* tndosu 1 Fan ll b 22.bUlT f ' U i e l d r mI \I I

I r_7 26 . U26L ..———— 2 6 . 6 i bI r 2/.U63L i_ _____I r———— U i b u t v 1 c h L o r e n d a t e\- fI Ih II ! MethoxyeniorI I 3U.664'

h j 31.8U4j !I- I

OC0230flR305553

BUM LABUKAIUKltb Keport - btNlt Medium Area horm

Sample Name : 13U422MB 6U8 1L-1UML W1UU/ Keport No : 82.UUMIH hUK LLK Ktblb/KLBb UN AUL-14 ' Haae 1LULUMN UB1/U1 3UM X U.b3MM 1UM hILM 1U# U4*3Ub2 1NJ I 2bULK-b -bML/MIN MAbb hLUU MAKt UK K-b hUK 1UIAL Uh -/UML/M1NtLU 3UUL, KANLit U, lui INJtLllUN IbUL, 1mm bL/mm, 2/bL

Book/Kage :

Keak Krocessor : benie Multilevel : haise


Calculation : txternalblL) LJuan t 11 at ion : AreaUnits

Kesult h i l e : /UAIA/tXIKAL1S/KtbULI/U1U142U*.Ktb

Kun l i m e : 4U.UU Minutes 1 n i ected on Iue Uct Ib, 1**1 3:43:U1 pm

Sequence h i l e : /UAIA/tXIKALIb/btUUtNLt/bhUULK lUlb*l 14.btl|

bubseq/b'amp le: I/ _*___ bottle no. : b*

reshold Min-Ar Hkwidth Kh Unknownb.U 2.UUUUt+U3 .16U U.UUUt+UU

Kef Wdw Abs Kef-KIW Non Kef Win Abs Non Kef-KIW Ident LevelU.UU l.bU U.UU l.bU 1UUU.UU

% Uii-hact bmp-Amt btd-Amt - % Kurity ini Uo1 Katiol.UUUUt+U3 U.UUUUt+UU 1.UUUUt+UU 1UU.UUU l.UUU

Kun Status : KunbtatusUKtndUf t'Base i me

I imed tvents I irne tvents Logic Ualue tventUpdate1 U.UU KesetBLAtUa1 ley tventUn -l.UU haise2 U.UU NegativeHeaks tventUFF -l.UU haise3 b.UU KesetBLAtUalley tventUn -l.UU haise4 1U.UU ^esetBLAf'a 1 ley tventUn -l.UU halseb Ib.UU KesetBLAtUailey tventUn -l.UU halse6 2U.UU KesetBLAtUa1 ley tventUn -l.UU halse

2 b . U U :-' :• s 5 r r'LH t •'a i 1 e v tventUn - i . U U haise8 3U.UU KesetBLAtUalley tventUn -l.UU haise

Kk# Kl lU-tm HeakWidth Area Lode AMUUNI Name1 .12 .2U2U 22U2BB U.UUUUt+UU2 1.12 .2486 2283BU U.UUUUt+UU3 1.63 .124/ 21UU383Hb U.UUUUt+UU-4 l.*4 . Ubbb 1*68UBI U.UUUUt+UUb 2.31 .U/bl /6682BI U.UUUUt+UU6 2.43 .U/*6 b2Ub2UI U.UUUUt+UU

2.63 .U*U1 //664UI U.UUUUt+UUB 2.8* _ . Ijy2b ,_ lb61UKI U.UUUUt+UU'-> 2.y* - , , , . - . . IJ646 /2U6U! U.UUUUt+UU

1U 3.. 11 . U612 21832UI U.UUUUt+UU


Sample Name : 13U422MB 6U8 1L-1UML W1UU/ Keport No : 82.UUMIH hUK LLK Ktblb/PLBb UN AUL-14 ' Kaqe 2PMt= Kl iU-tm Pe'akWidth Area Lode AMUUN I Name11 3.26 .U621 bUU8HI U.UUUUt+UU12 3.4U .U/*2 - 238*KI U.UUUUt+UU13 4./4 .U*ll 4316PI U.UUUUt+UU14 b.16 .U838 ~ bl/6PI U.UUUUt+UUI1? b.41 .1U4U 226bBU U.UUUUt+UU16 b.*8 .U862 236UPU U.UUUUt+UU'L/ 6./6 . lb/8 b343UU U.UUUUt + UU10 6.*8 .22*/ 46/8UU U.UUUUt+UUly /.6/ .b832 l/U6bUU U.UUUUt+UU'• U 8.28 . 1/Ub 3/312UU U.UUUUt + UU'^1 8.6b .2/38 bl*3UU U.UUUUt + UU'•^ *.UU .244y 3162UU U.UUUUt+UU23 *./b #y.82 .118U bauaU/PB *.U486t-!Jl 2 ,4,b ,6- 111 KAUHLUKU-m-XYLtl24 11.UU .1486 22/bKU U.UUUUt+UU2b 11.46 .11/b 6b38UU U.UUUUt+UU26 12./* .18/6 3/81UU U.UUUUt+UU2/ 13.31 #13.3/ .1U13 63yiKU 1.2442t-U228 14.3b .11U1 3U63KU U.UUUUt+UU2y 14.8b #14.*2 .1133 /3U3PB 1.644yt-U23U lb.24 .12b4 y//4BU U.UUUUt+UU31 lb.64 #lb./l .Ib34 iy3b3UU 2.3144t-U232 16.6y #16./6 .1338 *86/UU l.b**Ut-U233 I/.48 .13*U 1134UPU U.UUUUt+UU34 1/.62 .162* lUbbbUU U.UUUUt+UU-••b 18. b3 .16UU 6//2UU U.UUUUt+UU36 18./3 .2U2/ 2U3bUU U.UUUUt+UU3/ l*.l/ #l*.2b .1246 12141UU l./bb8t-U2 IHg l. u •-11'.-I i—-r-oxide38 2U.1/ #2U.2b .13bb 1U/43BB l.b484t-U23* 2U.84 #2U.8* .12U3 b*b8BU 1.43/2t-U2~*U 21.4* #21. b6 . 148y 1244yKU 2.Uy3Ut-U2-*1 22.21 .161/ 1184UUU U.UUUUt+UU^2 'J3.6b . 1U11 134*/PU U.UUUUt + UU-*3 23.*2 #24. UU .1431 31626UU 6./63/t-U2 LTIUL . j i i'un 11«4 24.23 #24.31 .1/6U 33*26UU *.UU33t-U24b 24.b* • .166b lb2/UUU U.UUUUt+UU46 'Jb.62 .2UU8 3436BU U.UUUUt + UU4.' 2b . 84 .22^3 lU/aUUU U.UUUUt + 'JUA8 26.24 #26.26 . 228b /6334UU 6.*4U4t-Ul tnUJ-L'i . -Tn^sulfate /4* 26.b* #26.6/ .221U 48U/2*UU /.4b84t-Ul U i bu t y 1 ch 1 o renda t e ""^ M * /„

l o t a l Area : 386844U lotai AMUUNI : 2.63*

Keport l i m e : Iue Uct Ib, l**i 4:24:1* pmMethod : /UAIA/tXIKALIb/MtIHUU/MIHuLp 1U14*1 14.MIH

°C0292

BUM LABUKAIUKitb Keport - UtNlt Medium Area horm

Sample Name : 13U422MB 6U8 1L-1UML W1UU/ Keport No : 82.UUMIH hUK ULP Ptblb/PLBb UN AUU-14" Page 3

i / . 11*L JI ? 1. lib . , . _ _ . - . _ . - - ,|- ^ ..i,*?••..———————————————————————-——— 1-6--Vi -to

2 ,4,b ,6- I tIKAUHLUKU-m-XYLtNt' ' '( 1 1 . U U U! r n.46 ui i

h f 12. /8b^* alpha-BHU

14.34ygamma-BHU CUndaneJ

k r Heptachlorj \j- f Aldr inL ? i^:i&-/I

L I iS:>^I f Heptachior epoxideh L 'I f tndosuifan Ij- f 4,4'-UUtj_ f U i e 1 d r i nj r 22.214 . _.I- j! W

l f a t e:.-' i fc u t v l c J". i o r e n 1 1 a T; ,s

i-!i-

}- I ^ AR30S556 000293


Lab Name: BCM ContractMSPIKE

Lab Code: BCM Case No. :<-$!<?/ SAS No.: SDG No.: W1007

Matrix: (soil/water) WATER Lab Sample ID: MSPIKESample wt/vol: 1000. (g/mL)ML Lab File ID: N1014213

Level: (low/med) LOW Date Received: 9/24/91

% Moisture: not dec. 100. dec. 0. Date Extracted: 9/30/91- ff'/y? /q(Extraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 10/15/91 ?&<<•

iilnhiGPC Cleanup: (Y/N) N pH: .0 Dilution Factor: 10.00

CONCENTRATION UNITS:GAS NO. COMPOUND • (ug/L or ug/Kg) UG/L Q

319-84-6 ———— alpha-BHC319-85-7 ———— beta-BHC

58-89-9 ———— gamma-BHC (Lindane)76-4 4-8 ———— Heptachlor309-00-2 ——— Aldrin1024-57-3 ———— Heptachlor epoxide959-98-8 ———— Endosulfan I60-57-1 ———— Dieldrin72-55-9 ———— 4 , 4 ' -DDE72-20-8 ——— Endrin

33213-65-9 ———— Endosulfan II/ <& « "* o H f ** LJLJU

1031-07-8 ——— Endosulfan sulfate50-29-3 ———— 4 , 4 ' -DDT72-43 -5 ———— Methoxychlor

53494-70-5 ———— Endrin ketone5103-7 1-9 ——— alpha-Chlordane5103-7 4-2 ——— gamma-Chlordane8001-35-2 ———— Toxaphene12674-11-2 ———— Aroclor-101611104-28-2 ———— Aroclor-122111141-16-5 ———— Aroclor-123253469-21-9 ———— Aroclor-124212672-29-6 ———— Aroclor-124811097-69-1 ———— Aroclor-125411096-82-5 ———— Aroclor-1260

1.71.6.501.71.71.8.501.81.91.01.07.01.01.011.1.51.05.05.010.5.05.05.05.05.010.10.

U

U

UU

UU

JUUUUUUUUUUU

FORM I PEST 1/87 Rev

SR305559C0294

METHOD BLANK SPIKE RECOVERY WATER

BATCH NO. :wl007SPIKE VOLUME :, 1 ml

COMPOUND SPK SOLN EXPECTEDNAME CONC ( PPM ) CONC ( PPB )

4,4' -ODD4,4' -DDTEndosulf. IIEndosulf .SulHeptachlorEndrinLindaneAldrinbeta-BHCdelta-BHCalpha-BHCHept. epoxid4,4' -DDEDieldrinEndosulf. IEnd. AldehydMethoxychlorDibutylchlorTmx

METHOD

10101010222222222222211

BLANK

10101010222222222222211

SPIKE

FOUND SPIKECONC(PPB) REC. (%)

12.410.8

70.561.731.951.711.81.630.9951.721.861.791.861.78

01.52

0.9210.859

RECOVERY

124 %108 %70 %5.6 %

86.5 %97.5 %85.5 %92 %

81.5 %49.75 %

86 %93 %

89.5 %93 %89 %0 %76 %

92.1 %85.9 %

WATER

HR30555S

BLM LABUKAIUKltb Keport - UtN1t Medium Area horm

Sample Name : MbPlKt 6U8 1L-1UML X1U W1UU/ Keport Ho : 86.UlMIH hUK LLK PtbIS/HUBS UN AUU-13 Page 1LULUMN UB6U8 j'UM X U.b43 MM U.83 UM h 1LM 1 U#U331222 , i NJ I 2bULAKKltK K-b Al bPbl, IU1 AL hLUW -,'UML/MiN tLU 3UUU KANb't Ulul INJtLllUN IbUU, 1mm bU/min, 2/bU 14M1N

Book/Kage :



Lalcuiation : txternaiblU Ljuan t 11 a t ion : AreaUnits

Kesult h i i e : /UAIA/tXIKALIS/KtbULI/N1U14213.Ktb

Kun l i m e : 4U.UU Minutes iniected on lue Uct Ib , 1**1 6:36:12 pm

Sequence hiie: /UA I A/tX I KAU I S/StUUtNUt/btUULP lUlb*l 13 . btL|

bubseq/bampie: I/ 13 Bottle no. : 13

Ihreshold Mm-Ar Pkwidth Kh Unknown2.U l.UUUUt+U3 .U4U U.UUUt+UU

Kef IJdw Abs Kef-KIW Non Kef Win Abs Non Kef-PIW ident LevelU.UU l.bU U.UU l.bU 1UUU.UU

% Uii-hact Smp-Amt btd-Amt % Purity Ini Uo1 Katiol.UUUUt+U4 U.UUUUt+UU 1.UUUUt+UU 1UU.UUU l.UUU

Kun Status : KunbtatusUKtndLJF f Base i me

limed tvents lime tvents Logic Ualue tventUpdate1 U.UU NegativePeaks tventUff -l.UU halse2 .1U KesetBLAllUa1 ley tventUn -l.UU halse

Kk# Kl lU-tm KeakWidth Area Lode AMUUMI NameI 1.33 #1.32 .U8*3 1*/318BB b.*4IJ6t-Ub bULUtN I hKUNI2 1./6 .U/23 4666UBB U.UUUUt+UU3 l.*b .Ub*l 3UU8bBB U.UUUUt+UU4 2.U* .U48U 2/2UBB U.UUUUt+UUb 2.44 .Ub62 2186BB U.UUUUt+UU6 2.*1 1.118U 13/64BB U.UUUUt+UU/ b.*6 .11/3 /236BB U.UUUUt+UU nonoQ8 /.2/ .12ya b3Ub4BB U.UUUUt+UU QGQZ9S* /.** .162U 1U22BB U.UUUUt+UU

1U *.b8 .1133 11/11BB U.UUUUt+UU ___11 lU.Ub #1U.U4 .121b 4/2/bBb 8.b*3*t-Ul 2 ,4,b ,6-111 KAUHLUKU-m^PK-tt12 11.28 .13*3 1/66BB U.UUUUt+UU13 13.14 #13.13 .12U3 /88U2BB l./164t+UU alpha-BHU14 1^.31 .1632 16b2BB U.UUUUt+UUIb 14.88 #14.8/ .Ilb2 /U*/bBB l./U/Ut+UU qamma-BHL CLmdaneJ•1,6 lb.1 ' it'ib.16 . 114/ b!J3/'LHB 1.63U*h.+ UU b e^- ©- H-tr C C Q

n^PR_t

BUM LABUKAIUKitS Keport - LJtNlt Medium Area l-orrn

'ample Name : MbPlKt 6U8 1L-1UML X1U W1UU/ Keport No : 86. UlMIH hUK LLP Ptblb/PUBb UN AUU-13 Page 2Pk# Kl lU-tm P-aakWidth Area Lode AMUUN I NameI/ lb./a .1434 _ 1//UBB U.UUUUt+UU18 16. 3 U #16.2* .13*1 ~~ 11U844BB 1 •'/afl» k'HJ u Heptachlor1* 16./* .lib/ 38286BB U . U Ij U 6tf+U U •2U l/.U/ .1184 1UU4BB U.UUUUt+UU21 1/./4 #l/./3 .148b *3114BB 1.81A3t+UU Aldrin22 2U.14 . 13b2 !U3blbBB U.'uulht + U23 21.13 .122b 336/BB U.UUUUt+UU24 21.64 #21.62 . 13/* 1U12U1BB 1. /JU 3.JJi. + U U tndosu 1 Fan2b 22. bU .1262 a*6/lBB U.m3lJUk+UU DOfe26 22.*2 #22.*1 .13b/ 861b3BB 1.864/t+UU Uieldrm2/ 23.b* .1UU8 1313BB U.U^jmt+UU28 24.46 .123* 4642UBB U.JMttt+UU2* 24./y /1134 31Uy82BB U.WuVt + UU.-U 2b.l8 #2b.l/ . 12y4 3U4/8/BB ,-'.UU/6t + UU tndosu i Fan 11J-l 2b.44 . U/83 2U1BBB U.UUUUt+UU32 26.U2 #26.UU .12Ub 2/246/BB l.U823t+Ul 4,4'-UUI33 26.61 . 162/ 66823BB U . U UJlUt + U U

14/b 2//y4BB U.OfftTffL+UUCAJo. S*il+-* _.»/A3b 28.13 #28.11 .lob/ 3/344BB *.214bt-Ul Uibutyich1orendate

36 3U.2b #3U.23 .1/62 31b*3BB l.b2Ubt+UU Methoxychior/ 31.24 .18*8 //43BB U.UUUUt+UU

otai Area : 23b48U8 lot a l AMUUNI : 33.4U4

weport l i m e : Wed Uct 16, 1**1 12:U3:36 pmMethod : /UAIA/tXIKALIS/MtIHUU/MIHULP lUlb*l 13.MIH

000297flR305S60

BLM LABUKAIUKltb Keport - LitNlt Medium Area harm

Sample Name : MbP 1 K.t 6U8 1L-1UML X1U W1UU/ Keport No : 86. UlMIH hUK LLP Ktb IS/PUBS UN AUU-13 Page 3

SULUtN I h KUN I"

r \ 2.yuaI ii i

j [ b.yb6L 1i r~~ .-'.2/2i i /.yy4i ir iL L *.•://1 r— 2,4, b,6-ItIKAUHLUKU-m-XYLtNtM ' ' "I f 11.284h /

, f r^—— aipha-BHUh I.j ( _14_. 313i- ~ =— . qamma-BHL (LmdaneJj r beta —DHL.h L. lb./8bI tr————"~ Heptachlor

A i d r i n

I j-—==a~" '2U. 13V\- \\ L. 21. 12*L r————~ tndosuifan 1

F r———~ uteldrinL i 2 - . b y 2

i ~~ _— " '' • 'l6 ] -_____—===—— tndosulfan 11

| •--——-————-————————— 4 ,4 ' - UU IL *r.—' 26.612I r" 2/.Ub3L l_I ;-—" L11 bu t v 1 ch 1 o renda t eL II !I- [j r= Me t hoxvch 1 orh •'! r -1.23- . . . .h !

r 'i ir l

i I

BUM LABUKAIUKltb Keport - LStN 1 1 Medium Area rorm

bampie Name : MSPlKt 6U8 1L-1UML XI U W1UU/ Keport No : a6.UUMIH hUK LLP PtblS/PLBb UN AUU-14 Page 1UULUMN UB1/U1 3UM X U.b3MM 1UM h I LM 1 U# U4*3Ub2 i N J I 2bULP-b ~bML/MlN MAbb hLUW MAKt UP P-b hUK I U I AL Uh -/UML/M1NtUU 3UUU, KANUt U, lu i INJtUllUN IbUU, 1mm bU/mm, 2/bU

Bo ok /Page :

Peak Processor : benie Multilevel : halse


Ualculation : txternaiblU Uuan t i t a t ion : AreaUnits

Kesuit h i l e : /UA I A/tX 1 KAU I b/KtbUL I /U1U14213 . Ktb

Kun l i m e : 4U.UU Minutes Iniected on lue Uct Ib, 1**! 6:36:12 pm

bequence h i l e : _/UA I A/tX I KAU I b/btUUtNUt/btLJULP lUlb*l 14.btLJ

b'ubseq/bamp ie : I/ 13 Bottle no. : 63

reshold Mm-Ar Pkwidth Kh Unknownb.U 2.UUUUt+U3 .16U U.UUUt+UU


% Uii-hact bmp-Amt btd-Amt % Purity Ini Uo l Katioi.UUUUt+U4 U.UUUUt+UU 1. UUUUt+UU 1UU.UUU l.UUU

Kun Status : KunbtatusUKtndUf f Base 1 me

l i m e d tvents lime tvents Logic Uaiue tventUpdate1 U.UU KesetBLAtUal ley tventUn -l.UU halse2 U.UU Negat ivePeaks tventUFF -l.UU haise3 b.UU KesetBLAtUa i ley tventUn -l.UU halsei 1U.UU -e.etBLAt1 'a i ley t'-'erstUn -l.'JU haiseb Ib.UU KesetBLAtUal ley tventUn -l.UU halse6 2U.UU KesetBLAtUa 1 ley tventUn -l.UU haise

<- •." . U •.! _ . — ass t BLH ~. VG lie •,> t _ sn t LJ:"> — j. . U U r a i ss,8 3 U.UU KesetBLAtUal ley tventUn -l.UU haise

Pk# Kl iU-tm KeakWidth Area Lode AMUUN I Name1 .12 .2U41 214*BB U.UUUUt+UU2 1.63 . 11*U 3*b6U8UU U.UUUUt+UU3 2.43 .1363 81/42PU U.UUUUt+UU4 2.63 . U/88 663b2UU U.UUUUt+UUb 2.88 .lUb* 6226UU U.UUUUt+UU6 3.1U .Ib81 14482UU U.UUUUt+UU/ 3. /I .2b/8 4**bUU U.UUUUt + UU8 4.Ub .16U3 4I.I82UU !.! . U U U Ut+ U U* 4.1* .12*U 2*28UU U . UUUUt +

1U 4.36 713** 38*4UU U.UUUUt+UU

U Un Q q A C r r yUU" U 'U «3 U C

BLM LABUKAIUKitb Keport - LdtNlt Medium Area horm

Sample Name : MbPlKt 6U8 1L-1UML X1U W1UU/ Keport No : 86. UUMIH hUK LLP Htblb/PLBb UN AUU-14 Paae 2Pk# Kl lU-tm Pe'akWidth Area Lode AMUUN I Name11 4.b/ .21b6 6*43UU U.UUUUt+UU1- 4./3 .1888 66*UUU U.UUUUt + UU13 b.lb .3U34 11*63UB U.UUUUt+UU14 /.b* .3111 23b4BU U.UUUUt+UUl^1 8.U* .1/3* 266*UU U.UUUUt+UU16 8.26 .1U68 13U*UUB U.UUUUt+UUI/ *./U #y.82 .1432 118816BB 1.8bllt+UU 2 , 4 ,b ,6- 1 1 1 KAUHLUKU-m-XYLtr18 1U.3U .UV34 !Ubb3BU U.UUUUt+UU1* 12. 6U .36y8 2441UU U.UUUUt+UU-u 13. 3u .1U4U /yaayuu u.uuuut+uu21 14.83 #14. *2 .lU4b /4422PB 1.6/62t+UU gamma-BHU (.Lindane)22 lb.63 #lb./l .12/3 13*U*1BU 1.6634t+UU Heptachior23 16. 6/ #16. /6 .1328 !U663bPU l./281t+UU Aldrin24 I/. 61 .12* U b4bU/PU U.UUUUt+UU2b 18. U2 .18U1 bU42UU U.UUUUt+UU26 18. b4 .112* 3426bUU U.UUUUt+UU2/ 18. 8b .1442 2by6UU U.UUUUt+UU28 1*.16 #1*. 2b .1437""" 12yi4yUU 1.86//t+UU Heptachior epoxide2* 2U.16 #2U.2b .14yu 118b6yPB l./uyut+UU tndosu 1 Fan 13U 2U.82 .121U b648UBU U.UUUUt+UU31 21.48 #21. b6 .lb/U 1168UyuU l.*638t+UU Uieidrm.?2 22. 2U . Ibb/ *8b82UU U.UUUUt+UU33 23.63 .1142 16b*/UPU U.UUUUt+UU34 23. *1 #24. UU .14b3 362b*/UU /./b46t+UU tndosu 1 fan 113b 24.22 #24.31 .2U8U 43*484UB 1.1663t+Ul 4,4'-UUI36 26.2* #26.26 .166* 44231BU 4.U216t+UU tndosu if an sulfate3/ 26. b4 #26. 6/ .3Ulb 8//41UU 1.3613t+UU U i bu t y 1 ch 1 o r endat e

'J8.ll #28. I/ .2323 4b6UUU 6./3U6t-U2 tndnn ketone28. 3/ .13** 3621UB U.UUUUt+UU

l o t a l Area : 28822'lb l o t a l AMUUr-H : 3/.32/

Keport I irne : I ue Uct ib , 1**1 /:l/:32 pmMethod : /UA I A/tX I KAU I S/Mt I HUU/M I HULK 1U14*1 14. MIH

.//,

5R305563 QCQ300


sample Name : MbPlKt 6U8 1L-1UML X1U W1UU/ Keport No : 86. UUMIH hUK LLP Ptblb/PUBb UN AUU-14 Page 3

i- ^-jfH

M b! ibl

h ii iL 1 /. b*4

M . . . . . . " ; "j- 'h-'" 2 , 4 , b , 6- 1 1 I KAUHLUKU-m-XYLtNti f 1U.2*8h i! ! . . .M . . . .L 12.b*8 _

13.3UU

gamma-BHU CL.indane)Hep t ach 1 o r

Aldrin_ , 1/.611 "I I _ 1 8 . U 1 6

Heptachlor epoxide

tndosu i fan 12U.824

U i e i d r i n'| ' ==— 22.2U4h i

™ Lb, . „————— 4,4tn.0Bfulfan'r ' '"! Vh L .fc'ate

j. | - - -- OC0301LI " " "": •• - • " '


Lab Name: BCM Contract:(30414MS

Lab Code: BCM Case No.: SAS No.: SDG No.: W1007

Matrix: (soil/water) WATER Lab Sample ID: 130424SSample wt/vol: 980. (g/mL)ML Lab File ID: N1014210

Level: (low/med) LOW Date Received: 9/24/91% Moisture: not dec. 100. dec. 0. Date Extracted: — a/SOSlExtraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 10/15/91 , ,GPC Cleanup: (Y/N) N pH: .0 Dilution Factor: 1.00


319-84-6 ———— alpha-BHC

319-86-8 ———— delta-BHC58-89-9 ———— gamma-BHC (Lindane)76-44-8 ———— Heptachlor309-00-2 ——— Aldrin1024-57-3 ——— Heptachlor epoxide959-98-8 ———— Endosulfan I60-57-1 ———— Dieldrin72-55-9 ———— 4 , 4 ' -DDE72-20-8 ——— Endrin

33213-65-9 ——— Endosulfan II72-54-8 ———— 4 , 4 ' -ODD

1031-07-8 ———— Endosulfan sulfatew> w *c* ./ . ~f f *± UU X

72-43-5 ———— Methoxychlor53494-70-5 ——— Endrin ketone5103-71-9 ——— alpha-Chlordane5103-74-2 ———— gamma-Chlordane8001-35-2 ———— Toxaphene12674-11-2 ———— Aroclor-101611104-28-2 ——— Aroclor-122111141-16-5 ——— Aroclor-123253469-21-9 ———— Aroclor-124212672-29-6 ———— Aroclor-124811097-69-1 ———— Aroclor-125411096-82-5 ———— Aroclor-1260

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BUM LABUKAIUKltb Keport - btNlt Medium Area rorm

Sample Name : 13 U424S t 14 ) 6U8 *8UML-1UML W1UU/ Keport No : 83. UlMIH hUK LLP Ptb IS/PUBS UN AUU-13 Paqe 1LULUMN UB6U8 3UM X U.b43 MM U.83 UM h i LM 1 U#U3 3 1222 , 1 NJ I 2bULAKKltK K-b A I bPbi, I U I AL h LUW ~"JML/M1N tUU 3UUU KANUt Ului INJtUllUN IbUU, 1mm bU/mm, 2/bU 14M1N

Book/Page :

Peak Processor : benie Mul t i l e v e l : halse


Lalcuiation : txternaTSlU Uuan t 1 1 a t ion : AreaUnits

Kesuit h i l e : /UA I A/tX I KAU I S/KtbUL I /N1U1421U . Ktb

Kun lime : 4U.UU Minutes Iniected on lue Uct Ib , 1**1 4:26:26 pm

Sequence hiie: /UA I A/tX I KAU I b/StUUtNUt/btUULP lUlb*l 13.btU)

bubseq/bamp ie: I/ 1U Bottle no. : 1U

reshoid Mm-Ar Pkwidth Kh Unknown2.U l.UUUUt+UJ . U4U U.UUUt+UU

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% Uii-hact bmp-Amt btd-Amt % Purity ini Uo i Katiol.U2U4t+U3 U.UUUUt+UU 1. UUUUt+UU 1UU.UUU l.UUU

Kun Status : KunbtatusUKtndUFFBase 1 me

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l o t a l Area : - 18*bb/64 l o t a l AMUUNI : 2.321

Peport l i m e : Wed Uc t 16, iy*l il:23:U'l amMet nod : /UAIA/tXIKAUIS/MtIHUU/MI HULK lUlbyi 13.MIH

OC0305RR305S68

BLM LABUKAIUKltb Keport - btN1t Medium Area horm

Sample Name : 13U424SC314J 6U8 *yUML-!UML W1UU/ Keport No : 83.UlMIH hUK LLP ^tblb/PUBb UN AUU-13 Paqe 4

SULUtN I h KUfJ . (

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BUM LABUKAIUKitb Keport - UtN1t Medium Area rorm

Sample Name : 13U424b_^jl4) 6U8 yaUML-lUML W1UU/ Keport No : 83. UUMIH hUK LLP Ptblb/PUBb UN AUU-14 Page 1UULUMN UB1/U1 3UM X U.b3MM 1UM hiLM 1U# U4y3Ub2 1NJ 1 2bULP-b ~bML/MlN MAbb hLLIW MAKt UP P-b hUK I U I AL Uh -/UML/M1NtUU 3UUU, KANbt U, lu1 INJtUliUN IbUU, 1mm bU/min, 2/bU

Book/Page :

Peak Processor : benie Multilevel : haise


Uaicuiation : txternalblU Uuantitation: AreaUnits

Kesult h i l e : /UAIA/tXIKAUIb/KtbUL1/U1U1421U.Ktb

Kun l i m e : 4U.UU Minutes Iniected on lue Uct Ib, 1**1 4:26:26 pm

bequence h i i e : /UAIA/tXIKAUIb/btUUtNUt/btUULP lUlbyi 14.btU

bubseq/bampie: I/ 1U _ Bottle no. _ : 6U

eshold Mm-Ar Pkwidth Kh Unknownb.U 2.UUUUt+U3 .16U U.UUUt+UU

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\ Uii-hact bmp-Amt btd-Amt % Purity Ini Uol Katioi.U2U4t+U3 U.UUUUt+UU 1.UUUUt+UU 1UU.UUU l.UUU

Pun Status : KunbtatusUKtndUf fBase 1 me

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BUM LABUKAIUKitb Keport - UtN 11 Medium Area horrn

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l o t a l Area : 2323b2U4 lotal AMUUNI : b.U68

k'eport lime : I ue Uct Ib ,. IVVl b:U/:b3 pmMethod : /UAIA/tX1KALIS/ML1HUU/MI HULK 1U14*1 14.MIH


Sample Name : 13 U424SC 314 ;> 6U8 yaUML-lUML W1UIJ/ Keport No : 83. UUMIH hUK LLK Ptblb/PUBb UN AUU-14 Page 4

2.30$

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• ~ ' •- Heptachlor

Aldrin

18 . /66 _———— ~~ Heptachlor epoxide

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OG03108R305573


Name: BCM Contract:(30414MSD

Lab Code: BCM Case No.: j SAS No.: SDG No.: W1007

Matrix: (soil/water) WATER Lab Sample ID: 130423D

Sample wt/vol: 980. (g/mL)ML Lab File ID: N1014211Level: (low/med) LOW Date Received: 9/24/91% Moisture: not dec. 100. dec. 0. Date Extracted: y?o/9l

Extraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 10/15/91GPC Cleanup: (Y/N) N pH: .0 Dilution Factor: 1.00

CONCENTRATION UNITS:GAS NO. COMPOUND (ug/L or Ug/Kg) UG/L Q

319-84-6 ———— alpha-BHC3 19-85-7 —— — beta-BHC3 19-8 6-8 —— — delta-BHC58-89-9 ——— gamma-BHC (Lindane)76-44-8 ———— Heptachlor309-00-2 ———— Aldrin1024-57-3 ———— Heptachlor epoxide959-98-8 —— —Endosulfan I60-57-1 ——— Dieldrin72-55-9 ————— 4 , 4 ' -DDE '72-20-8 ———— Endrin

33213-65-9 ———— Endosulfan II72-54-8 ———— 4 , 4 ' -ODD

1031-07-8 ——— Endosulfan sulfate72-43-5 ——— Methoxychlor

53494-70-5 ——— —Endrin ketone5103-71-9 ——— alpha-Chlordane5103-74-2 ———— gamma-Chlordane8001-35-2 ——— Toxaphene12674-11-2 ———— Aroclor-101611104-28-2 ———— Aroclor-122111141-16-5 ———— Aroclor-123253469-21-9 ———— Aroclor-124212672-29-6 ———— Aroclor-124811097-69-1 ———— Aroclor-125411096-82-5 ———— Aroclor-1260

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L } 3a.62/! i

BUM LABUKAIUKltb Keport - bitN 1 1 Medium Area horm

Sample Name : 13U423LH^14J 6U8 *8UML-1UML W1UU/ Keport No : 84. UlMIH hUK LLP Ptb IS/PUBS UN AUU-13 __ Page iLULUMN LJB6U8 3UM X U.b43 MM IJ.83 UM h i LM L U#U 33 1222 , 1 NJ I 2bULAKKltK K-b A I bPbi, I U I AL h LUW "/UML/M1N tUU 3UUU KANLt Ulul INJtUllUN IbUU, 1mm bU/mm, 2/bU 14M1N

Book/Paqe : ,

Peak Processor : U-enie Multilevel : halse

instrument : AUU 13 Application : Loop

Uaicuiation : txternalblU Uuan t i t a t ion : AreaUnits

Kesult h i i e : /UA I A/tX 1 KAU I S/KtbUL 1 /N1U14211 . Ktb

Kun l i m e : 4U.UU Minutes Imected on lue Uct Ib , l*yi b:U*:2U pm

Sequence h i i e : /UA I A/tX I KAU I S/btUUtNUt/btUULP lUlbyi 13.btU

bubseq/Samp le : 1/11 Bottle no. 11

threshold Mm-Ar Pkwidth Kh Unknown2.U l.UUUUt+U3 . U4U U.UUUt+UU


•^ Uii-hact bmp-Amt Std-Amt % Purity Ini Uo 1 Katiol.U2U4t+U3 U.UUUUt+UU 1. UUUUt+UU 1UU.UUU l.UUU

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Audit Date: III/ i client:By: __fQi-'_____ , Jobf:

)rder *:

SampleNumber

•V-5/9/

SampleDate

/3o -/ - *j 1 kit/3<9<V/^ /

130 35/3OJ-J3L(- „/

1

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/

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y~ holding time met; * - holding time exceeded

Holding Times: ECRA 40 CFR Part 136 ' SW-846 CLPUntil Extraction

Solid -it days —————— t days 10 daysLiquid 7 days 7 days ————— 5 days

All samples must be analyzed within 40 days after extraction.

AR30558U000321

BCM LABORATORY/' , I -GC EXTRACTASLES BLANK ANALYSIS I

Audit Date: fll'sh, . Client: .Audited By: ^^ Jobt: 00-406,4-/3°*<-er *« *&9I Units: M*JiL Matrix:

1SampleNumber/ X-' ..i.

Comments :

Analy;Date

/0//c/<v

1sis |Time

Blank< CRQL 3

Comp<J

.

Eor allaunds 1

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15 OKINo |

____

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Pesticide and PCB % Recovery RangeLiquid Solid

Endrin 56-121 42-139Dieldrin 52-126 31-134Aldrin 40-120 34-124Lindane (G-BHC) 56-123 46.-127Heptachlor 40-131 35-1304r4'-DDT 38-127 23-134Arochlor 1260 47-125 35-131* Indicates the matrix spike/dup compound is outside criteria

i»

RR305587

\ TRILL1UIVU

DATA VALIDATION

FOR

OCCIDENTAL CHEMICAL PLANTPOTTSTOWN, PENNSYLVANIA

INORGANICS ANALYSIS DATA:TAL Metals and CyanideOrder Number 43191

Chemical Analyses Performed by:BCM Laboratory

FOR

Occidental Chemical CompanyNiagara Falls, New York

BY

Trillium, inc.7A Grace's Drive

Coatesville, PA 19320———— (215) 383-7233

February 25, 1992

9U41/3S

flR3Q5588

\ TRILLIUM,

EXECUTIVE SUMMARY

Validation of the inorganic analysis data (TAL metals andcyanide) prepared by BCM Laboratory for four water samples (twofiltered and two unfiltered) from the Occidental Chemical PlantSite in Pottstown, Pennsylvania, has been completed according tothe U.S. EPA Laboratory Data Validation Functional Guidelines forEvaluating Inorganic Analyses (7/88), with modifications specifiedby EPA Region III. Two rinse blanks (one filtered and oneunfiltered) were associated with these samples. These data werereported by the laboratory under Order Number 43191, which includesthe following samples:

Client Number Lab ID Collected

OXY-TB1GW-1 (Unfiltered) 130414 9/24/91OXY-TB1GW-1 (Filtered) 130415 9/24/91OXY-TB1BGW-1 (Unfiltered) 130416 9/24/91OXY-TB1BGW-1 (Filtered) 130417 9/24/91Rinse Blank (Unfiltered) 130419 9/24/91Rinse Blank (Filtered) 130420 9/24/91

Key findings of the validation effort that resulted inqualification of sample results include:

• Results for copper in Samples OXY-TB1GW-1 (Filtered),OXY-TB1BGW-1 (Unfiltered), OXY-TB1BGW-1 (Filtered), RB(Unfiltered), and RB (Filtered) were qualified as notsignificantly greater than the associated blank level(B).

• Results for arsenic in Samples OXY-TB1GW-1 (Unfiltered)and QXY-TB1GW-1 (Filtered) were qualified as biased lowand not significantly greater than the associated blanklevel (BL).

• Detection limits for arsenic were qualified as biased low(UL) in Samples OXY-TB1BGW-1 (Unfiltered), OXY-TB1BGW-1(Filtered), RB (Unfiltered), and RB (Filtered).

HR305539

\ TRILLIUIVU• Results for selenium in Samples OXY-TB1GW-1 (Unfiltered) ,

OXY-TB1GW-1 (Filtered), OXY-TB1BGW-1 (Unfiltered), OXY-TB1BGW-1 (Filtered), and RB (Filtered) were rejected (R) .

• The result for selenium in RB (Unfiltered) was qualifiedas estimated (UJ) .

• Results for lead were qualified as biased low (L, UL) inSamples OXY-TB1GW-1 (Filtered), OXY-TB1BGW-1(Unfiltered), OXY-TB1BGW-1 (Filtered), and RB(Unfiltered).

• The result for lead in Sample RB (Filtered) was qualifiedas estimated (UJ).

• The result for lead in Sample OXY-TBlGW-1 (Unfiltered)was qualified as biased low and not significantly greaterthan the associated blank level (BL).

• Detection limits for potassium were qualified as biasedlow (UL) in Samples RB (Unfiltered) and RB (Filtered).

• Results for potassium in Samples OXY-TBlGW-1(Unfiltered), OXY-TBlGW-1 (Filtered), OXY-TB1BGW-1(Unfiltered), and OXY-TB1BGW-1 (Filtered) were qualifiedas estimated (J).

• Detection limits for thallium were qualified as biasedlow (UL) in all samples.

• Results for chromium in Samples OXY-TBlGW-1 (Unfiltered)and OXY-TBlGW-1 (Filtered) were qualified as estimated(J).

• Results for chromium in Samples OXY-TB1BGW-1 (Unfiltered)and OXY-TB1BGW-1 (Filtered) were qualified as biased high(K).

• Results for magnesium in Samples OXY-TBlGW-1(Unfiltered), OXY-TBlGW-1 (Filtered), OXY-TB1BGW-1(Unfiltered), and OXY-TB1BGW-1 (Filtered) were qualifiedas estimated (J).

• Results for sodium in Samples OXY-TBlGW-1 (Unfiltered),OXY-TBlGW-l (Filtered), OXY-TB1BGW-1 (Unfiltered), andOXY-TB1BGW-1 (Filtered) were qualified as estimated (J) .

• Results for sodium in Samples RB (Unfiltered) and RB(Filtered) were rejected (R).

SR3Q5590

\ TniLuuiyi.o.• Results for mercury in all samples were qualified as

estimated (J, UJ).

• Results for silver in all samples were qualified asbiased low (UL).

In addition, the following observations were noted duringvalidation of the data package:

• The rinse (field) blanks (RB) were not given uniqueidentification numbers.

• Changes were made to the chain of custody (COG) documentas "write-overs"; the correct procedure is to draw asingle line through an incorrect entry, insert thecorrect entry, and initial and date the change. Becausethey are important legal documents, it is essential thatall COG records be complete, clear, and accuratelycompleted.

HR3Q5591

\ TRILLIUMINTRODUCTION

Analyses were performed according to the USEPA ContractLaboratory Program (CLP) 7/88 Statement of Work. According to thisprotocol, results of sample analyses are reported by the laboratoryas either qualified or unqualified. Unqualified results mean thatthe reported values may be used without reservations. Variousqualifier codes are used by the laboratory (per CLP procedures) todenote specific information regarding the analytical results.

The data validation process is intended to evaluate data on atechnical basis rather than a contract compliance basis forchemical analyses conducted under the USEPA's CLP. An initialassumption is that the data package is presented in accordance withthe CLP requirements. It is also assumed that the data packagerepresents the best efforts of the laboratory and has already beensubjected to adequate quality review prior to submission forvalidation.

During the validation process, laboratory-qualified andunqualified data are verified against all available supportingdocumentation. Based on this evaluation, qualifier codes may beadded, deleted, or modified by the data validator. Final validatedresults are, therefore, either qualified or unqualified.Unqualified results still mean that the reported values may be usedwithout reservation. Validator-qualified results are annotatedwith the following codes in accordance with the Region Ill-modifiedFunctional Guidelines:

U - Not detected. The associated number indicatesapproximate sample concentration necessary to bedetected.

B - Not detected substantially above the level reported inlaboratory or field blanks.

R - Unreliable result. Analyte may or may not be present inthe sample. Supporting data necessary to confirm result.

N - Tentative identification. Consider present. Specialmethods may be needed to confirm its presence or absencein future sampling events.

J - Analyte present. Reported value may not be accurate orprecise.

K - Analyte present. Reported value may be biased high.Actual value is expected to be lower.

AR3Q5592

\ TRILLIUM,»cL - Analyte present. . Reported value may be biased low.

Actual value is expected to be higher.

UJ - Not detected. Quantitation limit may be inaccurate orimprecise.

UL - Not detected. Quantitation limit is probably higher.

These codes are recorded on the Data Summary Forms containedin Attachment A of this validation report and on the InorganicAnalysis Data Sheets ("Form I's") in Attachment B to qualify theresults as appropriate according to the review of the data package.Note that on the Data Summary Forms, all client sample numbers wereabbreviated by eliminating the "OXY" portion in order to fit thenumbers into the available spaces.

Details of the validation findings and conclusions regardingthe reported data are provided in the following sections of thisreport, which represent each of the areas reviewed during inorganicdata validation:

I. Holding Times

II. Calibration

III. Blanks

IV. ICP Interference Check Sample

V. Laboratory Control Sample

VI. Duplicate Sample Analysis

VII. Matrix Spike Sample Analysis

VIII. Furnace Atomic Absorption QC

IX. ICP Serial Dilution

X. Sample Result Verification

XI. Field Duplicates

XII. Other QC

XIII. Documentation

XIV. Overall Assessment

HR305593

\ TRILLIUM,

I. Holding Times

The water samples were collected on September 24, 1991. Allmetals and cyanide analyses were conducted within acceptableholding times.

II. Calibration

All initial and continuing calibrations for metals and cyanidewere satisfactory.

Contract required detection limit (CRDL) standards wereanalyzed as required. Percent recoveries for lead (76%), mercury(50%), and selenium (197%) were outside acceptance limits for theCRDL standards analyzed by atomic absorption. For inductivelycoupled plasma (ICP) analytes, the percent recovery for chromium(141%) in the initial CRDL standard and percent recoveries forsilver (55.5%, 54.5%) in both the initial and final CRDL standardswere outside acceptance limits. The following qualifications wereapplicable based on the CRDL standard:

• Results for lead in all samples were qualified as biasedlow (L, UL) .

• Results for mercury in all samples were qualified asbiased low (L, UL).

• Results for selenium in Samples OXY-TBlGW-1 (Unfiltered) ,OXY-TBlGW-1 (Filtered), OXY-TB1BGW-1 (Unfiltered), OXY-TB1BGW-1 (Filtered), and RB (Filtered) were rejected (R) .

• The result for selenium in Sample RB (Unfiltered) wasqualified as estimated (UJ).

• Results for chromium in Samples OXY-TB1BGW-1 (Unfiltered)and OXY-TB1BGW-1 (Filtered) were qualified as biased high(K).

• Results for silver in all samples were qualified asbiased low (UL).

O

\ TRILLIUM

III. Blanks

Calibration and preparation blanks were prepared and analyzedat the proper frequency for all analytes.

Arsenic, copper, potassium, and selenium were reported inpreparation and calibration blanks at concentrations above theirrespective instrument detection limits (IDLs). Positive sampleresults for potassium were sufficiently high that dataqualification was not warranted. The following qualifications wereapplicable based on calibration and preparation blank results:

• Results for copper in Samples OXY-TBlGW-1 (Filtered),OXY-TB1BGW-1 (Unfiltered), OXY-TB1BGW-1 (Filtered), RB(Unfiltered) , and RB (Filtered) were qualified as notsignificantly greater than the associated blank level(B).

• Results for arsenic in Samples OXY-TBlGW-1 (Unfiltered)and OXY-TBlGW-1 (Filtered) were qualified as notsignificantly greater than the associated blank level(B).

• Results for selenium in Samples OXY-TBlGW-1 (Unfiltered) ,OXY-TBlGW-1 (Filtered), OXY-TB1BGW-1 (Unfiltered), OXY-TBlBGW-l (Filtered), and RB (Filtered) were qualified asnot significantly greater than the associated blank level(B).

Arsenic, lead, potassium, selenium, and thallium were reportedin preparation and calibration blanks at values less than thenegative IDLs for these analytes. The following qualificationswere applicable based on negative blank values:

• Results for arsenic were qualified as biased low (L, UL)in all samples.

• Results for lead were qualified as biased low (L, UL) inall samples.

• Detection limits for potassium were qualified as biasedlow (UL) in Samples RB (Unfiltered) and RB (Filtered).

• Detection limits for thallium were qualified as biasedlow (UL) in all field samples.

Results for thallium for continuing calibration blank #1 andthe preparation blank were recorded incorrectly on the Form III.

INC.

\ TRILLIUMThe correct results were -1.1 B ug/L for the continuing calibrationblank and -2.2 B ug/L for the preparation blank.

Two method blanks were associated with this dataset. Copperwas reported above the IDL in both method blanks; sample resultsfor copper were previously qualified based on calibration andpreparation blank results.

Two RBs were associated with these field samples, oneunfiltered and one filtered. Copper and lead were reported in theunfiltered RB; copper, selenium, and sodium were reported in thefiltered RB. Results for copper and selenium were previouslyqualified based on preparation and calibration blank results. Theresult for lead in Sample OXY-TBlGW-1 (Unfiltered) was qualified asnot significantly greater than the associated blank level (B). Theresults reported for sodium in the unfiltered and filtered RBs wererejected (R) as discussed in Section XII of this validation report.

IV. ICP Interference Check Sample

Interference check sample results were satisfactory; allresults were within the 80 to 120 percent recovery limits.

V. Laboratory Control Sample

All percent recoveries (%R) reported for the laboratorycontrol sample were correctly calculated and accurately reported.All %Rs were within acceptance criteria.

VI. Duplicate Sample Analysis

Laboratory duplicate analyses were performed on Samples OXY-TBlGW-l (Unfiltered) and OXY-TBlGW-1 (Filtered). All results forthe duplicate analysis of OXY-TBlGW-1 (Filtered) met acceptancecriteria. The relative percent difference for mercury in theduplicate analysis of OXY-TBlGW-1 (Unfiltered) was above theacceptance limit. Results for mercury were qualified as estimated(J, UJ) in Samples OXY-TBlGW-1 (Unfiltered), OXY-TB1BGW-1(Unfiltered), and RB (Unfiltered).

The result for arsenic for the laboratory duplicate of OXY-TB1GW-1 (Unfiltered) was reported incorrectly on the Form VI. Thecorrect result was 1.4 ug/L. The result for selenium for thelaboratory duplicate of OXY-TBlGW-1 (Filtered) was reportedincorrectly on the Form VI. The correct result was 1.97 ug/L.

INC.

AR3G5596

\TRILLIUM,VII. Matrix Spike Sample Analyses

Matrix spike analyses were conducted on Samples OXY-TBlGW-1(Unfiltered) and OXY-TBlGW-1 (Filtered). The %R for selenium(72.5%) in the matrix spike analysis of OXY-TBlGW-1 (Unfiltered)was below the acceptance criterion. Results for selenium in allunfiltered samples were qualified as biased low (L).

The %Rs for mercury (145%) and selenium (70%) were outsideacceptance limits in the matrix spike analysis of OXY-TBlGW-1(Filtered). Results for mercury were qualified as estimated (UJ)and results for selenium were qualified as biased low (L, UL) inall filtered samples.

VIII. Furnace Atomic Absorption QC

The post digestion spike recoveries for selenium (127.7%) inRB (Unfiltered) and for lead (116%) and selenium (128.8%) in SampleRB (Filtered) were outside acceptance limits of 85 to 115 percent.The result for selenium in RB (Unfiltered) and the results for leadand selenium in RB (Filtered) were qualified as estimated (J, UJ).

IX. ICP Serial Dilution

Serial dilution analyses were performed on OXY-TBlGW-1(Unfiltered). Percent differences for chromium (13.0%), magnesium(13.1%), potassium (44.3%), and sodium (47.3) were above theacceptance limit of 10 percent. Positive sample results werequalified as follows:

• Results for chromium in Samples OXY-TBlGW-1 (Unfiltered)and OXY-TBlGW-1 (Filtered) were qualified as estimated(J).

• Results for magnesium in Samples OXY-TBlGW-l(Unfiltered), OXY-TBlGW-1 (Filtered), OXY-TB1BGW-1(Unfiltered), and OXY-TB1BGW-1 (Filtered) were qualifiedas estimated (J).

• Results for potassium in Samples OXY-TBlGW-1(Unfiltered), OXY-TBlGW-1 (Filtered), OXY-TB1BGW-1(Unfiltered), and OXY-TB1BGW-1 (Filtered) were qualifiedas estimated (J).

• Results for sodium in Samples OXY-TBlGW-1 (Unfiltered),OXY-TBlGW-1 (Filtered), OXY-TB1BGW-1 (Unfiltered), andOXY-TB1BGW-1 (Filtered) were qualified as estimated (J) .

AB30S59

TRILLIUM,NC.

X. Sample Result Verification

Calculations were performed correctly, and results wereaccurately reported.

XI. Field Duplicates

No field duplicate pair was submitted for analysis with thissample set.

XII. other QC

Samples were submitted for both total and dissolved metalsanalyses. Results of the unfiltered and filtered sample pairs wereacceptable with one exception. Sodium was reported in the filteredRB but was not detected in the unfiltered RB. The results forsodium in RB (Unfiltered) and RB (Filtered) were rejected (R) .

XIII. Documentation

A COC record documenting all pertinent samples was included inthe data package. Changes were made to the document as "write-overs"; the correct procedure is to draw a single line through anincorrect entry, insert the correct entry, and initial and date thechange. Because they are important legal documents, it isessential that all COC records be complete, clear, and accuratelycompleted.

The sample numbers used on the COC record were not recorded onForm I (sample results) for each sample. On the custody recordincluded in the data package, however, the laboratory ID isrecorded in the far left column. This does establish a direct linkbetween the COC documentation and the reported results, and is animprovement over earlier data packages reviewed for this project.

The field (rinse) blanks were not given unique identificationnumbers, but were recorded on the chain of custody record as simply"Rinse Blank." The use of unique sample numbers for the RB wasinitiated with the last set of groundwater samples collected forthis project; it is not clear why the practice was not continuedhere.

10

AR3Q5598

\ TRILLIUM,

XIV. Overall Assessment

Inorganics data were acceptable as reported with the followingexceptions:

• Results for copper in Samples OXY-TBlGW-1 (Filtered),OXY-TB1BGW-1 (Unfiltered), OXY-TB1BGW-1 (Filtered), RB(Unfiltered) , and RB (Filtered) were qualified as notsignificantly greater than the associated blank level(B).

• Results for arsenic in Samples OXY-TBlGW-1 (Unfiltered)and OXY-TBlGW-1 (Filtered) were qualified as "BL"; the"B" indicating that it was not significantly higher thanassociated blank contamination and the "L" due tonegative blank values.

• Detection limits for arsenic were qualified as biased low(UL) in Samples OXY-TB1BGW-1 (Unfiltered), OXY-TB1BGW-1(Filtered), RB (Unfiltered), and RB (Filtered) based onnegative blank results.

• Results for selenium in Samples OXY-TBlGW-1 (Unfiltered) ,OXY-TBlGW-1 (Filtered), OXY-TB1BGW-1 (Unfiltered), OXY-TB1BGW-1 (Filtered), and RB (Filtered) were qualifiedwith a "B" due to associated blank contamination, asrejected based on the high %R for the CRDL standard, asbiased low based on low %Rs for the matrix spikeanalysis, and, in the case of RB (Filtered) , as estimateddue to the high post digestion spike recovery. Based onthe hierarchy of qualifier codes used by Region III,selenium in these samples was rejected (R).

• The result for selenium in RB (Unfiltered) was qualifiedas estimated due to the high %R of selenium in the CRDLstandard and the high post digestion spike recovery;selenium was qualified as biased low due to the low %R inthe matrix spike analysis. Based on the hierarchy ofqualifier codes used by Region III, selenium in RB(Unfiltered) was qualified as estimated (UJ).

• Results for lead were qualified as biased low (L, UL) inSamples OXY-TBlGW-1 (Filtered), OXY-TB1BGW-1(Unfiltered), OXY-TB1BGW-1 (Filtered), and RB(Unfiltered) based on negative blank values and on thelow %R of lead in the CRDL standard.

11

HR305599

\ TRILLIUM,*,The result for lead in Sample RB (Filtered) was qualifiedas estimated based on negative blank results and the highpost digestion spike recovery; lead was qualified asbiased low due to the low %R of lead in the CRDLstandard. Based on the hierarchy of qualifier codes usedby Region III, lead in RB (Filtered) was qualified asestimated (UJ).

The result for lead in Sample OXY-TBlGW-1 (Unfiltered)was qualified as "BL". The "B" indicated that lead inthis sample was not significantly higher than associatedblank contamination. The "L" qualifier was applied toreflect the low %R for the CRDL standard and negativeblank values.

Detection limits for potassium were qualified as biasedlow (UL) in Samples RB (Unfiltered) and RB (Filtered)based on negative blank results.

Results for potassium in Samples OXY-TBlGW-1(Unfiltered), OXY-TBlGW-1 (Filtered), OXY-TB1BGW-1(Unfiltered), and OXY-TB1BGW-1 (Filtered) were qualifiedas estimated (J) based on results of the serial dilutionanalysis.

Detection limits for thallium were qualified as biasedlow (UL) in all samples based on negative blank results.

Results for chromium in Samples OXY-TBlGW-1 (Unfiltered)and OXY-TBlGW-1 (Filtered) were qualified as estimated(J) based on results of the serial dilution analysis.

Results for chromium in Samples OXY-TB1BGW-1 (Unfiltered)and OXY-TB1BGW-1 (Filtered) were qualified as biased high(K) due to the high %R of chromium in the initial CRDLstandard.

Results for magnesium in Samples OXY-TBlGW-1(Unfiltered), OXY-TBlGW-1 (Filtered), OXY-TB1BGW-1(Unfiltered), and OXY-TB1BGW-1 (Filtered) were qualifiedas estimated (J) based on results of the serial dilutionanalysis.

Results for sodium in Samples OXY-TBlGW-1 (Unfiltered),OXY-TBlGW-1 (Filtered), OXY-TB1BGW-1 (Unfiltered), andOXY-TB1BGW-1 (Filtered) were qualified as estimated (J)based on results of the serial dilution analysis.

12

3R3G56QG

\TRILLIUM

• Results for sodium in Samples RB (Unfiltered) and RB(Filtered) were rejected (R) due to poor comparison ofthe filtered and unfiltered sample results.

• Results for mercury in Samples QXY-TBlGW-l (Unfiltered) ,OXY-TB1BGW-1 (Unfiltered) , and RB (Unfiltered) werequalified as biased low based on results of the CRDLstandard and as estimated based on the laboratoryduplicate analyses. Based on the hierarchy of qualifiercodes used by Region III, mercury in these samples wasqualified as estimated (J, UJ) .

• Results for mercury in Samples OXY-TBlGW-1 (Filtered) ,OXY-TB1BGW-1 (Filtered) , and RB (Filtered) were qualifiedas biased low based on results of the CRDL standard andas estimated based on the matrix spike analysis. Basedon the hierarchy of qualifier codes used by Region III,mercury in these samples was qualified as estimated (UJ) .

• Results for silver in all samples were qualified asbiased low (UL) based on the low %Rs of silver in theCRDL standards.

The following observations were also made with respect to thedata package:

• The rinse (field) blanks (RB) were not given uniqueidentification numbers.

• Changes were made to the chain of custody (COC) documentas "write-overs" ; the correct procedure is to draw asingle line through an incorrect entry, insert thecorrect entry, and initial and date the change. Becausethey are important legal documents, it is essential thatall COC records be complete, clear, and accuratelycompleted.

,NC.

13

SR3Q560!

TRILLIUM INC.

ATTACHMENT A

Data Summary Form: order #43191

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\ TRILLIUM.NC.

ATTACHMENT B

Inorganic Analysis Data Sheets(Form I's)

Order #43191

HR3Q56

ENVTROFORMS/INORGANIC CLPSAMPLE NO.

1INORGANIC. ANALYSIS DATA SHEET

1 1 3 0 4 1 4ab Name: BCM LABORATORY DIVISION Contract: OXYCHEM

Lab Code: BCM Case No.: 43191 SAS No.: , SDG No.: A43191

Matrix (soil/water): WATER Lab Sample ID: 130414-UF

Level (low/med): LOW Date Received: 09/24/91

% Solids: 0.0

Concentration Units (ug/L or mg/kg dry weight): UG/L

CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-0"7440-62-27440-66-6

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLead'MagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

Concentration

U 10321.0a. en47.01.42.8

33900290

C22 . 5.147.05163.4

18000•. 3140.50"46.4

260000- l.C -2.3

1290001.0

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flR305605

ENVIROFORMS/INORGANIC CLPSAMPLE NO.

1INORGANIC ANALYSIS DATA SHEET

130415Lab Name: BCM LABORATORY DIVISION Contract: OXYCHEM

Lab Code: BCM Case No.: 43191 SAS No.: SDG No.: A43191

Matrix (soil/water): WATER , Lab Sample ID: 130415-F-


% Solids: 0.0


CAS No.

7429-9.0-57440-36-07440-^38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

Concentration

50.021.0ri.aEi47.01.42.8

C4580J280

C18.O25.4

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265000— 1.0 '2.3

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Comments:

000008FORM i - IN 5R305606


1 ' _________INORGANIC.ANALYSIS DATA SHEET

130416.b Name: BCM LABORATORY DIVISION Contract: OXYCHEM


Matrix (soil/water): WATER Lab Sample ID: 130416-UF


% Solids: 0.0


GAS No.

7429-90-5 .7440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

C53..0121.00.9047.01.42.8

11700C8.8Di.Sp0.1.231160.90159002150.2043.7

142000— 0.-5-5

2.3865001.010.033.2

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000009FORM i -IN flR305607



130417Lab Name: BCM LABORATORY DIVISION , Contract: OXYCHEM


Matrix (soil/water): WATER Lab Sample ID: 130417-


% Solids: 0.0


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-6 '7440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-6.2-27440-66-6

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodium •ThalliumVanadiumZincCyanide

Concentration

50.021.00.9047.01.42.8

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Comments:

000010FORM i - IN AR305608


1 _________INORGANIC ANALYSIS DATA SHEET

130419ab Name: BCM LABORATORY DIVISION Contract: OXYCHEM

Lab Code: BCM Case Nq.: 43191 SAS No.: SDG No.: A43191

Matrix (soil/water): WATER Lab Sample ID: 130419RB-


% Solids: 0.0


GAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

50.021.00.9047.01.42.87554.0

11.0C4.83

• 18.0a. 436444.0

0.2010.0577

0.502.3

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1 _________INORGANIC.ANALYSIS DATA SHEET





% Solids: 0.0


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-4.7440-23-57440-28-07440-62-27440-66-6

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCqppjerIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCvanide

Concentration

50.021.00.9047.01.42.87554.0

11.0C4.2J18.00.906444.0

0.2010.0577

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Comments:

•000012

FORM i B, AR3056IO

Attachment C

AR3G56II

3CM uooratory fenaivtical I-ata Pac.<jgs

3CS Laooratory Division1350 Gravers Road _ . . .Sorristonm. " ? A i94Qi • _ _ _ _ _ _ _ _ _ _

i £ata P'cxagesrt. ? : :vj 77175 i

: ?i 46-.07 i Client: :CCi:<E!iTAL C.-.-HICAL

Project No.: vO-4064-13

i Project Manager:i! Order: 43191

-OCATIOS SAH?-_E ID BCM No. LOCATION SAMPLE III BCM No. LOCATION SAMPLE ID BCM No.

OXY-731GH uKFILTERED 130414' OXY-T3Gii-l FILTERED 130415 OXY-TBi2Gy-l UNFILTESED 130416•jXY-TBiBSy-1 FIL~?.E5 130417 RINSE BLANK UNFILTESED 130419 RINSE BLANK FILTERED 130420>ITHQ3 BLANK 130422 i)U? 130414 130423 SPIKE 130414 130424'JETKC'D BLANK _ 130425 DUP 130415 130426 SPIKE 130415 130427

This case includes the following packages: 3Crt Subcontractor

GC/MS VoiatiiesGC/MS Seni-Volatiles C /X' C 3

Metais 'M E 1Micro [ is' L 3

wetChefi Itif.s' C 3GC CvT C 3

This is trie Metais oackaae for tnis case

Data PacKace audited "o"

000001

^3056(2



130415,Lab Name: BCM LABORATORY DIVISION Contract: OXYCHEM


Matrix (soil/water): WATER Lab Sample ID: 130415-F-


% Solids: 0.0


CAS NO.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

50.021.01.8

47.01.42.8458028018.125.429.30.9069204.00.2047.1

2650001.62.3

1310001.0

10.027.0

C

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000008FORM I - IN



Comments:

AR3056I3



1 1 3 0 4 2 0b Name: BCM LABORATORY DIVISION Contract: OXYCHEM




% Solids: 0.0


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

50.021.00.9047.01.42.87554.011.04.218.00.906444.00.2010.05770.652.311901.010.04.0

C

UuuuuuuuuBUUuuuuuBUBUUU

Q

E

W

N

ENW

E

M


tarnmc



nents:

000012

-IN /1R3056U





Matrix (soil/water): WATER Lab Sample ID: 130422MB-


% Solids: 0.0


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

50.021.00.9047.01.42.87554.011.04.518.00.906444.00.2010.05770.502.35521.010.04.02.0

C

UUuuuuuuuBUuuuuuuuuuuuuu

Q

E

*

ENW

E

M




Comments:

000013FORM I - IN

AR3Q56I5

ENVIROFORMS/INORGANIC CLP

2AINITIAL AND CONTINUING CALIBRATION VERIFICATION

Lab Name: BCM LABORATORY DIVISION Contract: OXYCHEM


Initial Calibration Source: IV

Continuing Calibration Source: IV

Concentration Units: ug/L

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCvanide

Initial CalibrationTrue Found %R(l)

10000.01000.0

40.010000.0250.02500.025000.01000.02500.01250.05000.042.7

25000.02500.0

4.02500.025000.0

65.2275.0

25000.021.2

2500.02500.0120.0

10102.00950.0039.85

10011.00249.102472.4024779.00'1006.702572.101179.705066.6044.70

24438.002333.70

3.902539.0024677.00

62.30269.20

24546.0022.55

2447.702542.90104.00

101.095.099.6100.199.698.999.1100.7102.994.4101.3104.797.893.397.5101.698.795.697.998.2106.497.9101.786.7

Continuing CalibrationTrue Found %R(1) Found %R(1)

10000.01000.0

40.010000.0250.02500.025000.01000.02500.01250.05000.042.7

25000.02500.0

4.02500.025000.0

65.2275.0

25000.021.2

2500.02500.0120.0

10316.001000.0039.10

10246.00254.102559.8025821.001050.102657.201198.505224.8046.40

24831.002432.80

4.202607.7025263.00

61.60276.90

24351.0021.35

2510.802665.90104.00

103.2100.097.8102.5101.6-102.4103.3105.0106.395.9104.5108.799.397.3105.0104.3101.194.5100.797.4100.7100.4106.686.7

10180.00949.3038.70

9703.40243.302396.2024293.00995.602516.001186.305004.8044.70

24550.002320.40

3.902472.2025225.00

58.50269.20

23276.0022.25

2420.802526.20105.00

101.894.996.897.097.395.897.299.6100.694.9100.1104.798.292.897.598.9100.9*K>97.993.1105.096.8101.087.5

M


(1) Control Limits : Mercury 80-120; Other Metals 90-110; Cyanide 85-115

FORM II (PART 1) - IN

000016





Initial Calibration Source:



Analyte


Initial CalibrationTrue Found %R(1)

————

—— : —


40.0

42.7

25000.065.2

25000.021.2

120.0

38.80

45.65

23970.0058.90

23662.0020.45

105.00

97.0

106.9

95.990.3

94.696.5

87.5

10164.00940.2040.90

9761.80245.102405.2024388.00999.602527.601183.304988.30

24610.002323.90

2479.8025176.00

61.40270.00

23904.0019.55

2425.602537.30

101.694.0

102.297.698.096.297.6

100.0101.194.799.8

98.493.0

99.2100.794.298.295.692.297.0

101.5

M

PPF

P

*PPPFPP

PPFPPFPPAS



000017 SR3056I7








Analyte

AluminumAntimonyArsenicBariumBerylliumrcadmiumfcalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide



40.0

65.2

21.2

39.85

60.40

21.45

99.6

92.6

101.2

62.90

19.60

————

96.5

92.5————

____

M

F~—

F

F



oooois








Analyte




65.2

21.2

64.60

22.10

99.1

104.2

63.70

————

97.7————

M

—

f—

F

F_



oooois flR3056i9








Analyte




65.2 68.50 105.1 63.70

————

97.7

M

—

—

—

F



W30562Q








Analyte




65.2 63.50

,

97.4 61.90

————

————

————

94.9

————

M

Ir—

F



000021 AR30562!






Continuing Calibration Source: IVt


Analyte

AluminumAntimonyArsenicBariumBeryllium^CadmiumFCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

Initial CalibrationTrue Found %R ( 1 )


65.2 63.60 97.5

_

————

————

————

————

————

————

M

—

—

F

€



000022 flR305622


2BCRDL STANDARD FOR AA AND ICP



AA CRDL Standard Source: IV

ICP CRDL Standard Source: IV


Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZinc

CRDL St

True

10.0

6.0

0.2

5.0

10.0

.andard for

Found

9.80

4.60

0.10

9.85

10.70•

"„ AA%R

98.0

76.7

50.0

197.0

107.0

True

400.0120.0

400.010.010.0

10000.020.0

100.050.0200.0

10000.030.0

80.010000.0

20.010000.0

100.040.0

CRDL StarInitialFound

423.60132.30

422.2010.7011.80

10704.0028.20109.4054.90212.10

10715.0030.30

86.3010556.00

11.1010374.00

105.6045.90

idard f

%R

105.9110.2

105.6107.0118.0107.0141.0109.4109.8106.0

107.2101.0

107.9105.6

55.5103.7

105.6114.8

'or ICPFound

Found

393.40120.70

396.709.908.70

9907.9021.00100.3053.50199.50

10535.0028.50

85.0011284.00

10.9010384.00

92.9039.30

1

L%R

98.4100.6

99.299 )£jflhl^ W105.0100.3107.099.8

105.495.0

106.2112.8

54.5103.8

92.998.2


000023 AR305623

i - -ft. . - IENVIROFORMS/INORGANIC CLP

3BLANKS



Preparation Blank Matrix (soil/water): WATER

Preparation Blank Concentration Units (ug/L or mg/kg): UG/L

Analyte


InitialCalib.Blank(ug/L) C

50.021.0-0.947.01.42.8

755.04.011.04.318.0

- -i.o644.04.00.210.0

-684.70.52.3

552.01.010.04.02.0

UUBUUUUUUBUBUUUUBUUUUUUU

Continuing CalibrationBlank (ug/L)

1C 2 C 3 C

50.021.00.9

47.01.42.8

755.04.011.04.618.00.9

644.04.00.210.0577.00.52.3

552.01.010.04.02.0

UUUUUUUUUBUUUUUUUuuuuuuu

50.021.00.947.01.42.8

755.04.011.04.518.00.9

644.04.00.210.0577.00.52.3

552.0-1.410.04.02.0

UUuuuuuuuBUUUuuuuuuuBUUu

-0.9

0.9

-595.80.5

552.0-1.6

2.0

B

U

BU

UB

U

Prepa-rationBlank C

50.021.0-1.747.01.42.8

755.04.011.05.618.00.9

644.04.00.210.0577.0-0.62.3

552.0-1.210.04.02.0

UUBUUUUUUBUUUUUUUBUUBUUU

M,


FORM III - IN

000024


3BLANKS





Analyte

AluminumAntimony^ArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide



1 C 2 C 3 C

50.021.01.047.01.42.8

755.04.011.04.218.0

644.04.0

10.0657.20.52.3

552.01.010.04.0

UUBUUUUuuBU

UU

UBUUUUUU

0.9

0.5

1.0

U

u

u

0.5

-2.3

U

B

Prepa-rationBlank C M

PPFP|>

PPPP

PP

PPFPPFPP

FORM III - IN

000025AR3Q5625


3BLANKS





Analyte




1 C 2 C 3 C

0.5

1.0

U

U

0.5 U 0.5

•

B

Prepa-rationBlank C

—

M

F

F

_

FORM III - IN

000026


3BLANKS





Analyte



.


1 C 2 C 3 C

0.7 B 0.5 U 0.5 U

Prepa-rationBlank C

—

M

1

F

FORM III - IN

°00027 HR305627


3BLANKS





Analyte




1 C 2 C 3 C

-0.6

—

—

B

Prepa-rationBlank C M

F

FORM III - IN

000028


4ICP INTERFERENCE CHECK SAMPLE



ICP ID' Number: JY50 ICS Source: IV


Analyte


TrueSol. Sol.A AB

500000

500000

200000

500000

500000

500500

1000500000

500500500

200000

500000500

1000

1000

5001000

Initial FoundSol. Sol.A AB %R

473660-65

19056

4659507642-1

173000

45098027

10-1701

-39-713

338

473760.0-110.5

475.0446.9918.3

459360.0513.3468.2427.5

171260.0

452050.0440.9

863.7-968.1

929.0-427.0

447.0914.5

94.8

95.089.491.891.9

102.793.685.585.6

90.488.2

86.4————

92.9

89.491.4

Final FoundSol. Sol.A AB %R

465650-92

18053

4418807041-2

165590

44292026

7-1000

-38-569

-637

468320.0-86.0

449.3428.0870.6

436810.0496.1448.5420.1

164380.0

447240.0425.1

815.0-212.2

910.9-415.1

423.7883.3

93.7————

89.985. 187. •!87. W99.289.784.082.2

89.485.0

81.5

91.1

84.788.3

FORM IV - IN

000029 5R305629


5A SAMPLE NO.SPIKE SAMPLE RECOVERY

130415SLab Name: BCM LABORATORY DIVISION Contract: OXYCHEM

Lab Code: BCM ' Case No.: 43191 SAS No.: SDG No.: A43191

Matrix (soil/water): WATER Level (low/med): LOW% Solids for Sample: 0.0


Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobalt(Copper'ironLeadMagnesiumManganeseMercury^NickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

ControlLimit%R

75-12575-12575-12575-12575-12575-125

75-125-75-12575-12575-12575-125

75-12575-12575-125

75-12575-125

75-12575-12575-125

Spiked SampleResult (SSR)

2047.6000542.700040.8000

2056.200049.000050.6000

479.5000528.6000273.40001053.900022.1500

477.00002.9000

568.4000

8.550054.6000

48.8000508.0000563.7000

CSample

Result (SR)

50.000021.00001.800047.00001.40002.8000

280.500018.100025.400029.30000.9000

4.00000.200047.1000

1.55002.3000

1.000010.000027.0000

C

UuBUUU

B

BU

UU

BU

UU

SpikeAdded (SA)

2000.00500.0040.00

2000.0050.0050.00

200.00500.00250.001000.0020.00

500.002.00

500.00

10.0050.00

50.00500.00500.00

%R

102.4108.597.5

102.898.0

101.2

99.5102.199.2

102.5110.8

95.4145.0104.3

70.0109.2

97.6101.6107.3

Q

N

N

M

PPFPPPNRPPPPFNRPCVPNRFPNRFPPNR

Comments:

FORM V (PART 1) - IN

000031 ' flft30563Q


6 SAMPLE NO.DUPLICATES

130415DLab Name: BCM LABORATORY DIVISION Contract: OXYCHEM

Lab Code: BCM ' Case No.: 43191 SAS No.: SDG No.: A43191

Matrix (soil/water): WATER Level (low/med): LOW

% Solids for Sample: 0.0 % Solids for Duplicate:


Analyte


ControlLimit

25.0

5000.0

40.0

20.0

Sample (S)

50.000021.00001.800047.00001.40002.8000

4581.8000280.500018.100025.400029.30000.9000

6917.60004.00000.200047.1000

264580.00001.55002.3000

130870.00001.000010.000027.0000

C

UuBUUUB

B

BU

UU

BU

UU

Duplicate (D)

50.000021.00000.900047.00001.40002.8000

4396.4000270.400015.000022.400098.70000.9000

6884.20004.00000.200046.9000

269400.00001.95002.3000

134530.00001.000010.000022.2000

C

UuuuuuB

BBBU

UU

BU

UU

RPD

200.0

4.13.7

18.712.6

108.4

0.5

0.41.8

22.9

2.8

19.5

Q M

PPFPPPPiipFPPCVPPFPPFPP

FORM VI - IN

000035 AR30563I


7LABORATORY CONTROL SAMPLE



Solid LCS Source: ERA

Aqueous LCS Source: IV

Analyte

AluminumAntimonyArsenicBariumJery IliumfcadmiumValciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

Aqueous (ug/L)True Found %R

2000.0500.040.0

2000.050.050.0

5000.0200.0500.0250.01000.020.0

5000.0500.02.0

500.05000.010.050.0

5000.050.0500.0500.0

1959.00473.9043.15

1973.4047.0047.40

5553.00208.50503.20236.901047.2022.65

4886.90473.002.00

506.104429.90

9.7054.00

4585.8051.85484.80490.70

98.094.8107.998.794.094.8111.1104.2100.694.8104.7113.297.794.6100.0101.288.697.0108.091.7

103.797.098.1

Solid (mg/kg)True Found C Limits %R

—

—

FORM VII - IN

000036 3R305632


9 SAMPLE NO.ICP SERIAL DILUTIONS

130415LLab Name: BCM LABORATORY DIVISION Contract: OXYCHEM

Lab Code: BCM • Case No.: 43191 SAS No.: SDG No.: A43191

Matrix (soil/water): WATER Level (low/med): LOW


Analyte


Initial SampleResult (I)

50.0021.00

47.001.402.80

4581.80280.5018.1025.4029.30

6917.604.00

47.10264580.00

2.30130870.00

10.0027.00

C

UU

uuuB

B

B

U

U

U

SerialDilutionResult (S)

250.00105.00

235.007.0014.00

11548.50317.0055.00157.00164.50

7824.5020.00

133.50381685.00

11.50192790.00

50.00417.50

C

UU

UUUB

U

B

BU

B

U

U

%Differ-ence

152.113.0100.0518.1461.4

13.1

183.444.3

47.3

*****

Q

E

E

E

M

PP

PPPPPPPP

PP

PP

PP

PP

FORM IX - IN

000038 flR305633


10INSTRUMENT DETECTION LIMITS (QUARTERLY)

fab Name: BCM LABORATORY DIVISION Contract: OXYCHEM


ICP ID Number: JY50 , Date: 09/12/91

Flame AA ID Number:

Furnace AA ID Number:

imments:

Analyte


Wave-length(nm)

308.07206.83

233.53313.04226.50317.93267.72228.62324.75259.94220.35279.08257.61

231.60766.49

328.07589.59

310.23231.86

Back-ground

CRDL(ug/L)

200.060.010.0200.05.05.0

5000.010.050.025.0100.03.0

5000.015.00.2

40.05000.0

5.010.0

5000.010.050.020.0

IDL(ug/L)

50.021.0

47.01.42.8

755.04.0

' 11.03.7

18.020.0644.04.0

10.0577.0

2.3552.0

10.04.0

M

PP

PPPPPPPPPPP

PP

PP

PP

000063FORMX'IN





ICP ID Number: Date: 09/19/91

Flame AA ID Number:

Furnace AA ID Number: 5100

Comments:

Analyte


Wave-length(nm)

217.60193.70

283.30

196.00

276.80

Back-ground

BZBZ

BZ

BZ

BZ

CRDL(ug/L)

200.060.010.0200.05.05.0

5000.010.050.025.0100.03.0

5000.015.00.240.0

5000.05.010.0

5000.010.050.020.0

IDL(ug/L)

0.9

0.5

1.0

M

F~

——

——

——

——

F

F

000064FORM x - I N AR3Q5635



.b Name: BCM LABORATORY DIVISION Contract: OXYCHEM

Lab Code: BCM . Case No.: 43191 SAS No.: SDG No.: A43191


Flame AA ID Number:

Furnace AA ID Number: 2100

omments:

Analyte


Wave-length(nm)

283.30

Back-ground

BD

CRDL(ug/L)

200.060.010.0200.05.05.0

5000.010.050.025.0

100.03.0

5000.015.00.2

40.05000.0

5.010.0

5000.010.050.020.0

IDL(ug/L)

0.9

M

F

000065FORM X - IN






Flame AA ID Number:


Comments:

Analyte

AluminumAntimony^ArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZinc

Wave-length(nm)

253.70

Back-ground

CRDL(ug/L)

200.060.010.0200.05.05.0

5000.010.050.025.0

100.03.0

5000.015.00.240.0

5000.05.0

10.05000.0

10.050.020.0

IDL(ug/L)

0.2

M

——

——

CV——

000066FORMX-IN flR305637



ab Name: BCM LABORATORY DIVISION Contract: OXYCHEM



Flame AA ID Number:


omments:

Analyte

AluminumAntimonyArsenicBariumBeryl liumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZinc

Wave-length(nm)

Back-ground

CRDL(ug/L)

200.060.010.0200.05.05.0

5000.010.050.025.0

100.03.0

5000.015.00.2

40.05000.0

5.010.0

5000.010.050.020.0

IDL(ug/L) M

00006?-IN flR305638


11AICP INTERELEMENT CORRECTION FACTORS (Annually)



ICP ID Number: JY50 Date: 01/02/91

Analyte


Wave-length(nm)

308.22206.83

233.53313.04226.50317.93267.72228.62324.75259.94220.35279.08257.61

231.60766.49

328.07589.59

310.23213.86

Ir

Al

0.0033000

0.0005500

iterelement

Ca

Correction

Fe

Factors foi

Mg

* •

cu

••——

0.0100000

Comments:

000068FORM XI (PARTI) -IN


11BICP INTERELEMENT CORRECTION FACTORS (Annually)




Analyte


Wave-length(nm)

308.22206.83

233.53313.04226.50317.93267.72228.62324.75259.94220.35279.08257.61

231.60766.49

328.07589.59

310.23213.86

Ir

CR

0.0080000

0.0006000

iterelement

V

0.0252000

0.0010400

Correction

NI

0.0048000

Factors foi• •

omments:

000069FORM XI (PART 2) - IN


12ICP LINEAR RANGES (QUARTERLY)




Comments:

Analyte


Integ.Time(Sec.)

5.005.00

5.005.005.005.005.005.005.005.005.005.005.00

5.005.00

5.005.00

5.005.00

Concentration(ug/L)

197000.059500.0

192000.049900.020300.0202000.052900.051600.048400.096600.049200.0218000.048500.0

21000.0509000.0

6200.0482000.0

47400.051900.0

M

PP

PPPPPPPPPPP

PP

PP

PP

000070-IN 8R3056U


11AICP INTERELEMENT CORRECTION FACTORS (Annually)



ICP ID Number: 6500 Date: 10/01/90

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumIchromiumrcobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZinc

Wave-length(nm)

Ir

Al

iterelement

Ca

Correction

Fe

Factors foi

Mg

•• *

<

[omments:NOT APPLICABLE - INSTRUMENT IS A SEQUENTIAL ICP

000071FORM XI (PART 1) - IN


11BICP INTERELEMENT CORRECTION FACTORS (Annually)




Analyte


Wave-length(nm)

Iriterelement Correction Factors foi• •

— J——— IB——— [

Comments:NOT APPLICABLE - INSTRUMENT IS A SEQUENTIAL ICP

000072 FOEMXI(PART2)-INflR3056i*3


12ICP LINEAR RANGES (QUARTERLY)




omments:

»

Analyte


Integ .Time(Sec.)

1.00

1.001.001.001.001.001.001.001.001.001.001.00

1.001.00

1.001.00

1.001.00

Concentration(ug/L)

10253.0

4823.0491.0494.0

20040.01037.01957.01969.05104.020000.019840.01475.0

3846.051540.0

1015.020115.0

5000.01985.0

M

——

——

——

000073FORM XII - IN

*Pb 0.00242/ 76O7. *Cd V.OOO63/ 667. $Co O.<02246/ 5.17. $Ni O."o4643/ 137.

$Ba 0.03453/ 2.67. *Mn 0.31375/ 0.307. *Fe O.51568/ 0.297. *Cr 0.29038/ 1 . 17.

$Mg 18.0207 0.267. $A1 0. 10979 / 3.07. $V -O.O0200/ 447. *Be-O.00011/ 317.33. <? ~OH~>v .Doz3

*Ca 33.S54/ 0.137. *Cu 0. 04699 / 0.777. *Ag 0.00014/ 3307.

Measurements for 130415-F- 1

Elements of SIMULTANEOUS

*As 193.699 0.46200 0.0000 0.458OO O.O04OO O.O4172 PPM0.47800 0.0000 0.44400 0.03400 0.13559 PPM0.46600 0.0000 0.46400 0.00200 0.03546 PPM

$Se 196.030 0.74800 0.80600 0.0000-0.05800-O.08992 PPM0.754OO 0.7S4OO 0.OOOO-O.O3OOO-O.04330 PPM0.78600 0.77200 0.0000 O.O1400 0.02997 PPM

*Sb 206.333 1.7620 0.0000 1.7680-O.00600 0.00196 PPM1.76OO O.OOOO 1.7860-0.O26OO-O.OO539 PPM1.7540 0.0000 1.7560-0.O020O 0.00343 PPM

$Zn 213.856 1.2940 0.0000 0.73800 0.55600 O.02511 PPM1.3500 O.OOOO 0.7500O O.6OOOO O.02774 PPM1.3520 O.OOOO 0.744OO 0.6OSOO O.02822 PPM

*Pb 220.353 4.0420 4.1520 0.0000-0.11OOO-O.02761 PPM4.160O 3.9560 O.OOOO 0.20400 O.O1802 PPM4.164O 4.1220 0.0000 0.04200-0.00552 PPM

*Cd 226.502 1.4540 0.0000 1.4640-0. OlOOO-O.00150 PPM1.4720 O.OOOO 1.4320 O.O4OOO O.OO125 PPM1.5100 O.OOOO 1.4980 0.01200-O.O0029 PPM

$Co 228.616 1.9680 O.OOOO O.OOOO 1.9680 O.O1867 PPM1.9760 0.0000 0.0000 1.976O O.O1917 PPM1.9340 0.0000 O.OOOO 1.9340 O.01654 PPM

$Ni 231.604 2.996O 0.0000 2.3780 0.61800 0.04683 PPM3.0660 0.0000 2.3720 0.694OO O.O5255 PPM2.9920 0.0000 2.4380 0.55400 0.04200 PPM

$Ba 233.527 1.6660 0.0000 1.1660 0.50000 0.01942 PPM1.6820 0.0000 1.1620 0.52000 0.02022 PPM1.6760 0.0000 1.1880 0.48800 0.01895 PPM

$Mn 257.610 1.378O O.OOOO 1.3120 0.O66OO-O.OO004 PPM1.4O8O O.OOOO 1.3OSO O.1OOOO O.O0042 PPM1.3820 O.OOOO 1.33OO 0.O52OO-O.O0022 PPM

*Fe 259.940 4.6640 O.OOOO 0.0000 4.6640 O.02778 PPM4.7660 O.OOOO O.OOOO 4.7660 O.03027 PPM4.7460 0.0000 0.0000 4.7460 0.02979 PPM

$Cr 267.716 4.1240 1.5100 0.0000 2.6140 0.27648 PPM4.1720 1.5120 0.0000 2.6600 0.28130 PPM4.2420 1.5600 0.0000 2.6820 0.28361 PPM

$Mg 279.079 15.524 1.2860 1.364O 14.199 6.8445 PPM15.666 1.3060 1.3520 14.337 6.9110 PPM15.858 1.2920 1.3920 14.516 6.9973 PPM

$A1 308.215 8.61OO O.OOOO O.OOOO 8.61OO-O.00298 PPMa.sioo o.oooo o.oooo s.sioo o.00995 PPM8.8140 O.OOOO O.OOOO 8.8140 O.O1022 PPM

$V 310.230 30.470 O.OOOO 8.876O 21.594-O.OO672 PPM30.880 0.0000 8.8500 22.030-0.00370 PPM30.838 0.0000 9.0800 21.758-0.00558 PPM

SBe 313.042 0.88600 0.28000 0.0000 0.60600-O.00017 PPM0.92400 0.29800 0.0000 0.62600-0.00009 PPM0.92OOO 0.29800 0.0000 0.62200-O.00010 PPM

$Ca 317.933 98.55O O.OOOO O.OOOO 98.55O 4. 5O32 S||tknQ4 R 3 0 5 6 k 51OO.S9 O.OOOO O.OOOO 1OO.S9 4.6175 HWW*»

-HW>_I w>^."T./»J-T i.-TSfW <w<. OST^UO U. UWW U./.'OSXJ O . O JL •9*+<3 ITTl

1.56OO 0.698OO O.OOOO O.S62OO O.O2137 PPM1.538O O.70400 O.OOOO 0.834OO O.02052 PPM

*Ag 328.068 8.10OO 0.0000 7.9260 0.174OO O.O0127 PPM8.1860 O.OOOO 7.9880 0.19800 0.00157 PPM8.2000 0.0000 8.0820 0.11800 0.00057 PPM

I——— 13:33:23 10/21/91 ———— Method: BCM1 WITHOUT RATIO

Sample 130415-F- 1 #MEAS.= 3 for Seq., #MEAS.= 3 for Simul.

EL CONC/ sigma EL CDNC/ sigma EL CONC/ sigma EL CONC/ sigma

*As 0. 15454/ 367. $Se-0.03441 / 1807. $SbO. 000000/+o***7. $Zn 0.02702/ 6.27.

*Pb-0.00504/ 4507. *Cd 0.00043/ 3207. *Co 0.01812/ 7.77. $Ni 0.04713/ 117.

$Ba 0.01953/ 3.37. $Mn oIoOOOS/ 6207. *Fe 0\02928/ 4.57. $Cr 0.'28047/ 1.37.

$Mq 6.9176/ 1.17. $A1 0.00574/ 1307. $V -O.OO533/ 297. $Be-O.OOO12/ 367.V-^B -Q2.3-Y <. 002-3

*Ca 4.5313/ 1.57. *Cu O.02535/ 3.97. *Ag O.OO114/ 457.

Measurements for 130416-UF- 1

•fl

«


*As 193.699 0.484OO O.OOOO 0.464OO O.02OOO 0.09173 PPM0.4920O O.OOOO 0.47800 O.O14OO 0.07301 PPM0.478OO O.OOOO O.48600-O.OO80O O.OO417 PPM

|Se 196.O3O O.758OO O.772OO O. OOOO-O. O14OO-O. 01665 PPM0.75600 0.800OO 0.0000-0.0440O-0.06661 PPMO.76800 0.80000 0.0000-0.03200-O.04663 PPM

*Sb 206.833 1.7720 O.OOOO 1.7780-0.OO6OO 0.00196 PPM1.7360 0.0000 1.8000-0.06400-0.01935 PPM1.7260 0.0000 1.7800-0.054OO-O.01568 PPM

*Zn 213.856 1.432.0 O.OOOO 0.72600 0.706OO O.O34O8 PPM1.4380 0.0000 0.75000 0.688OO O.03300 PPM1.430O O.OOOO 0.75200 0.6780O 0.0324O PPM

*Pb 220.353 4.174O 4.1740 0.0000 0.OOOO-O.01163 PPM4.2380 3.9740 0.0000 0.26400 0.02674 PPM4.184O 4.0820 0.0000 0.10200 0.00320 PPM

$Cd 226.502 1.4900 0.0000 1.4880 0.00200-O.00084 PPM1.5060 0.0000 1.4840 0.0220O 0.00026 PPM1.496O 0.0000 1.5080-0.01200-0.00161 PPM

$Co 228.616 2.0520 0.0000 0.0000 2.0520 0.02393 PPM2.O20O O.OOOO O.OOOO 2.020O 0.02192 PPM1.984O O.OOOO 0.0000 1.984O 0.01967 PPM

$Ni 231.604 3.016O O.OOOO 2.4600 O.556OO O.04215 PPM3.01SO O.OOOO 2.4500 O.568OO O.O4306 PPM3.054O O.OOOO 2.4500 0.60400 0.04577 PPM

*Ba 233.527 1.5680 0.0000 1.1860 0.3S20O 0.01473 PPM1.5880 0.0000 1.1720 0.41600 0.01608 PPM1.560O 0.0000 1.1880 0.3720O O.01434 PPM

$Mn 257.510 17.486 O.OOOO 1.3520 16.134 0.21474 PPM17.502 0.0000 1.3500 16.152 0.21498 PPM17.518 O.-OOOO 1.3480 16.170 0.21522 PPM

Fe 259.940 8.184O 0.0000 O.OOOO 8.184O O.11381 PPM8.2840 0.0000 0.0000 8.2840 0.11625 PPM8.346O O.OOOO 0.0000 8.3460 0.11777 PPM

*Cr 267.716 1.614O 1.5300 O.OOOO 0.084OO 0.01139 PPM1.5960 1.5480 O.OOOO O.O480O O.O0761 PftfhOO9ft1.588O 1.542O O.OOOO O.O46OO O.OO74O PPTT °

1«—i/tO U.U'SUOVJ C'.UWW—t? MTTIO.OOOO 1.29OO O.O76OO O.OOO4O-PPM

*Fe 2S9.94O 3 398CT O.OOOO O.OOOO> 3V598O O.OOfEZSTPRr3.482O O.OOOO O.OOOO 3.4S2O-O.OOL11 PPM3.368O 0.0000 O.OOOO 3.3680-O.OO389 PPM

*Cr 267.716 1.534O 1.5160 O.OOOO O.O1800 O.O0447 PPM1.4780 1.498O 0.OOOO-O.O200O O.OO049 PPM1.484O 1.4760 0.0000 0.00800 0.00342 PPM

$Mg 279.079 0.8520O O.886OO O.81400 0.002OO O.OO241 PPM0.844OO O.S58OO 0.784OO 0.02300 0.01253 PPM0.80200 0.8440O 0.76600-0.O03000.OOOOOO PPM

$A1 308.215 3.5820' O.OOOO 0.0000 8.5820-O.00479 PPM '8.4320 0.0000 0.0000 8.4320-O.O1449 PPM8.324O 0.0000 0.0000 8.3240-O.02148 PPM

$V 310.230 30.736 0.0000 3.8780 21.858-O.00489 PPM30.412 0.0000 8.7500 21.662-O.00625 PPM29.994 O.OOOO 8.5880 21.4O6-O.00802 PPM

$Be 313.042 0.9120O 0.292OO O.OOOO 0.62000-0.OOO11 PPMO.S800O 0.27800 O.OOOO 0.602OO-0.OO01S PPM0.86OOO 0.28OOO 0.0000 0.58000-O.O0027 PPM

$Ca 317.933 6.3620 0.0000 0.0000 6.3620 O.O0667 PPM6.1620 O.OOOO O.OOOO 6.1620-O.OO309 PPM6.2080 0.0000 0.0000 6.2080-O.00085 PPM

$Cu 324.754 0.85000 0.71000 O.OOOO 0.14000-O.O0059 PPM0.8180O 0.69200 0.0000 0.12600-0.00101 PPMO.S16OO O.6720O O.OOOO 0.144OO-O.OOO47 PPM

$Ag 328.068 3.1140 0.0000 8.0580 0.05600-0.OO021 PPM7.8740 O.OOOO 7.7840 0.09000 O.O0022 PPM7.8960 0.0000 7.8520 0.04400-0.O0036 PPM

———— 13:49:22 10721/91 ———— Method: BCM1 WITHOUT RATIO

Sample 130420RB-F- 1 #MEAS.= 3 for Seq. , #MEAS.= 3 for Simil

EL CONC/ sigma EL CONC/ sigma EL CONC/ sigma EL CONC/ sigmaS,£>Z/ <.&G>«

SAs 0. 12759/ 287. $Se 0.01776/ 1707. SSb-O.G1323/ 857. *Zn-O.OO012/ 8907.

$Pb-O. OOOOOO/+o***7. *Cd O.OO1O6/ 7O7. *Co-oIo018B/ 1O07. $Ni 0.00161/ 1907.

$Ba 0.00021/ 3407. $Mn O\ OOO13/ 1007. $Fe-O.OOlO9/ 2607. $Cr 0.00279/ 747.

$Mg 0.00498/ 1307. $A1-O.0135S/ 627. *V -0.00639/ 257. «Be-O.OOO19/ 437.

*Ca O.OOO91/ 5607. $Cu O.00418/ 6.87. $Ag-0.00012/ 2607.

Measurements for 130422MB- - 1


*As 193.699 0.44800 0.0000 0.44800 0.0000 0.02920 PPM0.44600 0.0000 0.46400-0.01800-0.02712 PPM0.444OO 0.0000 0.45200-0.00800 O.OO417 PPM

$Se 196.030 0.77400 0.76600 0.0000 0.00800 0.01998 PPM0.75200 0.75000 0.0000 0.00200 0.00999 PPM0.72000 0.75200 0.0000-0.03200-0.04663 PPM

*Sb 206.333 1.744O O.OOOO 1.7020 0.04200 0.01959 PPM1.6420 0.0000 1.6960-0.05400-0.01568 PPM1.7100 O.OOOO 1.726O-O.O16OO-O.OO171 PPM

$Zn 213.856 0.8460O O.OOOO 0.734OO 0. 1120O-O. OO143 P0.85200 0.0000 0.71400 0.13800 0.00012 p0.84200 0.0000 0.71600 0.12600-0.00060 PPM AR3Q564/

*Pb 220.353 3.9280 3.9640 0.0000-0.03600-0.O1686 PPM

O.UUCIU U.U/<*OO—O.*Cd 226-.502 1-43OO- O.OOOO 1.452O-O.O22OO-O. OO216 PPM

1V43&T O.OOOO 1.418O O.018OO O.OOOO4 PPM1.448O O.OOOO 1.4120 O.O3600 O.OO103 PPM

*Co 228.616 1.6300 O.OOOO 0.0000 1.6300-O.00251 PPM1.6500 O.OOOO 0.0000 1.6500-O.O0125 PPM1.6160 0.0000 0.0000 1.6160-O.00338 PPM

231.604 2.4020 O.OOOO 2.3840 0.01800 0.00161 PPM2.3180 0.0000 2.3780-0.060OO-O.00427 PPM2.3720 O.OOOO 2.3360 0.03600 0.00296 PPM

$Ba 233.527 1.2100 O.OOOO 1.1620 O.O4SOO O.OO146 PPM1.1820' O.OOOO 1.16OO O.O220O O.OOO42 PPM1.1680 0.0000 1.1640 0.OO4OO-O.OO029 PPM

$Mn 257.610 1.35SO O.OOOO 1.2840 O.O7400 O.00007 PPM1.364O O.OOOO 1.2720 0.09200 0.00031 PPM1.3660 O.OOOO 1.29OO 0.07600 0.00010 PPM

*Fe 259.940 3.4300 0.0000 0.0000 3.4300-O.00238 PPM3.4240 0.0000 0.0000 3.4240-0.00253 PPM3.4560 0.0000 0.0000 3.4560-O.00174 PPM

$Cr 267.716 1.498O 1.498O 0.0000 O.OOOO O.O025S PPM1.472O 1.498O O.OOOO-O.O260O-O.OOO14 PPM1.484O 1.49OO O.OOOO-O.O060O O.OO196 PPM

•$Mg 279.079 0.834OO 0.826QO 0.78800 0.02700 0.01446 PPM0.80800 0.85200 0.77200-0.00400-0.00048 PPM0.81800 0.83800 0.79400 0.00200 0.00241 PPM

*A1 308.215 8.4400 0.0000 0.0000 8.4400-0.01397 PPM8.4540 0.0000 0.0000 8.4540-0.01307 PPM8.4940 0.0000 0.0000 8.4940-0.01048 PPM

$V 310.230 30.404 '0.0000 8.6540 21.750-0.00564 PPM30.142 0.0000 8.8440 21.298-0.00877 PPM30.366 O.OOOO 8.7520 21.604-O.OO665 PPM

Be 313.042 O.S58OO O.25800 O.OOOO O.60OOO-O.OO019 PPM0.87OOO 0.2760O O.OOOO 0.594OO-O.00021 PPM0.88600 0.27800 0.0000 0.60800-O.00016 PPM

$Ca 317.933 6.136O O.OOOO O.OOOO 6.1360-O.O0436 PPM6.1040 O.OOOO 0.0000 6.1040-0.00592 PPM6.180O O.OOOO O.OOOO 6.1800-O.OO221 PPM

*Cu 324.754 O.S260O 0.6520O O.OOOO 0.174OO O.00045 PPM0.80600 0.68000 0.0000 0.12600-0.00101 PPMO.S14OO O.676OO O.OOOO O.138OO-O.O0065 PPM

*Ag 328.068 7.S30O O.OOOO 7.S620-O.O3200-O.00131 PPM7.796O O.OOOO 7.8100-O.O1400-O.O0109 PPM7.926O O.OOOO 7.6520 0.274OO 0.00252 PPM

13:53:14 10/21/91 ———— Method: BCM1 WITHOUT RATIO

Sample 130422MB- - 1 #MEAS.= 3 for Seq.. #MEAS.= 3 forSimul.

EL CONC/ siqma EL CONC/ siqma EL CONC/ siqma EL CONC/ sigma<* -&2.J <Z'&0¥

*As O.OS587/ 337. *Se-O.OO555/ 6507. $Sb 0. OOO73/+o***7. *Zn-0.00064/ 1207.

*Pb-0.00300/ 4307. $Cd o'.00026/ 6307. $Co-0.0023B/ 457. $Ni 0.00*010/+o***7.

$Ba O.OOO53/ 1707. *Mn O.'o0016/ 827. $Fe-O.OO222/ 197. $Cr O.O0147/ 977.

5Mg 0.00546/ 1507. *A1-0.01251/ 147. *V -0.00702/ 237. $Be-O. OOO19/ 15X

6Ca-0."o0416/ 45% *Cu 6.OO447/ 177. $Ag 0. OOO04/+o***7.

iI Measurements for 13O423-13O414DUP- 1 000104 HDOnCCf o

———— 14:20:52 1O/21/91 ———— Methods BCM1 WITHOUT RATIO

Sample 130426D-130415DUP- 1 #MEAS.= 3 for Seq., #MEAS.s 3 for Sin)ul .

EL CONC/ siqma EL CONC/ siqma EL CONC/ siqma EL CONC/<. 0Zf &#&> ~OZ3-

*As 0.11509/ 267. *Se-0.00888/ 6607. *Sb-0.00857/ 1307. *Zn 0.02220/ 3.27.4. £>&&£> 0«>£> .0/5- i$fff& . 2Y7 0&P

*Pb-0.00300/ 4707. SCd-0.00081 / 1307. *Co 0.01503/ 127. $Ni 0.04693/ 3.7%4.0Y7 &fiW> 4.00V QKP& *#<?9 ItftffP -270 Y#r

*Ba 0.01921/ 3.67. *Mn 0.00020/ 807. $Fe 0.09872/ 0.937. $Cr 0.27041/ 0.707.

$Mg 6.8S42/ 0.487. SA1-O.O1475/ 117. $V -0.00747/ 5.77. $Be-0.00023/ 407.'Jf-W y#PP .OZ.ZY /3#&> 4.00£2 &#PO

*Ca 4.S964/ 0.267. *Cu 0.02243/ 2.77. *Ag-O.OOO71/ 2607.

Measurements for 130427S-130415SPK- 1


$As 193.699 0.8460O O.OOOO 0.47400 0.37200 1.1932 PPM0.8320O O.OOOO O.464OO 0.36800 1.1806 PPM0.80400 0.0000 0.470OO O.334OO 1.0743 PPM

$Se 196.030 1.4460 0.78800 0.0000 0.65800 1.1024 PPM1.3880 0.79600 O.OOOO 0.59200 0.99245 PPM1.400O 0.766OO 0.0000 O.63400 1.0624 PPM

SSb 206.833 3.2780 O.OOOO 1.7840 1.4940 0.55302 PPM3.2280 O.OOOO 1.S26O 1.4O20 0.51923 PPM3.3OOO O.OOOO 1.7980 1.5020 0.55596 PPM

*Zn 213.856 10.344 0.0000 0.75600 9.5880 0.56507 PPM10.312 O.OOOO O.75SOO 9.554O O.563O4 PPM10.30O O.OOOO 0.7480O 9.5520 0.56292 PPM

$Pb 220.353 7.51OO 4.1120 O.OOOO 3.3980 O.48221 PPM7.464O 4.2300 O.OOOO 3.2340 0.45838 PPM7.266O 4.1S8O O.OOOO 3.0780 0.43571 PPM

SCd 226.502 2.442O O.OOOO 1.4860 0.95600 0.05156 PPM2.424O 0.0000 1.4980 0.92600 O.O4992 PPM2.418O O.OOOO 1.4940 0.92400 O.O4981 PPM

$Co 228.616 10.108 0.0000 0.0000 10.108 0.52849 PPM10.096 0.0000 0.0000 10.096 0.52774 PPM10.124 0.0000 0.0000 10.124 O.52950 PPM

$Ni 231.604 9.968O O.OOOO 2.4100 7.5580 0.56986 PPM9.9680 0.0000 2.4460 7.5220 0.56714 PPM9.9320 0.0000 2.3960 7.5360 O.56820 PPM

SBa 233.527 52.826 O.OOOO 1.2520 51.574 2.O495 PPM53.264 O.OOOO 1.2740 51.990 2.O660 PPM52.892 0.0000 1.2220 51.670 2.0533 PPM

$Mn 257.610 37.076 0.0000 1.3620 35.714 0.47646 PPM37.240 0.0000 1.3640 35.876 0.47863 PPM37.046 0.0000 1.3800 35.666 0.47582 PPM

$Fe 259.940 46.574 O.OOOO O.OOOO 46.574 1.0521 PPM46.878 O.OOOO O.OOOO 46.878 1.0595 PPM46.50O O.OOOO O.OOOO 46.5OO 1.05O3 PPM

$Cr 267.716 6.0480 1.5300 O.OOOO 4.5180 O.47599 PPM6.1020 1.5300 O.OOOO 4.5720 O.48165 PPM6.0960 1.5320 0.0000 4.564O 0.48OS1 PPM

$Mg 279.079 26.520 1.5200 1.7100 24.905 12.004 PPM26.804 1.5660 1.7660 25.138 12.116 PPM26.678 1.5720 1.7440 25.020 12.060 PPM nfMVI1§»R 3 0 5 6 k 9

*A1 SOS. 215 4O.268 0.0000 0.0000 4O.268 2.0448 PPM v""-"*______ ao ^ 1 Q O f-.f-ioo r\ - - -

r*r*n_ 31O.23O 1O*.S3- O.OOOO 9.O12O 95.87S O.5O77S PPM

1O5L29* O.OOOO? 8.934O? 3G 3SS>O.5I1O9 PPM -^<3104.64 O.OOOO 9.156O 95.48O O.505O2 PPM

*Be 313.O42 13.ISO O.288OO O.OOOO 12.862 O.O4917 PPM13.134 O.28600 O.OOOO 12.848 O.04912 PPM13.062 0.31200 0.0000 12.750 O.04872 PPM

pa 317.933 202.04 0.0000 0.0000 202.04 9.5510 PPM202.54 0.0000 0.0000 202.54 9.5756 PPM201.71 0.0000 0.0000 201.71 9.5347 PPM

*Cu 3 4.754 9.5260 0.70200 0.0000 3.8240 0.26355 PPM9.5980' 0.73400 0.0000 S.S64O 0.26477 PPM9.53OO 0.72OOO O.OOOO 8.81OO 0.26313 PPM

$Aq 328.068 12.712 O.OOOO S.274O 4.4380 O.O5475 PPM12.614 O.OOOO S.1660 4.4480 0.05487 PPM12.630 0.0000 8.2300 4.4000 0.05427 PPM

14:24:52 10/21791 ——-" Method: BCM1 WITHOUT RATIO

Sample 130427S-130415SPK- 1 #MEAS.= 3 for Seq., ttMEAS.= 3 for Siul. .

EL CONC/ siqma EL CONC/ siqma EL rry CONC/ siqjna EL_-? CONC/

*As 1.2150/ 5.47. *Sf» 1.0524/ 5.37. *SbO. S4274/ 3.87. *ZnLo. 56367V O.215U:46P .ffyo6 i*&A*Mfr .£-& /V8&A ^ Z soV"**.

4Pb 0.45876 / 5.17. $Cd 0.05061/ 1.97. *Cb 0.52858/ 0.177. *Ni 0.56840 / 0.247,

2.0562/ 0.427. *Mn 0. 4VE97/ 0.317. $Fjfj 1.0539/ 0.4£7. *ifr°*p. 4794S/ 0.647. o

$Mg 12.O60/ 0.477. $A .2.0476/ 0.137. $tr O.*50796/ O.6O7. *BeO.O49Ol/ O.5O7.

9.553S/ 0.227. *Cu 0.27342/ 0.317. *AVo.05463/ 0.587.

Measurements for 130415L-1/5- 1


*As 193.699 0.43400 O.OOOO 0.446OO-0.O1200-O.00834 PPM0.4420O O.OOOO O.434OO O.OO8OO 0.05423 PPMO.44200 O.OOOO 0.446OO-0.OO4OO O.01669 PPM

$Se 196.030 0.73000 0.74800 0.0000-0.01800-0.02331 PPM0.80000 0.74200 O.OOOO 0.05800 O.10324 PPMO.764OO 0.742OO O.OOOO O.O22OO O.0433O PPM

$Sb 206.833 1.7180 0.0000 1.7420-0.02400-0.00465 PPM1.686O 0.0000 1.7080-0.02200-0.00392 PPM1.6980 O.OOOO 1.7080-0.01000 0.00049 PPM

$Zn 213.856 2.2100 O.OOOO 0.74600 1.4640 0.07939 PPM2.2700 0.0000 0.74200 1.528O O.O8322 PPM2.3220 0.0000 O.718OO 1.604O 0.08776 PPM

$Pb 220.353 4.0400 3.9460 0.0000 0.094OO 0.00203 PPM4.12SO 3.9O20 O.OOOO 0.22600 0.02122 PPM3.94OO 3.8360 O.OOOO 0.1O400 0.00349 PPM

$Cd 226.502 1.4620 0.0000 1.436O 0.02600 0.00048 PPM1.4480 0.0000 1.4500-0.00200-0.00106 PPM

1 1 . 4 5 6 0 0.0000 1.4380 O.O1800 0.00004 PPMCo 228.616 1.6900 O.OOOO O.OOOO 1.6900 0.00125 PPM

1.6920 0.0000 0.0000 1.6920 0.00138 PPM1.6480 0.0000 0.0000 1.6480-0.00138 PPM

*Ni 231.604 2.6660 0.0000 2.3220 0.34400 0.02618 PPM2.618O O.OOOO 2.3OOO O.318OO O.O2422 PPM ^ „ r -2.7020 0.0000 2.3120 0.39OOO 0.02964 PPM 00011$R 3 0 D D J U

*Ba 233.527 1.328O O.OOOO 1.166O O.162OO O.OOS99 PPMPPM

*Mn 257.610 1 3320 O.OOOO - 111:

1.524&T- O~OOOO 1$Fe 259.940 4.7880 0.0000 0.0000 4.788O O.O3O81* PPM"

4.9220 O.OOOO O.OOOO 4.922O O.O34O9 PPM4.9060 0.0000 0.0000 4.9060 0.03370 PPM

$Cr 267.716 2.0280 1.4660 0.0000 0.56200 0.06147 PPM2.0660 1.4600 0.0000 0.606OO 0.06608 PPM2.0720 1.5000 0.0000 0.57200 0.06252 PPM

$Mg 279.079 4.1160 0.92800 0.93000 3.1870 1.5374 PPM4.2060'O.94200 0.89800 3.2860 1.5851 PPM4.180O 0.934OO 0.9O8OO 3.2590 1.5721 PPM

$A1 3O8.215 9.0100 0.0000 O.OOOO 9.0100 O.O2290 PPM8.9520 0.0000 O.OOOO 3.9520 0.01915 PPM8.9380 0.0000 0.0000 8.9380 O.O1824 PPM

$V 310.23O 30.454 0.0000 8.6720 21.782-O.O0542 PPM30.236 0.0000 8.6400 21.596-O.00670 PPM30.106 0.0000 3.6960 21.41O-O.OO799 PPM

$Be 313.042 O.S460O 0.25800 0.0000 0.58800-0.00024 PPMO.S56OO O.254OO O.OOOO O.6020O-O.OOO18 PPM0.8620O 0.25600 O.OOOO 0.60600-0.OOO17 PPM

*Ca 317.933 52.624 0.0000 0.0000 52.624 2.2631 PPM54.036 0.0000 O.OOOO 54.O36 2.3320 PPM54.078 0.0000 O.OOOO 54.078 2.3340 PPM

$Cu 324.754 1.6200 0.65400 0.0000 0.96600 0.02454 PPM1.63OO 0.67200 0.0000 0.95800 0.02429 PPM1.82SO O.6700O O.OOOO 1.1580 O.03038 PPM

$Ag 328.068 7.8760 0.0000 7.8220 0.05400-O.00023 PPM7.9320 0.0000 7.8920 0.0400O-0.00041 PPM7.8900 0.0000 7.7840 0.10600 0.00042 PPM

———— 14s29:55 10/21/91 ———— Method: BCM1 WITHOUT RATIO

Sample 130415L-1/5- 1 #MEAS.= 3 for Seq., #MEAS.= 3 for Simul

EL CONC/ sigma EL CONC/ sigma EL CONC/ sigma EL CONC/ sigma

$As 0.10435/ 307. *Se 0.04108/ 1507. *Sb-O.00269/ 1007. $Zn 0.08346/ 5.07.4 .00Z 4. OH

$Pb 0.0089 1/ 1207. $Cd O.OOO43/ 190% $Co O.OOO42/ 37O% $Ni O.02668/ 10%

$Ba 0.00665/ 8.67. $Mn O.O0227/ 117. $Fe 0.03286/ 5.47. $Cr 0.06336/ 3.87./•-s~£ 4.0 s-o 4.of<=> 4-OD/y

*Mg 1.5649/ 1.6% $A1 0.0201O/ 12% *V -O.OO67O/ 19% $Be-O.OOO2O/ 19%.?.J/ .0L?;V 4.ooZ2>

$Ca 2.3097/ 1.7% $Cu 0.03135/ 117. *Ag-O.OOO08/ 5807.

Measurements for ICSAF- - 1


$As 193.699 5.0560 O.OOOO 3.2O4O 1.8520 5.8239 PPM5.1120 O.OOOO 3. 17OO 1.9420 6. 1055 PPM4.9620 0.0000 3.1780 1 . 784O 5. 6112 PPM

$Se 196.030 2.4480 2.5100 0. OOOO-O. 06200-0. 09658 PPM2 . 4740 2 . 5460 0 . 0000-0 . 07200-0 . 1 1 323 PPM2.4000 2.5260 0.0000-0.12600-0.20315 PPM

*Sb 2O6.833 8.2O4O 0.0000 8 . 2700-0 . 06600-O . 02008 PPM8. 01 20 0.0000 8. 3600-0. 348OO-0 . 1 2368 PPMS.O220 0.0000 S.392O-0.37OOO-O. 13177 PPM

$Zn 213.856 1.914O O.OOOO 1.184O O.73OOO O.O3551 PPM 00011 R 3 0 5 6 5 I1.936O O.OOOO 1.2O2O O.734OO O.O3575 PPM

etmerits TOr-

Elements of SIWUfcJHNEOUS

*Na 589.592 15.698 O.OOOO O.OOOO 15.698 4.6O6O PPM15.636 O.OOOO O.OOOO 15.636 4.5412 PPM15.7O2 0.0000 O.OOOO 15.702 4.6102 PPM

K 765.490 9.56OO O.OOOO 0.0000 9.5600 4.3170 PPM9.6060 0.0000 0.0000 9.6060 4.4828 PPM9.6080 0.0000 0.0000 9.6080 4.4900 PPM


Sample LCSW1O-4 - - 1 #MEAS.= 3 for Seq., #MEAS.= 3 fSimul.

EL CONC/ sigma EL CONC/ sigma

$Na 4.585B/ 0.84% $K 4?4299/ 2.27.

Measurements for 13O414-


*Na 589.592 135.26 0.0000 0.0000 135.26 129.52 PPM134.16 0.0000 0.0000 134.16 128. 37 PPM133.65 0.0000 0.0000 133.65 127.84 PPM

K 766.490 80.894 0.0000 O.OOOO 80.894 261.37 PPM80.402 0.0000 0.0000 80.402 259.60 PPM79.942 O.OOOO O.OOOO 79.942 257.94 PPM

———— 16:10:23 10/21/91 ———— Method: BCM4 WITHOUT RATIO

Sample 13O414- - 1 #MEAS.= 3 for Seq., #MEAS.= 3 formul .

EL CONC/ siqma EL CONC/ sigmaSa9 6o

*Na 128. 58/ O.677. *K 259. 64/ O.667.



*Na 589.592 136.20 0.0000 0.0000 136.20 130.50 PPM136.85 0.0000 0.0000 136.85 131.18 PPM136.61 0.0000 0.0000 136.61 130.93 PPM

$K 766.490 81.426 0.0000 0.0000 81.426 263.29 PPM82.022 0.0000 0.0000 82.022 265.44 PPM81.908 0.0000 0.0000 81.908 265.02 PPM

———— 16:12:40 10/21/91 ———— Method: BCM4 WITHOUT RATIO

Sample 130415- - 1 #MEAS.= 3 for Seq., #MEAS.= 3 for

13O.87/ Oi 2fiX£«Mfe.' 2fc*_5e/ O.43O-.



*Na 589.592 94.522 O.OOOO 0.0000 94.522 86.958 PPM93.918 O.OOOO 0.0000 93.918 86.327 PPM93.818 O.OOOO O.OOOO 93.818 86.222 PPM

$K 766.49O 47.968 O.OOOO 0.0000 47.968 142.72 PPM47.744 0.0000 O.OOOO 47.744 141.91 PPM47.854 O.OOOO 0.0000 47.854 142.31 PPM


Sample 130416- - 1 #MEAS.= 3 for Seq., #MEAS.- 3 formul.

EL CONC/ sigma EL CONC/ siqma&£.<g~ W2-$Na 86.502/ 0.46% $K 142.31/ 0.287.

Measurements for 130417—


$Na 589.592 98.272 O.OOOO 0.0000 98.272 9O.876 PPM98.354 0.0000 0.0000 98.354 9O.961 PPM98.452 O.OOOO 0.0000 98.452 91.064 PPM

*K 766.490 49.308 0.0000 0.0000 49.308 147.55 PPM49.314 0.0000 0.0000 49.314 147.57 PPM49.396 O.OOOO O.OOOO 49.396 147.87 PPM


Sample 130417- - 1 #MEAS.= 3 for Seq., #MEAS.= 3 for imul.


*Na 90.967/ 0.10% *K 147.66/ 0.12%

Measurements for 130419RB-


$Na 589.592 11.116 0.0000 0.0000 11.116-0.18109 PPM11.280 0.0000 0.0000 11.280-0.00975 PPMLA*4v7& O.OOOO O.OOOO 11.-176-O-.144341.PPM- ui-ffjinai-

SK 766.490 8.1300 O.OOOO O.OOOO 8.130O-0.836O2 PPJ3--.. OMi S R 3TT58.I860 O.OOOO O.OOOO 8.1S6O-O.63422 pp900127 Hl8.2140 O.OOOO O.OOOO 8.214O-O.53332 PPM

inuui KHIIU

Simul.

EL CONC/ sigma EL CONC/ sigma^ • ~ - °™ fc * . v. j r ^ ^

iNa-O.10308/ 847. *K -O.66785/ 23%

Measurements for 130420RB-


*Na 589.592 12.424 O.OOOO O.OOOO 12.424 1.1855 PPM12.41O O.OOOO O.OOOO 12.410 1.1708 PPM12.444 O.OOOO O.OOOO 12.444 1.2O63 PPM

$K 766.490 7.8880 0.0000 0.0000 7.8880 -1.7081 PPM7.924O O.OOOO 0.0000 7.9240 -1.5783 PPM8.1360 0.0000 0.0000 8.1360-O.81439 PPM


Sample 130420RB- - 1 #MEAS.= 3 for Seq., #MEAS.= 3 foiSimul.


SNa LISTS/ 1.57. *K -1.3669/ 357.

Measurements for 130422MB- - 1


$Na 589.592 11.204 0.0000 0.0000 11.204-0.O8915 PPM11.296 0.0000 0.0000 11.296 0.00697 PPM11.248 0.0000 0.0000 11.248-O.04318 PPM

*K 766.490 8.318O 0.0000 O.OOOO 8.3180-O.15855 PPM8.3440 O.OOOO 0.0000 8.3440-0.06486 PPM8.296O O.OOOO O.OOOO 8.2960-O.23783 PPM


Sample 130422MB- - 1 #MEAS.== 3 for Seq., #MEAS.= 3 foiSimul.


$Na-0.04179/ 120% *K -0. 15375/ 567.

Measurements for 130423D-130414DUP- 1

——————————— OOO128Elements of SIMULTANEOUS

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Comments:

indicates analysis data exca«ds holding tisum. RR305655000324

I BCM LABORATORY

vudlt Date:Audited By:3rder *:

Analysis

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000325 ftR305656

1 BCM LABORATORY II SPIKE SAMPLE ANALYSIS

.udit Date:Audited By: vDrder ft:

Analysis

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flR305657000326

I BCM Laboratory IBlank Analysis Results

I I II Type I Cone IMatr ix

^ Mb(<Lr>/

<=ESample #

H20Source Contaminant

O.

/nr,Stir,i,**

Cone/Detection Limit

c . , urr,

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000327 flR305658

i ECULDeceerion Limits Resultst

Detecrion limits were reported for all samples analyzed: Yes]/ Ho.Exceptionsx

Analvsis 1 Dace'•lliiii11'

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000328 AR305659

DATA VALIDATION · 2020. 12. 12. · documentation of manual integrations was included in the data...

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Transcript of DATA VALIDATION · 2020. 12. 12. · documentation of manual integrations was included in the data...