Post on 12-Sep-2021
Phase Equilibrium and Purification Processes in the Production of Biofuels and Biocompounds
Research Team:
Antonio J. A. Meirelles – Lab. EXTRAE - FEA/UNICAMP Pedro A. Pessoa Fo. – EPUSP/USP Martín Aznar, M. Alvina Krahenbühl, Roberta Ceriani – FEQ/UNICAMP Mariana Conceição da Costa – FCA/UNICAMP Christianne E. C. Rodrigues, Cintia B. Gonçalves – FZEA/USP Eduardo A. C. Batista - FEA/UNICAMP 37 Graduate Students + 2 Postdoctorates (Simone, Magno, Inês, etc.)
National Collaboration: Luiza Silva – UFPA, Érika Cren – UFMG, Charles Abreu –
UFRJ, Lúcio Cardozo Fo. – UEM, Elias Monteiro Fo. – UFSJ, Adenilson – UFMA,
International Collaboration: Christian Stevens, Roland Verhé – Ghent University,
Belgium; Jérôme Pauly– University of Pau, France; João Coutinho – Aveiro University, Portugal; Rafiqul Gani, Technical University Denmark.
Industrial Collaboration: Santa Adélia Mill, Müller Beverage Company, Desmet
Ballestra (Belgium).
PROJECT GOALS
1.Simulation and Optimization of
Bioethanol Industrial Distillation.
2.Development of Biodiesel
Production by the Ethylic Route
3.Purification and Formulation of
Biocompounds.
Alcoholic
products Specifications
Standards
fixed by
Fuel
( Hydrous/ Anhydrous )
alcoholic content, pH, acidity, conductivity,
density, chloride, sulfate, iron, hydrocarbons ANP
Special/
Neutral
alcoholic content, pH, acidity, conductivity,
density, chloride, sulfate, iron, hydrocarbons, sulfur, copper, sodium, nitrogen, phosphorus,
acetaldehyde, ethyl acetate, methanol,
propanol , isopropanol , butanol , isobutanol , isoamilic alcohol, higher alcohols,
crotonaldehyde , dioxane , ciclohexane , benzene, ethylene glycol, diethylene glycol, acetal
Market
Industrial Distillation of Bioethanol
Bioethanol Distillation 1. Topic frequently investigated in the literature 2. Most works focused on Bioethanol Dehydration (last step
of the concentration process) 3. Oversimplified versions of the process: wine assumed to
be a binary mixture Ethanol + Water; Distillation Equipment as a simple Binary Distillation Column.
4. Minor components are neglected and their role in the distillation of Special Alcoholic Products not considered
Wine Composition
20 Components
Investigating Bioethanol Distillation
in Industrial Scale
1. Samples and Information collected in different sugar mills
2. Simulation of the real industrial equipment using ASPEN PLUS
3. Most important minor components taken into account
Validation Results
Evaluating Performance of Different Industrial Configurations
winecont
eth
productcont
eth
w
w
w
w
F
Total
Factor onPurificati
Heat Integrated Distillation Columns
ALCOHOL-CHEMISTRY requires PURE BIOETHANOL for avoiding damage to catalyst by minor components;
secondary reactions; accumulation of minor components
and final product contamination.
Conventional New Plant 1 New Plant 2 Steam Consumption (SC) (Kg/L) 5.22 3.31 5.22 Number of Trays (NT) 279 144 144 Decrease of SC 36 % 0 % Decrease of NT 48 % 48 % Purification Factor (FTotal) 8250 1092 8804
Patent submission
to INPI
Developing New
Configurations for Distilling
Neutral Alcohol
Developing an ethylic route for biodiesel production
“biodiesel are still among the most prominent alternative biofuels, and there
are still a lot of challenges in the future for research including the use of ethanol instead of methanol” (M. Mittelbach, Eur. J. Lipid Sci. Technol. 2009, 111, 745–746)
Concept: bioethanol used in the entire sequence of biodiesel production,
from the seed (extraction) to the tank.
Problem: Bioethanol accumulates water during biodiesel production, it must
be dehydrated before recycling. 2 Patents submitted to INPI.
Oil Extraction with Ethanol 1. Replacing Hexane as solvent used in the extraction of vegetable oils. 2. Combining the extraction of oils for producing Biodiesel and for edible
use. 3. Recovering Nutraceuticals of high added value (oryzanol, tocopherols,
tocotrienols, phytosterols, etc.) as byproducts or concentrated in the edible oil.
4. The future of the oil industry producing biofuels + food + feed + high added value products.
1. Close to Ethanol boiling point, Vegetable Oils highly
soluble in Bioethanol. 2. Strong acid used in Ion Exchange regeneration can be
also used as the Esterification Catalyst.
0.0
0.2
0.4
0.6
0.8
1.0
1.2
0 200 400 600
Co
nc
TIM
E/C
on
cIN
ITIA
L
time (min)
Soybean OilFFA
Crude Oil must be deacidified for biodiesel production
and for edible use.
Deacidification by Ion Exchange of Crude Oil dissolved in Ethanolic Solutions.
Initial Acidity (FFA)=2.12% Final Acidity=0.23%
Purification of ethylic Biodiesel 1.Phase splitting and decanting:
(biodiesel rich + glycerol rich) phases. 2.Ethanol evaporation, dehydration and
recycling. 3.Glycerol recovery, use as dehydrator
and purification as byproduct. 4.Biodiesel washing and drying. 5.Ethanol as reactant can be fed to the
process as hydrous ethanol and be dehydrated also using glycerol.
Oil Refining and biodiesel purification
Alcoholic and Fatty Biocompounds 1.Purifying and Obtaining Derivatives of High Alcohols (Fusel Oil) by
Computational Simulation Using ASPEN PLUS.
2.Refining of Edible Oils Containing high Levels of Nutraceuticals (-
carotene degraded during refining of Palm Oil can supply the worldwide
requirements of Vitamin A - Mayomol et al., JAOCS, 84, 587-596, 2007).
3.Physicochemical Properties and Solid-Liquid Transitions of Fatty
Systems: Important Information for Formulating Biodiesel Mixtures,
Cosmetics, Pharmaceutical Products and Food Additives.
Flash Point Data of Biodiesel Mixtures
Solid-Liquid Transition and Cloud Point Data
Type 2009/2010 2010/2011 2011/2012
Dissertations,
Theses, etc.
Postdoc 2/0a 3/2 2/2
PhD 19/2 18/3 21/1
MSc 17/4 21/6 16/6
Scientific Initiation 12/5 12/8 7/3
Technical Training 2/1 2/0 3/2
Publications
International
Journals
17 16 23
1.259 Impact Factors (2012) 4.268
Papers in Scientific
Meetings
25 21 19
Human Resource Training and Scientific Production
a x/y: x=total of students in activity, y=total of students that finish their work in the period.
Thank you for your attention
Acknowledgments: