No. 1

L’innovation dans les thermoplastiques techniques à haute tenue en température

CFP, les plastiques très techniques

June 19 th , DIJON Norberto Robalo Technical support engineer specialties France Olivier Pertoldi Sales developement specialist France

No. 3

Content

• Sabic Today

1st : part

• Xtrem high temperature polycarbonate technology

• Market segment applications

2nd: part

• high heat polyimide performance technology

• Market segment applications

No. 4

SABIC IN NUMBERS

36 years of growth

2nd largest global

diversified chemical company*

88 B$ total assets

50 B$ annual revenue

33,000 employees

40 countries

* Forbes 2011

No. 5

OUR GLOBAL OPERATIONS

Global Headquarters

Application centers (3)

Distribution, storage facilities and logistic hubs (46)

Technology centers (14)

Corporate research and innovation center (1)

International subsidiaries and sales offices (87)

Manufacturing and compounding companies (60)

No. 6

Polymers

Fertilizers

Metals

Performance

Chemicals

Innovative

Plastics

Polyolefines

PVC and

polyester

rubber

chemicals

Specialty

polymers

and polymer

additives

Long steel

and flat

steel

Aluminum

joint

ventures

Ammonia

Urea

compounds

Phosphate

Liquid fertilizers

Specialty

automotive

Catalysts

Rubber chemicals

Specialty

polymers

Polymer additives

Engineered

thermoplastics:

PC, ABS, PBT,

PPO, PEI

Specialty

compounds

Sheet & film

Polymershapes

Olefins,

oxygenates

and aromatics

Chemical

intermediates &

industrial gases

Chemicals

SIX STRATEGIC BUSINESS UNITS

No. 7

PRODUCTION HAS MULTIPLIED BY 6 IN 20 YEARS

A high rate of growth…

613

22

28

47

67

0

10

20

30

40

50

60

70

1985 1990 1995 2000 2005 2010

Pro

du

cti

on

(m

illio

n to

ns)

…reaching 67M metric tons in 2010

Metals

5.191

Fertilizers

7.043

Chemicals

42.268

Polymers

10.667

Performance Chemicals

0.458

Innovative Plastics

1.231

No. 8

WE RANK AMONG THE TOP PRODUCERS WORLDWIDE

#1 #2 #3 Mono-ethylene glycol

MTBE

Polycarbonate

Polyphenylene

Polyether imide

Granular urea

Methanol Polyethylene

Polypropylene

Polybutylene terephtalate

Engineering plastics

and its compounding

No. 9

Producing Plastics since 1935

Our company created:

‒ Polycarbonate (Lexan* resin) in 1953

‒ PPO (Noryl* resin) in 1961

‒ Polyetherimide (Ultem* resin) in 1982

‒ Amorphous thermoplastic polyimide (Extem* resin) in 2006

Since 1950, we have over 5,000 patents issued and in force

OUR HERITAGE IN INNOVATION

Lexan* Noryl* FILM / SHEET Valox*

Engineering Structural Foam

Ultem*

Xenoy*

Geloy*

Lexan* SLX

Cycolac*

Cycoloy*

Supec*

Noryl GTX*

Xylex*

Noryl PPX*

LNP*

Lexan* EXL

Lexan* XHT

Lexan* DMX

Flex Noryl*

Extem*

Valox* iQ

1950 1960 1970 1980 1990 2000 2010

pro

duct

port

folio s

ize

No. 10

INNOVATIVE PLASTICS IN THE ENGINEERING

THERMOPLASTICS INDUSTRY

Polystyrene Polyvinyl chloride

Lexan* (PC) Noryl* (PPO) Cycoloy* (PC/ABS) Geloy* (ASA) Cycolac* (ABS)

Xenoy* (PBT/PC) Valox* (PBT) Nylon

PEEK LCP HTN

PI PPSU Extem* (PI) Ultem* (PEI)

Engineering polymers and blends

Bulk polymers

High performance polymers

Family

Polyethylene Polypropylene

Clarity, colorability, impact strength

Chemical resistance, flow, electrical properties

AMORPHOUS CRYSTALLINE

High

Low

Perf

orm

an

ce

Pri

ce

* Trademark of SABIC Innovative Plastics IP BV

Lexan* Lexan* XHT Resins

A new family of truly high heat polycarbonate resins

Heat resistance

No. 12

Lexan* Specialty Resins Bring Value to Customers

Addition of new building

blocks yields Lexan PC

resins with new properties

Polymer

Functionalization

through additives

Polymer blends

Specialty Copolymers

Process Technology

Fu

nctio

na

lity

• Standard Technology

• Established Properties

• Advanced Technology

• Expanded Property Space • Greater Value for Customers • Leverages Core Expertise

Polymer

Functionalization

through additives

Polymer blends

Process Technology

Fu

nctio

na

lity

• Standard Technology

• Established Properties

• Advanced Technology

• Expanded Property Space • Greater Value for Customers • Leverages Core Expertise

No. 13

Heat

Amorphous Crystalline

PBI

PAI

PI

PPS

LCP PTFE

PEEK

HHPC

PSU

PES

PEI PPSU PA46

PPA XHT

PMMI

PAR

Chemical Resistance

High heat Polycarbonate

• Glass like clarity

• Long term use temperatures

- Robust Metallization/plating

- Stable clarity/color

- 150oC RTI UL Rating

• Heat/flow/ductility balance

Lexan* XHT

Resins

EXPANDING HIGH HEAT SOLUTIONS – FILLING A NEED

among all high heat resins…

True high heat performance between 140oC and 185oC w/

Glass Clarity, Metallization, Thin wall & Mechanical advantages

No. 14

Lexan* XHT Resins

Standard PC

Flow / Processing

Tru

e h

eat

perfo

rm

an

ce

Why another high heat PC?

Competitive HHPC Resins

No. 15

High heat resistance • Clarity

• Metallization aesthetics & aging

• Color stability on heat aging

• Improved flow/impact compared to

other high heat PCs

Auto bezels, Lens covers, Reflectors

Lexan* XHT resins – Automotive applications

Superior

Flow

Heat

resistance

No. 16

High heat resistance

• Color stability

• Higher RTI rating

• Flame retardant – clear V0 down to 2mm

and 5V down to 3mm possible

• Two shot molding with other materials

• Excellent flow for thin wall parts

• Single use medical devices

• Electrical applications at high use temp XHT4141 resin:

Mobile Phone Cover

XHT4143 resin:

Spot Light Lens

XHT4141 resin:

Mobile Phone

Battery housing

XHT4141 resin: Heater Pads

XHT4141 resin:

Face Shield

Lighting

Lexan* XHT resins – Industrial applications

Competitive material

Housings, Industrial lighting, Electrical

components, Flashlights, Fuses, Face

shields

Heat

resistance

As molded After use

No. 17

Lexan* XHT resins – Opaque Metalizable

Where? • Metallized

components

Why? • Range of Tg available – 155oC to 185oC

• Higher use temperature at equivalent

HDT

• Better resistance to blistering and micro-

cracking

170oC 175oC

Lexan* XHT

Resin

Competitive

High Heat PC

Resin

Failure modes

during use:

Pass

Hazing

Blistering

18

Lexan* XHT resins – Opaque Metallizable

Lexan* XHT resin Competitive HHPC

170 175 180 185 190

Temperature (ºC)

Video of failure mode with temperature for Lexan* XHT resin (Tg=185oC) and competitive high heat PC resin of

higher heat (Tg=205oC)

True Haze

Blisters before Haze

No. 19

LEXAN* XHT RESINS – TRANSPARENT –

COLOR STABILITY ON HEAT AGING

Heat Aging against Comp PC at 140oC

Lexan* XHT

High use temperatures (140oC+)

+

Clarity

+

Color stability

= Lexan* XHT resins

BPI PC

Control

BPI PC

250h

BPI PC

500h

BPI PC

750h BPI PC

1000h

Lexan* XHT

0h

Lexan* XHT

250h

Lexan* XHT

500h

Lexan* XHT

750h

Lexan* XHT

1000h

Comp PC

No. 20

COLOR STABILITY ON UV WEATHERING

PAR

XHT

PAR

XHT

High heat + Clarity + Low color shift on UV weathering = Lexan* XHT

resins PAR - Polyarylate

No. 21

LEXAN* XHT RESINS : MECHANICAL PROPERTIES

RELATIVE THERMAL INDEX (UL RTI)

HIGHEST RTI + Clarity = Lexan* XHT resins

Tensile strength retention at 150oC

Comp HHPC Std PC

Lexan* XHT resin

0%

20%

40%

60%

80%

100%

120%

1000 2000 3000 4000 5000 6000 7000

Time of exposure (hrs)

Ten

sil

e S

tren

gth

Rete

nti

on

Comp HHPC Std PC

Lexan* XHT resin

Impact Strength Retention at 150oC

0%

20%

40%

60%

80%

100%

120%

1000 2000 3000 4000 5000 6000 7000 Time of exposure (hrs)

Imp

act

Str

en

gth

Rete

nti

on

125oC 130oC 150oC 145oC 140oC 135oC

PAR Std PC Competitive

HHPC

Lexan* XHT

resins PMMI

HH PC – High Heat Polycarbonate,

No. 22

LEXAN* XHT RESINS – PROCESSING AND FLOW

Why? • Lexan* XHT resins demonstrate

~30% improvement in flow length

compared to competitive high heat

PC

• Lexan* XHT resins offer better

release

When? • When molding productivity is desired

• When design flexibility is desired

XHT4141 resin:

Mobile Phone

Battery housing

0.8 mm thickness

20

30

40

50

60

70

300 350

Temperature (oC)

Sp

ira

l F

low

Le

ng

th (

cm

)

Competitive HHPC

Lexan* XHT resin (HDT 155oC)

325

High heat + Clarity + Processability (flow, release)

= Lexan* XHT resins

No. 23

ARE LEXAN* XHT RESINS WHAT YOU NEED?

Lexan* XHT resin features

High Flow

High Heat

Direct Metallizable

Recyclable

Your Benefits

Enables Thinner walls with lower mass, faster cycle

times and Lower cost

Reduced Failures and broader design windows

Eliminate Lacquering cost and scrap

Reduced scrap, high yield, lower net cost

No. 24

LEXAN* XHT RESINS – PRODUCT PORTFOLIO

Le

xan

* X

HT

Resin

s

MFI‡

(g/10 min)

HDT†

(oC)

XHT4141 165 26

Notes: † 1.8MPa, 3.2mm

‡ 330oC/2.16kg

XHT3141 156 33

XHT4143

UV

Stabilized

XHT3143

Standard

XHT2141 145 48 XHT2143 XHT2146

High Release

XHT1141 70 135

XHT3146

XHT1143

No. 25

Lexan Copolymers – Portfolio Look

25

Clarity Impact Colors

Unique Product Attributes expand Polycarbonate Performance to New Applications

SLX

Weatherable

+

XHT

Heat Resistance

+

HFD

Superior Flow

+ CFR

Clear Flame

Resistance

+

EXL

Low Temp Impact

+

FST

Flame Smoke Toxicity

+ DMX

Scratch Resistance

+

No. 26

CONTACT US

Rob de Jong Product Marketing Manager Lexan* Copolymers

SABIC Innovative Plastics BV

Plasticslaan 1

PO Box 117

4600 AC Bergen op Zoom

T: +31 (0)164 292256

F: +31 (0)20 7948191

M: +31 (0)6 5185 2519

rob.dejong@sabic-ip.com

www.sabic-ip.com

Robert van de Grampel Product Technology Leader Lexan* Copolymers

SABIC Innovative Plastics BV

Plasticslaan 1

PO Box 117

4600 AC Bergen op Zoom

T: +31 (0)164 291947

F: +31 (0)164 291686

M: +31 (6) 8186 8270

robert.vande grampel@sabic-ip.com

www.sabic-ip.com

EXTEM

19th June 2012

High Heat solution

No. 28

1. Introduction

2. The Extreme Polymer landscape

3. EXTEM XH resins

4. EXTEM UH resins

5. EXTEM UP resins

6. LNP Specialty compounds with EXTEM resins

No. 29 29

INTRODUCTION

No. 30

WHAT IS EXTEM*

Extreme Environment Thermoplastics (up to 300°c)

• Melt Processable suitable for Thermoplastic processes (injection,

extrusion,.)

• Based on proprietary amines and anhydrides

• Proprietary blend technology with e.g., PEEK resin

+

Thermoplastic PolyImide

No. 31 31

THE EXTREME POLYMER LANDSCAPE

No. 32

The top of the Pyramid

High Performance Amorphous

v Modulus at elevated temperature

v Dimensional stability

v Creep resistance

High Performance Crystalline

v Continuous use temperature

v Chemical resistance

v Wear resistance

Ultra High Performance

v High temp. load bearing

v Low & stable CTE

v Typically must have imidization step

Heat

Amorphous Crystalline

PBI

PAI PI

PPS

LCP PTFE

PEEK

HH PC PSU

PES ULTEM*

PEI resin

PPSU

PA46

PPA

Chemical Resistance

XH

UH

UP EXTEM

No. 33

THE EXTEM* PORTFOLIO

EXTEM

XH UH UP

• Amorphous

• Tg up to > 300°C

• Excellent chemical

resistance

• RTI Listing up to 260ºC

• Amber translucent /

amber transparent

• Amorphous

• Tg up to 267°C

• LOI = 45%

• Amber transparent

• *

• Amorphous/Semi-

Crystalline blends (Extem

/PEEK Blend)

• Tg ~ 145/300°C, Tm ~

343°C

• Outstanding chemical

resistance

• RTI Listing up to 240ºC

• LOI ~ 42%

• Opaque

No. 34 34

EXTEM XH FAMILY

High

Temp.

Resist.

High

Strength

FST

Perf.

No. 35

35

EXTEM* XH – DMA’s

10

100

1000

10000

50 100 150 200 250 300 350

Temperature [°C]

Mo

du

lus

[M

Pa

]

ULTEM* 1000

PPS

EXTEM XH

Tailorable Tg

No. 36

0

10

20

30

40

50

60

70

80

0 50 100 150 200 250 300

Sp

ecif

ic T

en

sile S

tren

gth

(M

Pa c

m3/

g)

Temp (deg C)

Aluminum/EXTEM XH Comparison

Specific Tensile Strength

EXTEM XH1005

Aluminum 6063-T5

Aluminum 1100-H18

Specific Tensile strength outperforms some DCAL’s at T°

EXTEM* XH – Specific strength & fst

LOI (%) UL-V0 (mm)

Ultem PEI resin 45 1.6

PEEK 35 1.6

PAI 45 1.2

Extem XH1005 45 0.4

Limiting Oxygen Index (LOI) & UL94

Aircraft Flammability

Aircraft Verticle burn OSU heat Smoke Density Smoke Toxicity

FAR and OEM release Ds, 4min Draeger tube

Specs FAR 25853 FAR 25.853 ASTM F814/E662

ABD0031 ABD0031

BSS7238 BSS7238

Extem UH1006 a(60s), pass 0/21 <50, pass Pass

Extem XH1005 a(60s), pass 3/41 <50, pass Pass

Ultem 1000 a(60s), pass 35/65 <50, pass Pass

Ultem 9085 a(60s), pass 20/40 <50, pass Pass

No. 37

EXTEM XH POTENTIAL APPLICATIONS

Semicon

• Chip Trays

• Pick up systems

•Test Sockets

Food Service

• Baking Trays

• Oven components

Offering:

• Cleanliness

• Dimension stability

• Strength/Creep resistance at high T’s

• Thin wall

Offering:

• Baking temperature up to 250°C

• Low Staining

• Durability

• Thin Wall

Agency’s Food-contact:

- EFSA approved per 1/1/2010

No. 38

Automotive

• Main beam/fog- light Reflectors

• Turbochargers

E&E/Lighting

• Defense, Aerospace Connectors

• LED Substrates

• FO Lenses and Connectors

• Industrial/Domestic lighting

Offering:

• Direct Metallization

• Haze Onset ~250oC

• Transparency for near IR

light

• Dimension stability

• System Cost

Offering:

• Dimension Stability

• Strength at high temperatures

• Lead-free soldering

• Direct metallization

• Transparency in visible light &

near IR light

• System Cost Agency’s:

- UL Yellow Card for unfilled

EXTEM XH POTENTIAL APPLICATIONS

No. 39 39

EXTEM UH FAMILY

Superior

Temp. Resist

Chemical

Perf.

High

RTI

No. 40

0

0.5

1

1.5

2

2.5

0 50 100 150 200 250

Temp [°C]

Dim

Ch

an

ge

[%

]

Extem UH1006

PEEK

Dimensional Stability

• Linear, low expansion up to 240°C

Continuous Use – Aging for 1,000 Hr

• High continuous use temperatures

0%

20%

40%

60%

80%

100%

120%

200 220 240 260

Str

en

gth

Re

ten

tio

n [

%]

0%

20%

40%

60%

80%

100%

120%

200 220 240 260 Aging Temp [ºC]

EXTEM UH MECHANICAL RESISTANCE

No. 41

23°C, 7 day, Immersion

Chemical Extem UH1006 Polyamideimide (PAI)

Sulfuric Acid (10%) 95% 104%

Hydrochloric Acid (20%) 91% 104%

Sodium Hydroxide (10%) 93% 98%

Methylethey ketone (MEK) 93% 103%

Toluene 97% 106%

o-Dichlorobenzene 98% 107%

% Strength Retention

EXTEM UH CHEMICAL RESISTANCE

High Strength Retention

No. 42

Semicon

• Chip Trays

• Pick up systems

Offering:

• Cleanliness

• Tg > 300°C/572°F

• UL94 V0 @ 0.4mm

• Dimension stability

• Strength/Creep resistance at high T’s

Electrical

• Connectors

• Wire and cable

• Film

• Speaker cones

• Electrical/thermal insulation

Offering:

• Strength/Creep resistance at high temp

• Dimension stability at high temp

• High continuous use/thermal class

• High cut through temperature

• Chemical resistance Agency’s:

- UL Yellow Card for unfilled

- UL RTI for EXEM0025 @ 260°C!!

EXTEM UH POTENTIAL APPLICATIONS

No. 43 43

EXTEM UP FAMILY

High

Temp. Resist

High

Chemical

Perf.

High

RTI

No. 44

Performance over 150-300ºC

• Mechanical strength

• Low Creep

• Dimensional stability

• Chemical resistance

Expanding PEEK performance over 150ºC

0

50

100

150

200

PEEK

PEK

PBI - PEEK UP1004

0

50

100

150

200

PEEK

PEK

PBI - PEEK

Mechanical

Chemical

Wear

MechanicalMechanical

ChemicalChemical

WearWear

UP1007

Perf

orm

an

ce

PEEK ™

polymer PEEK

PBI -

PEEK

Cost

Extem UP

Blends

PEEK ™

polymer PEEK

PEK PEK PEK

EXTEM UP PERFORMANCE

No. 45

100

1000

10000

50 100 150 200 250 300 Temp [ °C]

Mo

du

lus

[ M

Pa

]

PEEK

UP1004

UP1007

EXTEM resin

Increasing EXTEM resin content

Up to ~5-10 times higher stiffness at 200ºC

EXTEM UP DMA

No. 46

Offering:

• Strength/Creep resistance at high temp

• Dimension stability at high temp

• Chemical resistance

• Excellent FR and low heat release

Transportation/Aerospace

• Connectors

• Cable wraps/holders/fixations

• Composites

EXTEM UP POTENTIAL APPLICATIONS

Offering:

• Strength/Creep resistance at high temp

• Dimension stability at high temp

• High Continuous Use Temperature

• Chemical resistance

• Thin wall

Industrial

• Pump/valve linings/seats

• Seals

• Bearings

• Gears

• Bushings

• Composites

47

LNP COMPOUND FAMILY

Many available effects with

Glass Fibre

Carbon Fibre

Mineral Filler

Additives (lubricant)

No. 48

MERCI !

Q & A

No. 49

Global Disclaimer

THE MATERIALS, PRODUCTS AND SERVICES OF SABIC INNOVATIVE PLASTICS

HOLDING B.V. ITS SUBSIDIARIES AND AFFILIATES (“SELLER”), ARE SOLD SUBJECT

TO SELLER’S STANDARD CONDITIONS OF SALE, WHICH CAN BE FOUND AT

http://www.sabic-ip.com AND ARE AVAILABLE UPON REQUEST. ALTHOUGH ANY

INFORMATION OR RECOMMENDATION CONTAINED HEREIN IS GIVEN IN GOOD

FAITH, SELLER MAKES NO WARRANTY OR GUARANTEE, EXPRESS OR IMPLIED, (i)

THAT THE RESULTS DESCRIBED HEREIN WILL BE OBTAINED UNDER END-USE

CONDITIONS, OR (ii) AS TO THE EFFECTIVENESS OR SAFETY OF ANY DESIGN

INCORPORATING SELLER’S PRODUCTS, SERVICES OR RECOMMENDATIONS.

EXCEPT AS PROVIDED IN SELLER’S STANDARD CONDITIONS OF SALE, SELLER

SHALL NOT BE RESPONSIBLE FOR ANY LOSS RESULTING FROM ANY USE OF ITS

PRODUCTS OR SERVICES DESCRIBED HEREIN. Each user is responsible for making its

own determination as to the suitability of Seller’s products, services or recommendations for

the user’s particular use through appropriate end-use testing and analysis. Nothing in any

document or oral statement shall be deemed to alter or waive any provision of Seller’s

Standard Conditions of Sale or this Disclaimer, unless it is specifically agreed to in a writing

signed by Seller. No statement by Seller concerning a possible use of any product, service

or design is intended, or should be construed, to grant any license under any patent or other

intellectual property right of Seller or as a recommendation for the use of such product,

service or design in a manner that infringes any patent or other intellectual property right.

SABIC is a trademark of SABIC Holding Europe BV

* Trademark of SABIC Innovative Plastics IP BV